Experimental Study and Dynamics Discussion of RhI_3 Direct Synthesis AITranslate
Abstract AITranslate
Direct synthesis method was applied in RhI3 preparation from 12 powder and Rh powder. Analysis is made of the influences of reaction temperature, reaction time and ball to powder ratio on the conversion rate, and the optimal reaction conditions were determined. Activation energy of the reaction was computed by Arrhenius formula. The results show that the effect of reaction temperature is limited. Therefore,the measures of using catalyst,improving I2 concentration and so on should be considered to improve the reactlon rate.
KeyWords AITranslate
1王亦飞,沈才大,于遵宏,朱新生.甲醇低压羰基合成醋酸的均相复合催化剂开发[J].华东理工大学学报:自然科学版,1997,23(1):33-38. 被引量:8
2Anjoy Majhi, Sung Soo Kim, Santosh T, et al. Rhodium (Ⅲ) iodide hydrate catalyzed three-component coupling reaction: synthesis of a-aminonitriles from aldehydes,amines, and trimethylsilyl cyanide[J]. Tetrahedron, 2008, 64(23) :5 509-5 514.
3邵昌平,王捷宇,郭和夫.Rh(Ⅰ),Co(Ⅰ)和Ru(Ⅱ)双齿磷氢化物的合成.结构表征和催化加氢活性[J].分子催化,1993,7(1):62-66. 被引量:2
4王胜国,熊晓东,吴聪,李茂良,李治宇.羰基合成用催化剂三碘化铑的合成[J].稀有金属,2005,29(4):482-484. 被引量:6
5权变利.均匀设计在活性碘化铑制备中的应用[J].贵金属,2011,32(3):60-63. 被引量:3
6杜清枝,杨继舜.物理化学(第二版)[M].重庆:重庆大学出版社,2005.
1刘桂华,潘再富,余尧,侯文明,沈善问,高金翠,杨军,彭玉玲,杨善晓,匡飞平.三碘化铑的新合成方法[J].云南化工,2012,39(3):13-15.
2徐传涛,刘殿华,房鼎业,贾云,冯成海,高有智,延建军.二甲醚与合成气制取二醋酸亚乙酯[J].化学反应工程与工艺,2012(5):418-421. 被引量:2
3陈静静.铑粉密度影响硫酸铑转化率的研究[J].化工时刊,2008,22(7):32-34.
4王定友.小议A法测定炭黑吸碘值的计算[J].炭黑工业,1997(4):21-23.
5贵研铂业股份有限公司[J].乙醛醋酸化工,2015,0(2):74-75.
6廖秋玲,曲志平,姚文学.水合三氯化铑的开发研究[J].中国资源综合利用,2000,18(11):9-10. 被引量:5
7王春芳,周宗辉,刘彩霞,程新.含MgO的硅酸盐水泥熟料的形成动力学(英文)[J].硅酸盐学报,2011,39(4):714-717. 被引量:11
8邓克旺,汤晓玉,陈春燕,蒋越,傅晟伟,肖泽仪.丙炔醇-丁炔二醇-水溶液的渗透汽化分离研究[J].精细化工,2010,27(2):142-146. 被引量:10
9王振宇,唐应吉,张蕾,马晓迅.羰基合成催化剂碘化铑的制备及催化性能研究[J].应用化工,2012,41(6):1003-1005.
10贵金属化合物系列标准荣获2012年度全国有色标委会救术标准优秀奖—等奖[J].中国贵金属,2012(11):12-12.
Basic Information:
DOI:
Chinese Library Classification Number:TQ138.22[化学工程—无机化工]
Citation Information:
Direct synthesis method was applied in RhI3 preparation from 12 powder and Rh powder. Analysis is made of the influences of reaction temperature, reaction time and ball to powder ratio on the conversion rate, and the optimal reaction conditions were determined. Activation energy of the reaction was computed by Arrhenius formula. The results show that the effect of reaction temperature is limited. Therefore,the measures of using catalyst,improving I2 concentration and so on should be considered to improve the reactlon rate.
quote
| GB/T 7714-2015 | [1] QUAN Bian-li. Experimental Study and Dynamics Discussion of RhI_3 Direct Synthesis[J]. Rare Metals and Cemented Carbides, 2012(4): 7-9. |
| MLA | [1] QUAN Bian-li. "Experimental Study and Dynamics Discussion of RhI_3 Direct Synthesis." Rare Metals and Cemented Carbides, no. 4, 2012, pp. 7-9. |
| APA | [1] QUAN Bian-li. (2012). Experimental Study and Dynamics Discussion of RhI_3 Direct Synthesis. Rare Metals and Cemented Carbides(4), 7-9. |
| IEEE | [1] QUAN Bian-li, "Experimental Study and Dynamics Discussion of RhI_3 Direct Synthesis," Rare Metals and Cemented Carbides, no. 4, pp. 7-9, 2012. keywords: {RhI3;direct synthesis;conversion rate activation energy} |
