Deep insight of unique phase transition behaviors and mechanism in Zr₂Co-H isotope system with ultra-low equilibrium pressure AITranslate

1Feng Wang,Rongfeng Li,Cuiping Ding,Wukui Tang,Yibo Wang,Shimeng Xu,Ronghai Yu,Ying Wu.Recent progress on the hydrogen storage properties of ZrCo-based alloys applied in International Thermonuclear Experimental Reactor(ITER)[J].Progress in Natural Science:Materials International,2017,27(1):58-65. 被引量：2

2Zhaoqing Liang,Zhendong Yao,Ruhong Li,Xuezhang Xiao,Zhichao Ye,Xuancheng Wang,Jiacheng Qi,Jiapeng Bi,Xiulin Fan,Huaqin Kou,Wenhua Luo,Changan Chen,Lixin Chen.Regulating local chemistry in ZrCo-based orthorhombic hydrides via increasing atomic interference for ultra-stable hydrogen isotopes storage[J].Journal of Energy Chemistry,2022,31(6):397-405. 被引量：2

4Wei Jiang,Hui Wang,Min Zhu.AlH_(3)as a hydrogen storage material:recent advances,prospects and challenges[J].Rare Metals,2021,40(12):3337-3356. 被引量：6

5Zi-Ming Cao,Pan-Pan Zhou,Xue-Zhang Xiao,Liu-Jun Zhan,Zhi-Fei Jiang,Shu-Mao Wang,Li-Jun Jiang,Li-Xin Chen.Development of Ti_(0.85)Zr_(0.17)(Cr-Mn-V)_(1.3)Fe_(0.7)-based Laves phase alloys for thermal hydrogen compression at mild operating temperatures[J].Rare Metals,2022,41(8):2588-2594. 被引量：1

6Zhi-Yu Lu,Hai-Jie Yu,Xiong Lu,Meng-Chen Song,Fu-Ying Wu,Jia-Guang Zheng,Zhi-Fei Yuan,Liu-Ting Zhang.Two-dimensional vanadium nanosheets as a remarkably effective catalyst for hydrogen storage in MgH_(2)[J].Rare Metals,2021,40(11):3195-3204. 被引量：11

1Yang Liu,Zhiyi Yang,Panpan Zhou,Xuezhang Xiao,Jiacheng Qi,Jiapeng Bi,Xu Huang,Huaqin Kou,Lixin Chen.A review of classical hydrogen isotopes storage materials[J].Materials Reports(Energy),2024,4(1):23-42.

1Fuzhou Wang,Jiaqi Xiang,Guike Zhang,Kai Chen,Ke Chu.Single-atom Co alloyed Ru for electrocatalytic nitrite reduction to ammonia[J].Nano Research,2024,17(5):3660-3666.

4Qi Cai,Qilin Yu,Xinyao Li,Yao Lu,Yanmo Li,Ganggang Cui.In situ investigation on densification mechanism of Ti-20Al-19Nb(at.%)alloy by TiH_(2)-assisted pressureless sintering[J].Journal of Materials Science & Technology,2023(34):170-186. 被引量：1

5Xiaochen Zhang,Hui Xue,Jing Sun,Niankun Guo,Tianshan Song,Jiawen Sun,Yi-Ru Hao,Qin Wang.Synergy of phosphorus vacancies and build-in electric field into NiCo/NiCoP Mott-Schottky integrated electrode for enhanced water splitting performance[J].Chinese Chemical Letters,2024,35(2):604-610.

6Fangling Hu,Liangliang Fu,Qingjin Zhang,Guangwen Xu,Dingrong Bai.Efficient synthesis of forsterite via high-temperature thermochemical reactions from boron mud waste without briquetting[J].Particuology,2024,87(4):124-132.

7Cancan Ling,Meiqi Li,Hao Li,Xiufan Liu,Guangming Zhan,Hongwei Sun,Chuan Liang,Yaling Li,Bing Zhou,Jincai Zhao,Lizhi Zhang.Symmetry dependent activation and reactivity of peroxysulfates on FeS_(2)(001)surface[J].Science Bulletin,2024,69(2):154-158.

8Chengyu Huang,Zhonghong Xia,Jing Wang,Jing Zhang,Chenfei Zhao,Xingli Zou,Shichun Mu,Jiujun Zhang,Xionggang Lu,Hong Jin Fan,Shengjuan Huo,Yufeng Zhao.Highly efficient and stable electrocatalyst for hydrogen evolution by molybdenum doped Ni-Co phosphide nanoneedles at high current density[J].Nano Research,2024,17(3):1066-1074.

9CHEN Hanming,WANG Jingyi,XU Xinhai.Parametric Study of Operating Conditions on Performances of a Solid Oxide Electrolysis Cell[J].Journal of Thermal Science,2023,32(6):1973-1988.

10Wu Hao,Wei Hongyuan.Optimization of Hydrocracking Process for Enhanced BTX Production from Coal Tar-Derived Hydrorefined Products[J].China Petroleum Processing & Petrochemical Technology,2024,26(1):139-151.

Basic Information:

DOI：

Chinese Library Classification Number:TB34[一般工业技术—材料科学与工程]

Citation Information:

Efficient capture,safe storage and release of tritium from the international thermonuclear experimental reactor(ITER) reaction exhaust gas is a perplexing problem,and the development of an efficient tritium-getter material with ultra-low hydrogenation equilibrium pressure is considered as a reliable way.In this work,Zr₂Co alloy was selected as a tritium-getter material and prepared through induction levitation melting.Fundamental performance test results show that Zr₂Co exhibits an ultra-low hydrogenation equilibrium pressure of 3.22 × 10^-6 Pa at 25℃ and excellent hydriding kinetics under a low hydrogen pressure of 0.005 MPa.Interestingly,unique phase transition behaviors were presented in Zr₂Co-H system.Specifically,Zr₂CoH₅ formed by Zr₂Co hydrogenated at room temperature is initially decomposed into ZrH₂ and ZrCoH₃ at200 ℃.With the temperature increasing to 350 ℃,ZrCoH₃is dehydrogenated to ZrCo,and then ZrCo further reacts with ZrH₂ at 650 ℃ to reform Zr₂Co and hydrogen.Among the staged phase transition pathways during dehydrogenation,the decomposition of Zr₂CoH₅ occurs preferentially,which is well accordance with both the smallest reaction energy barrier and the maximum reaction spontaneity that are determined respectively from kinetics activation energy and thermodynamics Gibbs free energy.Furthermore,first principles calculation results indicate that the stronger binding of hydrogen in interstitial environments of ZrCoH₃and ZrH₂ triggers the hydrogen-stabilized phase transformation of Zr₂CoH₅.The unique phase transition mechanisms in Zr₂Co-H system can shed light on the further exploration and regulation of analogous staged phase transition of hydrogen storage materials.