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Investigation on Preparation of Coarse Crystal W Powder through Li activated H 2 Reduction of WO 3

Rare Metals and Cemented Carbides | Vol., Issue 1, 1999 | pp. 1-6
Li activated H 2 reduction of WO 3 is carried out in four steps. During reduction of WO 3 with 200×10 -6 lithia at 900-950℃, the reduction duration can decrease by ~20%,The activation is greatly shown in the step of WO 2 W. The coarsening of W powder size and the effect of Li addition are clearly indicated in the step of WO 2.72 -WO 2,particularly in the step of WO 2-W. The mechanism of activation and grain coarsening during reduction is discussed.
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Study of Preparation of WCl 6

Rare Metals and Cemented Carbides | Vol., Issue 1, 1999 | pp. 7-10
Study is made of the preparation of WCl 6 by gas solid phase reaction.The reactor type, material morphology (W powder or briquette), furnace atmosphere, product quality, chloridization reaction velocity and the rectification of WCl 6 are investigated. Using the experiment results, the chloridization reaction velocity can accelarate, and the WCl 6 powder can be obtained with low oxygen(<0.5%).
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Trial Production of PVC Sheet by thd Addition of RE Stablizer

Rare Metals and Cemented Carbides | Vol., Issue 1, 1999 | pp. 23-26
Description is made of the reaction principle of RE Stablizer on the PVC plastics and the test on PVC sheet preparation by the said stablizer. The test results show that 0.2%~ 0.4 % addition of RE thermal stablizer can result in uniform plasticization of PVC plastics, longer thermal decomposition of the sheet, and a >50% decrease of “fish eyes” in the transparent sheet, 10~16° increase of the whiteness of the opal sheet, and 3~5° increase of the glossiness.
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Research and Manufacture of Composite Rolling Mill Guide Plate

Rare Metals and Cemented Carbides | Vol., Issue 1, 1999 | pp. 26-30
In this paper, on the basis of anal ysis of guide plate's damage form, according to hard alloy's properties and characteristics, we put forward that guide plate is made from hard alloy. In order to improve the fracture resistance of the plate and decrease the production cost, we develop acomposite cast technology of hard alloy. The results obtained show that the composite guide plate is safe and reliable in use, its service effect is more excellent than that of high Ni Cr steel and high Cr cast iron (steel) guide plate. The adoption of the composite guide plate will result in high precision rolled products with good surface quality, as well as increase of production rate by 2%~4%.
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Estimation of the Heat Capacity of Complex Organic Compounds by a Novel Topological Index

Rare Metals and Cemented Carbides | Vol., Issue 1, 1999 | pp. 30-35
A colored hydrogen depleted graph was proposed to replace molecular graph so as to obtain good discrimination of the complex organic compounds by dyeing both the edges and the vertices. Furthermore,the topological index Xu based on the adjacency matrix A and distance matrix D was derived and further adapted to the multiplybonds,heteroatom containing compounds by using the related bond length to C-C bond instead of the adjacent topological distance and the valence δ i instead of the degree of vertex ν i in this paper.The index was highly correlated with the heat capacity of alkanes, unsaturated hydrocarbons, aromatics and sulfur containing compounds,etc.,and the calculated values were in good agreement with experimental data. The proposed Xu index promised to be a useful parameter in QSPR/QSAR research.
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