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Recent Development Prospect of Separation of Scattered Metals with Solvent-impregnated Resins Process

Rare Metals and Cemented Carbides | Vol., Issue 4, 2003 | pp. 36-39
The current situation and prospect of separating scattered metals using solvent-impregnated resins(SIRs)process have been reviewed according to the types of SIRs.Such SIRs contain neutral organophosphorus extractants or acidic organophosphorus ones.The mechanism of SIR sorption is basically similar to the case of solvent extraction. The effective separation of scattered metals can be obtained under properly-controlled conditions.More study is required in respect of the improvement of the intensity and stability of the solvent-impregnated resin,separating mechanism,mass transfer mathematical model so as to provide theoretical criteria for its industrial application.The said technology will open up a new approach for the separation of scattered metals.
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Preparation of Ultra-fine CeO_2 Precursor for Optical Glass Polishing Material

Rare Metals and Cemented Carbides | Vol., Issue 3, 2003 | pp. 1-4
The ultra-fine CeO2 precursor for optical glass polishing material was prepared by selective oxidation and precipitation, washing, drying and calcination from low-cerium complex rare earth chlorides solution with NH3.H2O as precipitator, air and H2O2 as oxidative agent.The effect of reaction conditions and feeding mode on the content of CeO2 in precursor,and the correlativity between calcination temperature and particle size,specific surface area and mineralogical composition of precursor powder were investigated.The results show that by forward dripping, pH value controlled within 4.5 and 5.5,Ce3+ can be oxidized into Ce4+ to form hydroxide precipitant,followed by separation with other RE ions the ultra-fine polishing powder and precipitation before calcinations at 600~700 ℃ to obtain ultra-fine CeO2 precursor with CeO2 content over 80%,median particle size D50 less than 1.5 μm.
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Preparation of New Wearable Alloy Powder Block from Nano-structured WO_3+C Composite Powder

Rare Metals and Cemented Carbides | Vol., Issue 3, 2003 | pp. 5-8
A new type wearing-resistant alloy powder block was made from nano-structured WO3+C composite powder. Processing performance test is made for the analysis of surfacing layer structure,composition and hardness,etc.The results showed that the powder block has good welding processing performance,high deposition efficiency with tiny structure in the surfacing layer mainly containing W-enriched carbides of (Fe6W6C), acicular martensite and austenite.The hardness of the surfacing layer was over HRC60,max.HRC63.Compared to the micron powder,nano-powder block is characterized by higher W content in matrix,tiny structure,higher hardness,suitable for wearable surfacing.
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Failure Analysis of Cemented Carbide Drawing Die

Rare Metals and Cemented Carbides | Vol., Issue 3, 2003 | pp. 12-14
Failure analysis is made of cemented carbide die for drawing copper tube by scanning electron microscopy,etc.It was indicated that grain abrasion and adhesive abrasion were the main types of failure in the drawing die under boundary lubrication and dry friction.Based on the analysis of surface abrasion morphology and action of cyclic load and friction heat of the drawing die,theoretical analysis is made of its failure behavior.Based on the cause of the failures,exploratory suggestion is made for longer service life of the drawing die.
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