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Extraction of Vanadium from the Carbonaceous and Siliceous Vanadium Shale

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 1-3
Description is made of the property of carbonaceous and sdiceous vanadmm staale and test resmts on processes of direct acid leaching and blank oxidization and roasting acid leaching for vanadium extraction from the ROM ore. Comparison of technical and economic index shows that the use o{ ROM ore direct acid leaching resulted in 20.1~ less investment,1.85 ~ higher FIRR on investment (pre-income tax) and 0.28 year shorter investment return period, yet 4.8% more specific processing cost for per ton of ROM ore. This process is characterized by short process flowsheet, simple and sophisticated process,energy-saving and en- vironmentally friendly and easy for commercial production,It can he used for reference and popularized for similar vanadium mineral processing.
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Study on the Removal of Ammonia from APT Crystal Mother Liquor

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 4-7
Ammonia in APT crystal mother liquor was removed by adding sodium tungstate with sodium hydroxide and magnesium salts. The results show that the content of ammonia in the treated solution can be removed down to 0. 042 g/L up to 98.88% removal rate. The resultant sodium tungstate solution was diluted 10 times before prepared as ion exchange feed solution, the content of ammonia in the raffinate is less than 0. 000 5 % ,which can meet China national discharge standard.
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Research on the Thermal Decomposition of CoC_2O_4·2H_2O in the Argon Gas

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 8-12
Analysis is made on the thermal decomposition of CoC2O4 · 2H2O in the argon gas by TG-DSC and laser granulometer. The results showed that the thermal decomposition was done in two stages. First, the crystal water in CoC2O4 · 2H2O was lost at 150~275 ℃. Then,CoC2O4 was pyrolyzed into cobalt pow- der at 300~450℃. At 328.0~347.7℃ ,the biggest particle size change is found in the product,while at 347.7~500℃ ,the product particle size change is less. And between room temperature and 226.2 ℃ ,and at 226.2~328.0℃ ,the particle size change is not obvious. Therefore, the thermal decomposition condition of CoC2O4 · 2H2O in the argon gas can be controlled in stages in order to prepare cobalt powder of different particle sizes.
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Preparation and Particle Size Control of Spherical MnCO_3 Powder

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 13-16
Spherical MnCO3 powder of uniform particle size was prepared by liquid phase precipitation using MnSO4 as the manganese source and NH4 HCOa as the precipitating agent and sodium hexametaphosphate (SHMP) as the dispersant. In the paper,the impact of three primary parameters such as reaction temperature,reactant concentration and dosage rate of SHMP on the particle size of MnCO3 powder was investigated and the experimental results were charaeterized by the laser granulometer, scanning electron microscopy and X-ray diffraction. The results showed that at 10~50℃ ,the particle size of MnCOa decreased with the decrease of reaction temperature. However,too low reaction temperature results in serious agglomeration. The SHMP dosage rate η affects the particle size of MnCOa powder to a great extent and the size decreases gradually with the increase of dosage rate when dosage rate is η〈10%. The MnCO3 spherical particles of uniform size (~3.1μm) and excellent dispersibility were obtained under following processing parameters: reaction temperature up to 30℃,the ratio of [Mn2+]/[HCO3-] up to 5 : 1 and the dosage rate of SHMP up to 7 0/4o.
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The Latest Development of Preparation of Refractory Metals and Alloys by Molten Salt Electro-deoxidation

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 20-24
Description is made of the basic principle and process of the molten-salt electro-deoxidation for the preparation of refractory metals and alloys, the advantages and difficulties of the molten-salt electro-deoxidation are analyzed. The latest development of preparation of refractory metals and alloys by molten-salt electro-deoxidation is reviewed. The future development and prospect of the popularization,application and large-scale industrialization of the said process are discussed.
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新书推介——《钨冶金学》

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 12-12
由中南大学李洪桂教授、江西理工大学羊建高教授等编著的《钨冶金学》已由中南大学出版社出版。此书为国家出版基金项目“有色金属理论与技术前沿丛书”之一,内容限于钨的提取冶金领域(包括以提取冶金的原理和方法制取特种钨制品及钨基合金的前驱体),而对钨资源、钨化合物的性质等内容仅结合提取冶金过程的需要进行介绍;重点介绍近二十年来钨冶金领域基础理论研究和技术研发的新成果,在较全面收集近代有关文献资料和某些生产实践资料的基础上进行去粗取精、归纳提升,对前人已做全面介绍的内容则在不破坏其系统性的原则下尽量简化或删除。作者在著作过程中阅读了大量国内外文献(包括大量俄文文献)加以消化吸收,并与自己的研究实践结合著成此书。
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Analysis and the Latest Research of Basic Mechanics on Efficacy Loss of Hydrogen Storage Alloy Electrode

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 25-30
Analysis is made of the basic mechanics about efficacy loss of the electrode, such as pulverization of alloy particle, oxidation of element, amorphous after hydrogen absorption and crystalline after hydrogen desorption,and electrochemical corrosion. The latest research is reviewed. The way how to restrain or lower capacity degradation of electrode and improve cyclic property of hydrogen storage alloy electrode is introduced.
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The Influence of Monomer Concentration on Gelation and Property of Porous Titanium

Rare Metals and Cemented Carbides | Vol., Issue 4, 2011 | pp. 31-36
Porous titanium compacts were prepared by gelatining solidification and vacuum sintering techThe influence of monomer concentration on gelatining solidification,microstructure and properties of sintered compact of porous titanium were analyzed by scanning electron microscope (SEM), differential scanning calorimeter (DSC) and mechanical testing machine. The results showed that the role of dispersant citrate ammonium was apparent when the pH values of slurry were in the range from 7 to 9. When the monomer content,the added volume for the initiator and the ammonium are 20% 6mmol/L and 0.1 mL, respectively,the gelatin time is 68 rain at 45℃ reaction temperature. The bending strength of green compact with the monomer content of 15%,29% and 25% are about 15.2 MPa,20.6 MPa and 24.1 MPa,respectively. The green compact is sintered at 1 100℃ for 2 h,and the open-porosity ofsintered porous tita- nium is 39.5%.
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