Experimental optimization of process parameters for Pt/Al2O3-catalyzed hydrogen elimination and corresponding regulation strategies
To address safety hazards arising from trace H2 leakage in hydrogen energy systems, catalytic elimination using a Pt/Al2O3 catalyst was investigated. A test system was constructed to study the effects of Pt loading, inlet temperature, and space velocity on hydrogen conversion, along with catalyst microstructure analysis. Single-factor experiments indicate that increasing Pt loading from 1 wt% to 4 wt% significantly raises conversion rate from approximately 30% to over 85% at 1 vol% H2. Elevating the inlet temperature effectively overcomes the activation barrier, with a particularly pronounced effect at low temperatures. In contrast, the influence of space velocity is relatively weak and negatively correlated with hydrogen conversion. Multivariable synergistic analysis identifies inlet temperature as the dominant factor for overcoming surface activation limitations at low H2 concentrations, while Pt loading enhances reaction kinetics via increased active site density. At H2 concentrations above 2 vol%, the system enters an "interfacial reaction saturation" regime where all parameter effects diminish. Numerical simulations confirm these mechanisms, clarifying that synergistic mode of action wherein temperature dominates activation while Pt loading increases the reaction rate.
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