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Mechanical Activation Effect on Leaching of Molybdenite

Rare Metals and Cemented Carbides | Vol., Issue 1, 2004 | pp. 1-4
The effect of mechanical activation on leaching kinetics of molybdenite is studied.Mechanical treatment causes slight depression of apparent activation energy for leaching molybdenite in HNO_3-H_2SO_4 solution.After 40-minute intensive mechanical activation in planetary centrifugal ballmill,the activation energy becomes 6kJ/mol less than that for leaching of non-activated one.We ascribe this to the layered structure of molybdenite.When violent mechanical force is acted on molybdenite crystal,it is easy to obviate such force through inter-layer slip since the Van der Vals force between S-S layers is very weak.
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Study of Rapid Precipitation of Crystalline Neodymium Carbonate

Rare Metals and Cemented Carbides | Vol., Issue 1, 2004 | pp. 5-7
The reaction expression of precipitation and crystallization is put forward based on the pH value change during neodymium chloride precipitation by ammonium hydrocarbonate.Study is made of the influence of feed rate,dosage,aging time on the process of neodymium carbonate crystallization.The technological condition for rapid precipitation of crystalline neodymium carbonate is verified.
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Thermodynamic Analysis of Scheelite Leaching by Fluoride Solution

Rare Metals and Cemented Carbides | Vol., Issue 1, 2004 | pp. 8-10
With the depletion of wolframite,scheelite concentrate substitute has become the developing trend of the future extractive metallurgy of tungsten.For the hydrometallurgical processing of scheelite concentrate by fluoride solution,the equlibrium concentration logarithm diagrams of every component is drawn according to thermodynamics calculation,under conditions of 0.10 mol/L and 0.12 mol/L fluoride concentration.Based on the logarithm diagram,the thermodynamic analysis is made of scheelite leaching by fluoride solution.
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Study of Technological Conditions of Chemically-plated Ni-B Alloy

Rare Metals and Cemented Carbides | Vol., Issue 1, 2004 | pp. 11-15
Study is made of the impact of plating solution composition and technological conditions on the sedimentation velocity of Ni-B alloy. Proper technological conditions of chemically-plated Ni-B alloy is selected, based on which amorphous Ni-B alloy layer is obtained containing 4.508% boron with good corrosion resistance.
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