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浸出过程的理论基础及实践

Rare Metals and Cemented Carbides | Vol., Issue 1, 1995 | pp. 14-19
浸出过程的理论基础及实践李洪桂(中南工业大学长沙410083)第六讲浸出过程在有色冶金中的应用(续)(3)针铁矿法根据100℃下Fe2O3-H2O系的平衡图.在Fe3+浓度很稀的条件下,Fe’“将形成针铁矿a—FeOOH沉淀。针铁矿为一种很稳定的晶体...
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Preparation of High-purity Niobium

Rare Metals and Cemented Carbides | Vol., Issue 1, 1995 | pp. 41-47
The behaviour of various impurity during Nb refiningdiscussed. It is pointed out that liquid/liquid extraction and moltensalt electrolysis refining can effectively remove refractory Ta and Winpurity while electron-beam refining is conventionaly used for ordinarymetal impuri ty and low-melting-point impurity. Ultra-high-vacuum annealing can minimize the content of intetstitial solid-solution impurity,Oneprocess for high-purity Nb preparation is recommended, ie: Nb2O5extracnon→Nb2O5 reduction→electrolytic refining→electron beam refining→zone melting by suspended electron beam→ultra-high vacuum annealing→high-impurity Nb. Three new refining processes are finally described.
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独联体国家的难熔金属氟化物化学气相沉积技术(下)

Rare Metals and Cemented Carbides | Vol., Issue 1, 1995 | pp. 48-51
独联体国家的难熔金属氟化物化学气相沉积技术(下)李汉广(中南工业大学长沙410083)3掌握了产品沉积结构的变化规律和优化条件难熔金属氟化物氢还原气相沉积时,可能得到五种类型的沉积结构(图8):a.树脂状结构;b.佳状结构;C.细晶结构:d.层状结构...
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