daohang fenxiangbox searchbox qikanlogonew daohangnew searchboxnew navrightzone footerzone paper

Cobalt Determination of Cemented Carbide by Spectrophotometry with Picramazochrom as the Chromogenic Reagent AITranslate

Hubei Provincial Mechanical and Electrical Research Institute;Hubei Provincial Mechanical and Electrical Research Institute;Hubei Provincial Mechanical and Electrical Research Institute
AITranslate
Publisher: Editorial Office of Rare Metals and Cemented Carbides
Share Citation Information Add to Favorites

    Scan to share on WeChat or Moments

Use WeChat scan.
Share with WeChat friends or Moments

Abstract AITranslate

The chromogenic reaction between picramazochrom and cobalt was studied with plcramazocnrom as the chromogenie reagent. In the ammonium citrate-ammonia solution of pH10. 0,cobalt reacted with picramazochrom to form a green complex,which exhibited the maximum absorption wavelength at 670 nm with an apparent molar absorptivity of 2.62×10^4L /(mol·cm). And Beer's law was obeyed in the range of 0-50μg/25 mL cobalt. When the cobalt content in cemented carbide was determined directly by the spectrophotometry with picramazochrom,the relative standard deviation was between 1.4 % and 2.1%.

KeyWords AITranslate

cobalt picramazochrom spectrophotometry cemented carbide

1林阳书,万式郭.硬质合金YT料中钴的比色测定[J].南方钢铁,1990(3):6-8. 被引量:1

2赵尔燕,邱林友.分光光度法测定硬质合金中的钴[J].硬质合金,1993,10(1):35-36. 被引量:1

3李习纯,刘亮.电位滴定法连续测定硬质合金中的钴和镍[J].硬质合金,1993,10(4):229-231. 被引量:3

4张力,晁岳谦,刘以兴.YG类硬质合金中钴镍合量的测定[J].硬质合金,2003,20(1):32-34. 被引量:2

5吴玉霜.返滴定法测定硬质合金中的铁、镍和钴[J].硬质合金,1998,15(3):168-170. 被引量:3

6潘教麦,程思传,徐钟隽.苦氨酸偶氮变色酸与钴显色反应的研究及应用[J].冶金分析,1991,11(1):11-14. 被引量:7

7葛圣松,邵谦,徐小琳,朱云峰.苦胺酸偶氮变色酸分光光度法测定铝合金中钴[J].冶金分析,2005,25(4):43-45. 被引量:7

1姚喆,冯振华,柴成文,刘杰民.亚硝基R盐分光光度法测定合金钢中钴[J].中国无机分析化学,2011,1(1):61-64. 被引量:10

1喻生洁,赵勇,李霞,文占杰.亚硝基-R盐示差分光光度法测定粗钴盐中的钴量[J].世界有色金属,2022(18):115-118.

2周恺,孙宝莲,李波,张磊.高含量铼的紫外分光光度法测定研究[J].中国无机分析化学,2011,1(3):46-49. 被引量:14

3张家相,徐刚,贾云.紫外分光光度法测定增碳剂中氮含量[J].中国无机分析化学,2012,2(2):34-37. 被引量:8

4杨会珍.阶梯式程序升温测定硬质合金混合料中总氧量和氧分量[J].中国无机分析化学,2012,2(2):41-44. 被引量:6

5马哈亚.艾斯江,巴哈尔古丽.别克吐尔逊,段丽梅,罗新泽.铋、氧化铋、硫化铋在醋酸—硫脲中的溶解性研究[J].中国无机分析化学,2012,2(2):65-68. 被引量:3

6易可慧,邓飞跃,汪李,朱洁.多元光谱拟合-电感耦合等离子体原子发射光谱法测定钢铁中的磷[J].中国无机分析化学,2013,3(1):57-60. 被引量:7

7吕超,曾浩,王永明,夏乾坤.ICP-OES法测定镍铬合金中Si,Mn,Fe,Ti,Al,Cu多种元素[J].中国无机分析化学,2013,3(1):61-64. 被引量:5

8周志伟.分光光度法测定合金钢中的钼[J].中国无机分析化学,2013,3(2):53-55. 被引量:3

9李颖,冯秀梅,鲁魏,陈君,陈连芳.直读光谱法测定合金工具钢中铬、锰和钼[J].中国无机分析化学,2016,6(1):48-52. 被引量:1

10李敏,涂昀,傅凯文,邹健.电感耦合等离子体原子发射光谱法测定镍板中钴[J].中国高新科技,2019,0(16):96-97.

