daohang fenxiangbox searchbox qikanlogonew daohangnew searchboxnew navrightzone footerzone paper

Preparation of BaMgAl10O17∶Eu2+ Blue Phosphor with Microwave Heating AITranslate

Hunan Rare Earth Metal Material Research Institute;Hunan Rare Earth Metal Material Research Institute;Hunan Rare Earth Metal Material Research Institute
AITranslate
Publisher: Editorial Office of Rare Metals and Cemented Carbides
Share Citation Information Add to Favorites

    Scan to share on WeChat or Moments

Use WeChat scan.
Share with WeChat friends or Moments

Abstract AITranslate

The blue phosphor BaMgAl10O17 : Eu^2+ (BAM : Eu^2+) was prepared with microwave heating. The effects of synthesis temperature, heat preservation time and heating rate on the luminescent properties of BAM : Eu^2+ were studied by orthogonal tests. XRD results show that the blue phosphor BAM : Eu^2+prepared with microwave heating is hexagonal with the space group P63/mmc. The results from spectral analysis show that the peak wavelength of the sample is 450 nm,corresponding to Eu2+ broadband transition 4f^65d→4f^7(^8S7/2). And the chromaticity coordinates x and y are equal to 0. 146 3 and 0. 069 3 respectively. The relative brightness is 106.8%. The results from particle size analysis show that the center size Ds0 is 7.00 μm and particle size distribution is concentrated.

KeyWords AITranslate

BaMgAl10O17 : Eu^2+ blue phosphor microwave synthesis orthogonal test

1Ravichandran D, Johnson S T, Erdei S, et al. Crystal chemistry and luminescence of the Eu^2+ -activated alka- line earth aluminate phosphors[J]. Displays, 1999,19 : 197-203.

2Kim K B,Kim Y I,Chun H G,etal. Structural and optical properties of BaMgAl10 O17 : Eu^2+ phosphor[J]. Chem Mater,2002,14:5 045-5 052.

3Blasse G. Luminescence of rare earth ions at the end of the century[J]. J Alloys Compd, 1993,192 : 17-21.

4陈哲,严有为.PDP用纳米BaMgAl_(10)O_(17)∶Eu荧光粉的燃烧合成及发光性能[J].物理化学学报,2006,22(8):1030-1033. 被引量:11

5Verstegen J M P J. A survey of a group of phosphors, based on hexagonal aluminate and gallate host lattices [J]. J Electroehem Soc, 1974,121(12) : 1 623-1 627.

6刘应亮,周光梅,冯德雄,石春山.表面扩散法制备BaMgAl_(10)O_(17):Eu^(2+)荧光体[J].无机材料学报,1999,14(3):425-430. 被引量:7

7Oshio S,Matsuoka T,Tanaka S,et al. Mechanism of luminance decrease in BaMgAl10 O17 : Eu^2+ phosphor by oxidation[J]. J Electrochem Soc, 1998, 145 ( 11 ): 3 898- 3 902.

8Stevels A L N,Schrama-de Pauw A D M. Eu^2+ luminescence in hexagonal aluminates containing large divalent or trivalent cations[J]. J Electrochem Soc, 1976,123(5) : 691-697.

9Smets B, Rutten J, Hoeks G, et al. 2SrO · 3Al2O3 · Eu^2+ and 1.29(Ba,Ca)O · 6Al2O3 : Eu^2+ ,two new blue -emitting phosphors [J]. J Electrochem Soc, 1989, 136 (7) :2 119-2 123.

10戴德昌,李沅英,蔡少华,谢驭洲,何汉波.(Ce_(0.67)Tb_(0.33))MgAl_(11)O_(19)和BaMgAl_(10)O_(17)∶Eu^(2+)荧光体的微波辐射合成及其发光性能[J].中国稀土学报,1998,16(3):284-287. 被引量:24

1刘吉波,杨涛,王志坚,苏正夫,成维.废旧稀土荧光灯资源的回收方法研究现状[J].稀有金属与硬质合金,2014,42(2):29-31. 被引量:3

2王琦,李友芬,齐士成.Al_2O_3/蒙脱土:Eu^(2+)架状结构发光材料的制备及发光性能研究[J].中国稀土学报,2014,32(3):275-281. 被引量:1

3张优灵,高银留,尹荔松.我国稀土无机转光剂的研究进展[J].化工进展,2014,33(A01):258-260. 被引量:3

4倪正民.市售稀土发光材料的表征及LED器件制作[J].实验室科学,2022,25(3):30-34.

5刘威岑,于博宇,刘丽.稀土铕配合物显现手印研究进展[J].广东化工,2022,49(22):95-99.

1申孟林,段西健,张忠义,闫慧忠,张立业.铕化合物对光伏电池光电转换效率的影响[J].稀土,2016,37(3):27-30. 被引量:2

2蒋宪邦,邓陶丽,刘艳.三价钆、三价锑共掺杂钙钛矿荧光粉的改性制备[J].辽宁化工,2018,47(3):189-192.

