Study of New Process for Recovery of Cobalt Oxide from Al-containing Cobalt Sulphate Solution AITranslate
Abstract AITranslate
Study is made of a new process for directly extraction of the cobalt oxalate from ammonium oxalate in the acid solution directly dissolved from lithium cobaltate. Aluminum in the acid solution is completely complexed with F salt. Then,cobalt is precipitated with ammonium oxalate at pH= 2 and under 60 ℃. Finally,the cobalt is calcined into cobalt oxide in the muffle. To obtain the product,which is up to the requirement of the Co2O3-Y1(ehinese code GB6518-86). The dosage of the F salt is 110% of the theoretic dosage; while the dosage of ammonium oxalate can be reduced by 50 %. The rate of cobalt precipitation with ammonium oxalate is 99.37%.
KeyWords AITranslate
1廖春发.从含铝锂钴废料中回收氧化钴工艺研究[J].南方冶金学院学报,1999,20(3):181-185. 被引量:7
2郭炳琨 李新海.化学电源[M].中南工业大学出版社,2000..
3Zhang ping-wei,et al.Hydrometallurgical process for recovery of metal from spent lithium-ion secondary batteries[J].Hydrometallurgy,1998,47 (2-3):259.
4Contestable M,et al.A laboratory-scale lithium-ion battery recycling process[J].Journal of Power Sources,2001,92:65.
5Myoung J,et al.Cobalt oxide preparation from waste LiCoO2 by electeochemical-hydrothermal method [J].Journal of Power Sources,2002,112:639.
6吴芳.从废旧锂离子二次电池中回收钴和锂[J].中国有色金属学报,2004,14(4):697-701. 被引量:103
7钟海云,李荐,柴立元.从锂离子二次电池正极废料——铝钴膜中回收钴的工艺研究[J].稀有金属与硬质合金,2001,29(1):1-4. 被引量:66
8温俊杰,李荐.废旧锂离子二次电池回收有价金属工艺研究[J].环境保护,2001,29(12):39-40. 被引量:32
9申勇峰.从废锂离子电池中回收钴[J].有色金属,2002,54(4):69-70. 被引量:81
10潘泽强,杨声海.从钴锂膜废料生产钴产品[J].稀有金属,2002,26(1):39-42. 被引量:15
1张万琰,吴光源.从钕铁硼废料中回收稀土及氧化钴的条件试验[J].江西有色金属,2001,15(4):23-26. 被引量:12
2李丽琴.高炉低燃比操作模式[J].山东冶金,2002,24(5):40-42.
3舒利民.P204萃取分离钴、锰过程解析[J].中国新技术新产品,2012(22):85-86. 被引量:2
4A. Van den Steen,覃坚,覃国定.用硫化物沉淀法净化硫酸钴溶液的进展[J].有色冶炼,1992,21(4):5-10. 被引量:5
5第二季度中国进口现货锌精矿加工费减半[J].中国铅锌锡锑,2010(7):54-55.
6宾智勇,刘景槐,吴海国,李婕.废旧锂离子电池的综合利用试验研究[J].湖南有色金属,2008,24(5):27-31. 被引量:8
7李国民.高硅氧化锌矿浸出脱硅工艺的研究[J].中国有色冶金,2005,34(4):32-35. 被引量:31
8新技术[J].中国金属通报,2002,0(18):17-13.
9刁微之,徐远志,代云,左以专.氧化钴生产过程的非草酸盐沉钴工艺研究之二 碳铵(反加)法自硫酸钴溶液中沉钴[J].云南冶金,2007,36(5):29-33. 被引量:3
10钟海云,李荐,柴立元.从锂离子二次电池正极废料——铝钴膜中回收钴的工艺研究[J].稀有金属与硬质合金,2001,29(1):1-4. 被引量:66
Basic Information:
DOI:
Chinese Library Classification Number:TF816[冶金工程—有色金属冶金]
Citation Information:
Study is made of a new process for directly extraction of the cobalt oxalate from ammonium oxalate in the acid solution directly dissolved from lithium cobaltate. Aluminum in the acid solution is completely complexed with F salt. Then,cobalt is precipitated with ammonium oxalate at pH= 2 and under 60 ℃. Finally,the cobalt is calcined into cobalt oxide in the muffle. To obtain the product,which is up to the requirement of the Co2O3-Y1(ehinese code GB6518-86). The dosage of the F salt is 110% of the theoretic dosage; while the dosage of ammonium oxalate can be reduced by 50 %. The rate of cobalt precipitation with ammonium oxalate is 99.37%.
quote
| GB/T 7714-2015 | [1] TAN Hai-xiang, HU Qi-yang, LI Xin-hai, et al. Study of New Process for Recovery of Cobalt Oxide from Al-containing Cobalt Sulphate Solution[J]. Rare Metals and Cemented Carbides, 2006(1): 33-35. |
| MLA | [1] TAN Hai-xiang, et al., "Study of New Process for Recovery of Cobalt Oxide from Al-containing Cobalt Sulphate Solution." Rare Metals and Cemented Carbides, no. 1, 2006, pp. 33-35. |
| APA | [1] TAN Hai-xiang, HU Qi-yang, LI Xin-hai, WANG Zhi-xing, & GUO Hua-jun. (2006). Study of New Process for Recovery of Cobalt Oxide from Al-containing Cobalt Sulphate Solution. Rare Metals and Cemented Carbides(1), 33-35. |
| IEEE | [1] TAN Hai-xiang, HU Qi-yang, LI Xin-hai, WANG Zhi-xing, and GUO Hua-jun, "Study of New Process for Recovery of Cobalt Oxide from Al-containing Cobalt Sulphate Solution," Rare Metals and Cemented Carbides, no. 1, pp. 33-35, 2006. keywords: {lithium-ion secondary battery;Al-containing cobalt sulfate;ammonium oxalate;cobalt oxide} |
