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Chemically Activated Liquid Phase Sintering of Tungsten-copper

Rare Metals and Cemented Carbides | Vol., Issue 4, 1996 | pp. 59-64
Liquid phase sintering of mixed W--Cu powders is hampered'by the insolubi lity of tungsten in copper. In this study, the propertiesof the system are significant ly improved by addition of less than lwtqdCo to the starting powder mixture. The effects of process variablessuch as cobalt content, initial homogeneity, copper parcticle size.copper content, green blank density, heating rate, and sintering temperature are invest irated.
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Preparation of ZrO_2-Y_2O_3 Ultrafine Powder

Rare Metals and Cemented Carbides | Vol., Issue 3, 1996 | pp. 1-6
The properties(phase, particle size. etc. ) of ZrO2-Y2O3ultrafine powder prepared by coprecipitation are studied using the techniques of XRD, DTA, TEM, SEM, etc. The composition, density and microstructure of the sintered compacts are analyzed together with discussion of effects of dispersant, concentration of salt solution,pH, ignition temperature on thecr sintering behavior. Try is made on dispersant instead of absolute ethyl alcohol to dewater to control the powder agglomeration. Optimum conditions for production of ultrafine powder are given with obtaining 20nm ZrO2-Y2O3 ultrafine powder.
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Analysis of The Formation of The SHSTiC Crystalline Structure

Rare Metals and Cemented Carbides | Vol., Issue 3, 1996 | pp. 6-12
This paper briefly introduces the common feature of the SHS process and the SHS's materials; reveals the effects of initial temperature, fast cooling, additives and other factors on microstructure of SHSTiC: analyzes the SHSTiC crystal with discussion about mechanisms of the synthesis and the structure formation.
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Study on Phase Transformation During the Reduction of Molybdenum

Rare Metals and Cemented Carbides | Vol., Issue 3, 1996 | pp. 13-18
Molybdenum powders have been made by directly reducing of ammonium molybdate and three-step reduction of ammonium molybdate. The rules of phase transformation taking place during reduction have been investigated by X-ray diffraction analysis and the effects of unstable phase of Mo4O11 on the reduction of molybdenum have also been discussed.
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Influence of Final Sintering Conditions on Doped Tungsten Property

Rare Metals and Cemented Carbides | Vol., Issue 3, 1996 | pp. 18-23
Sintering is aimed to obtain pore-free, near-theoritical density products under the high temperature. But for doped W during sintering, suitable potassium bubbles should be formed to stablize the fine pores so ao to make W wires to have large high-temperature creep strength, and impurities and useless dopant should also be removed simultaneously.The study shows that optimum density of W bars can be obtained under suitable sintering conditions.
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Influence of Sintering Temperature on WC-TiC-Co Double-phase Alloy

Rare Metals and Cemented Carbides | Vol., Issue 3, 1996 | pp. 28-32
Overall inspection and analysis are made of the structure of WC-TiC-Co double-phase alloys. sintered at different temperatures.Cutting tests are carried out on their related tips. The results show that regardless of the sintering temperature, free WC phases are found in all the double-phase alloys made from WC-TiC 70: 30 by mass saturated solid solution and Co powder. Its relative amount varies inversely with the sintering temperature, while the grain size of the carbide varies directly. The cutting life of the specimen sintered at 1480℃ is the longest.
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