1潘教麦,程思传,徐钟隽.苦氨酸偶氮变色酸与钴显色反应的研究及应用[J].冶金分析,1991,11(1):11-14. 被引量:7

2钟国秀,黄清华,唐小红.苦氨酸偶氮变色酸光度法测定铜合金中钴[J].冶金分析,2012,32(1):68-70. 被引量:2

3张华山,黄应平,黎心懿,傅庸美.新取代苯基荧光酮试剂的合成及其性质的研究Ⅰ.新型取代苯基荧光酮的合成、提纯、鉴定及离解的研究[J].化学试剂,1995,17(4):197-200. 被引量:44

4夏心泉,赵书林,刘春华,薛芳.6─溴─苯并噻唑偶氮变色酸双波长标准加入法同时测定铁和铝的研究[J].岩矿测试,1996,15(3):217-221. 被引量:2

5杨浩义,钟国秀,黄清华.褪色光度法测定药物中钙的含量[J].理化检验:化学分册,2009,45(7):818-819. 被引量:1

6潘教麦,黄芳.苦胺酸偶氮变色酸光度法测定硝酸镍中痕量钴[J].化学分析计量,1999,8(2):6-7. 被引量:2

7黄应平,张华山.新试剂3,5-二溴-4-偶氮变色酸苯基荧光酮与锆(Ⅳ)显色反应的研究及应用[J].分析试验室,1997,16(6):18-20. 被引量:10

8黄应平,黎心懿,张华山.新试剂3,5-二溴-4-偶氮变色酸苯基荧光酮的合成及其应用研究[J].分析试验室,1996,15(4):33-36. 被引量:8

9黄应平,张华山,黎心懿.新型显色剂3,5-二溴-4-偶氮变色酸苯基荧光酮与锗显色反应的研究及应用[J].化学试剂,2000,22(3):160-162. 被引量:13

10黄应平,张华山,黎心懿.3,5-二溴-4-偶氮变色酸苯基荧光酮与铝显色反应及应用[J].岩矿测试,1997,16(4):293-295. 被引量:7

Basic Information:

DOI:

Chinese Library Classification Number:O657.32[理学—分析化学]

Citation Information:

The chromogenic reaction between picramazochrom and cobalt was studied with plcramazocnrom as the chromogenie reagent. In the ammonium citrate-ammonia solution of pH10. 0,cobalt reacted with picramazochrom to form a green complex,which exhibited the maximum absorption wavelength at 670 nm with an apparent molar absorptivity of 2.62×10^4L /(mol·cm). And Beer's law was obeyed in the range of 0-50μg/25 mL cobalt. When the cobalt content in cemented carbide was determined directly by the spectrophotometry with picramazochrom,the relative standard deviation was between 1.4 % and 2.1%.

quote

GB/T 7714-2015 [1] ZHONG Guo-xiu, YANG Hao-yi, YAN Gao-hua. Cobalt Determination of Cemented Carbide by Spectrophotometry with Picramazochrom as the Chromogenic Reagent[J]. Rare Metals and Cemented Carbides, 2009(3): 33-35.
MLA [1] ZHONG Guo-xiu, et al., "Cobalt Determination of Cemented Carbide by Spectrophotometry with Picramazochrom as the Chromogenic Reagent." Rare Metals and Cemented Carbides, no. 3, 2009, pp. 33-35.
APA [1] ZHONG Guo-xiu, YANG Hao-yi, & YAN Gao-hua. (2009). Cobalt Determination of Cemented Carbide by Spectrophotometry with Picramazochrom as the Chromogenic Reagent. Rare Metals and Cemented Carbides(3), 33-35.
IEEE [1] ZHONG Guo-xiu, YANG Hao-yi, and YAN Gao-hua, "Cobalt Determination of Cemented Carbide by Spectrophotometry with Picramazochrom as the Chromogenic Reagent," Rare Metals and Cemented Carbides, no. 3, pp. 33-35, 2009. keywords: {cobalt;picramazochrom;spectrophotometry;cemented carbide}