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Process Design for Milling and Reduction Roasting of Manganese Dioxide Ore

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 21-24
The production process of manganese monoxide roasted product prepared by using manganese di oxide ore as raw material,and using single cylinder dryer for drying ore,high pressure grinding roller for milling and electrothermal rotary kiln for reduction roasting was introduced. The reduction rate of manga nese can reach 98.5%,and high quality raw materials can be provided for the subsequent leaching,purifica tion, electrolysis, reprocessing, evaporation crystallization and other process steps to produce electrolytic manganese dioxide and high purity manganese sulfate products.
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Effect of Arsenic on the Preparation and Carbonization Process of Violet Tungsten Oxide

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 25-30
Arsenic (As) is a common impurity element in scheelite,and needs to be removed in the metallurgical process. However, the effect of arsenic on the subsequent tungsten products is not clear. APT-As composite powders with As mass content of 1% was prepared by using ammonium tungstate and As element as raw materials. After the treatment of calcination and carbonization, violet tungsten oxide(W18O49-As) and tungsten carbide (WC-As) containing arsenic were obtained, respectively.X-ray diffractometer, scanning electron microscope, high-resolution transmission electron microscope and differential scanning calorimeter were used to analyse the morphology and structure of W18O49-As and WC-As. The results show that As element mainly exists in the surface of the bar W18O49-As in the form of W2O3 (AsO4)2 phase,making bar W18O49-As easily break. The initial reaction temperatures of reduction and carbonization of W18O49-As are lower than those of W18O49. The phase of W2O3 (AsO4)2 is distributed between W18O49 powders,hindering substance migration and diffusion in the process of W18O49 carbonization and inhibiting aggregation and growth of fine WC particles,so the uniform WC-As powders are obtained.
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Preparation of WC Powder Containing Yttrium by Co-precipitation

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 31-35
The process of doping yttrium by co-precipitation with yttrium nitrate aqueous solution added during evaporation crystallization of ammonium tungstate was studied. Yttrium-doped ammonium paratungstate powder was prepared by the above process,and then tungsten carbide powder containing yttrium was prepared by redox,carbon distribution and carbonization.The results show that yttrium in APT pow der prepared by co-precipitation has relatively uniform distribution, and exists mainly in the form of Y(OH)3. The average particle sizes of tungsten carbide powders doped with 0.5%Y and 1%Y is 0.37μm and 0. 28μm,respectively.Yttrium doping has the effect of refining tungsten carbide powder.
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Research Progress on Corrosion Behavior of Titanium Alloy Used in Nuclear Spent Fuel Reprocessing Equipment

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 36-41
The material used in nuclear spent fuel reprocessing equipment and three-phase corrosion test ap paratus are introduced. The latest research progress on corrosion resistance of Ti-Ta and Ti-Ta-Nb typical corrosion resistant alloys in the simulated environment of nuclear spent fuel reprocessing is reviewed.
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Twinning and Texture Evolution of Beryllium during Room Temperature Deformation

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 42-46
The universal testing machine was used to carry out different strain compression tests of the isostatic-pressure beryllium at room temperature.SEM and EBSD were used to analysis twinning formation and texture evolution in beryllium material. The results show that only stretching twinning {1012} of be ryllium forms during room temperature compression. During the evolution of stretched twinning,twinning formation and growth has great promotion effect on the large-angle changing of grains and the formation of new texture {0001}. However,the coordination effect is reduced on the slip deformation of beryllium dur ing the later twinning period. In addition, uniaxial compression couples also play an important role in the formation of new texture {0001}.
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Effects of Homogeneous Interface Density on Thermoelectric Performance of P-type Bi0.5Sb1.5Te3 Alloy

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 47-50
The interface has a significant regulatory effect on the electroacoustic transport properties of the material.Therefore,the effect of homogeneous interface density on thermoelectric performance of P-type Bi0.5 Sb1.5Te3 alloy was investigated. The results show that the electrical conductivity of the alloy decreases and Seebeck coefficient increases with the increase of homogeneous interface density. Meanwhile,the ther mal conductivity decreases attributed to the enhanced scattering of phonons by increasing homogeneous in terface density. Because the sintered sample prepared by pulverizing for 1 min has the optimal electrical properties,it has excellent thermoelectric performance in the high temperature range.
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Research on Tool Wear in EHM Cutting of Inconel 718 Based on DEFORM-3D

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 51-55
Superalloy with difficult machining problem is the key material for engines. In order to reduce the tool wear depth in the machining area,the EHM simulation model of the superalloy Inconel 718 is estab lished by DEFORM-3D software. Then the simulation experiments of single factor experiments and or thogonal experiments are carried out with the EHM simulation model. The experimental results show that with the continuous increase of cutting speed, cutting depth and feed rate, the tool wear depth shows a steadily upward tendency,and the increase of the initial temperature of the workpiece continuously reduces the tool wear depth. Under the condition that the initial temperature of the workpiece keeps rising, the wear depth of the EHM simulation model tool is reduced by 21.9% compared with that of non-current heating cutting tool.
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Research Progress on Surface Modification of PEMFC Titanium Metal Bipolar Plate

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 56-61
Titanium and titanium alloys have low density,high strength and excellent corrosion resistance in acidic environments,and therefore have high research and application value in metal bipolar plates of proton exchange membrane fuel cells (PEM FC). The working principle of proton exchange membrane fuel cells is introduced,as well as the advantages and disadvantages of bipolar plates such as graphite materials,metal materials and composite materials. Taking titanium bipolar plate as an example, the surface modification methods and their research progress of metal bipolar plate are reviewed,and the future research direction of surface modification of titanium bipolar plate is pointed out.
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Application of Hafnium and Preparation Process of Hafnium Metal

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 62-65
Hafnium has very important application and research value because of its unique and excellent performance. The application of hafnium metal in nuclear industry and as a metal additive is introduced,as well as the application of hafnium compounds in various aspects. And several commonly used preparation methods of hafnium metal are described,such as iodination refining, electron beam melting, metal thermal reduction and molten salt electrolysis. The research progress and advantages and disadvantages of each method are summarized.
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Research Status and Application of Mechanical Ball Milling Coating Technology

Rare Metals and Cemented Carbides | Vol., Issue 3, 2019 | pp. 66-69
The research progress and application of mechanical ball milling coating technology in metal- based coating,photocatalytic coating and amorphous composite coating in recent years are reviewed. The process flow of mechanical coating technology is analyzed,as well as the influence of the technological pa rameters such as ball milling time,ball milling mode,ball milling speed and ball size on the mechanical ball milling coating technology. It is found that reasonable prolongation of ball milling time,selection of appro priate ball milling mode and ball size,and setting appropriate ball milling speed can increase the thickness of coatings and the fineness of material particles, and ensure the continuity, forming time and density of coatings. The advantages and disadvantages of this technology are briefly introduced and the future devel opment of this technology is prospected.
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