3张立志,周桓竹,樊思宁,秦振伟.发光材料中稀土元素回收的研究[J].科技创新与生产力,2018(7):50-52.

4郭钟群,赵奎,金解放,袁伟,梁晨.离子型稀土开发面临的问题与绿色提取研究进展[J].化工进展,2019,38(7):3425-3433. 被引量:15

5刘杨,刘琪,卫慧波,戴军,何文清.转光膜对草莓生长及品质的影响[J].中国蔬菜,2019,0(9):62-68. 被引量:7

6卡依尔江·卡哈尔.废荧光灯的环境污染对策探讨[J].新疆环境保护,2020,42(1):47-50.

7徐苏北,刘超,孙占学,李亚平,解原,王学刚.废弃荧光灯中稀土元素回收方法研究进展[J].稀有金属,2021,45(7):879-890. 被引量:2

1肖林久,张宝砚,邱关明,陈永杰,王双红,贺明睿.溶胶-凝胶法制备的BaMgAl_(10)O_(17)∶Eu^(2+)荧光性能研究[J].稀土,2005,26(4):15-19. 被引量:3

2郑永生,沈湘黔,景茂祥.控制反应沉淀法合成BaMgAl_(10)O_(17)球形粉体材料[J].矿冶工程,2005,25(6):82-86. 被引量:1

3一种免球磨、球形晶型荧光粉的制备方法[J].无机盐工业,2008,40(5):4-4.

4梅光军.Separation of Red (Y_2O_3:Eu^(3+)), Blue (BaMgAl_(10)O_(17):Eu^(2+)) and Green (CeMgAl_(10)O_(17):Tb^3) Rare Earth Phosphors by Liquid/Liquid Extraction[J].武汉理工大学学报:材料科学英文版,2009,24(4):603-607. 被引量:2

5张占辉,王育华,都云昆.BaMgAl_(10)O_(17)∶Eu^(2+)荧光粉的化学共沉淀法合成及其发光性质[J].功能材料,2004,35(5):627-629. 被引量:20

6陈鹏,朱月华,黄如喜.稀土氯磷酸盐体系蓝色荧光粉的研究[J].南京师大学报:自然科学版,2008,31(4):84-88.

7李曜,张金朝,宋鹂,骆志平.碱土金属离子对硼铝酸盐玻璃发光性能的影响[J].华东理工大学学报:自然科学版,2011,37(2):179-181.

8梁超,何锦华,蒋建清,董岩,张超.PDP用BaMgAl_(10)O_(17):Eu蓝粉的表面包覆研究[J].中国稀土学报,2007,25(3):360-363. 被引量:2

9刘海.萃取剂加水对C_(10~14)异构烷烃和环烷烃相对挥发度的影响[J].石油化工,2011,40(8):861-864. 被引量:1

10李永明.浅析D60型罗茨鼓风机的故障诊断[J].四川水泥,1994(1):28-30.

Basic Information:

DOI:

Chinese Library Classification Number:TQ133.3[化学工程—无机化工]

Citation Information:

The blue phosphor BaMgAl10O17 : Eu^2+ (BAM : Eu^2+) was prepared with microwave heating. The effects of synthesis temperature, heat preservation time and heating rate on the luminescent properties of BAM : Eu^2+ were studied by orthogonal tests. XRD results show that the blue phosphor BAM : Eu^2+prepared with microwave heating is hexagonal with the space group P63/mmc. The results from spectral analysis show that the peak wavelength of the sample is 450 nm,corresponding to Eu2+ broadband transition 4f^65d→4f^7(^8S7/2). And the chromaticity coordinates x and y are equal to 0. 146 3 and 0. 069 3 respectively. The relative brightness is 106.8%. The results from particle size analysis show that the center size Ds0 is 7.00 μm and particle size distribution is concentrated.

quote

GB/T 7714-2015 [1] YU Rong-min, LIU Yu-hui, WANG Yan-qi. Preparation of BaMgAl10O17∶Eu2+ Blue Phosphor with Microwave Heating[J]. Rare Metals and Cemented Carbides, 2012(1): 30-33.
MLA [1] YU Rong-min, et al., "Preparation of BaMgAl10O17∶Eu2+ Blue Phosphor with Microwave Heating." Rare Metals and Cemented Carbides, no. 1, 2012, pp. 30-33.
APA [1] YU Rong-min, LIU Yu-hui, & WANG Yan-qi. (2012). Preparation of BaMgAl10O17∶Eu2+ Blue Phosphor with Microwave Heating. Rare Metals and Cemented Carbides(1), 30-33.
IEEE [1] YU Rong-min, LIU Yu-hui, and WANG Yan-qi, "Preparation of BaMgAl10O17∶Eu2+ Blue Phosphor with Microwave Heating," Rare Metals and Cemented Carbides, no. 1, pp. 30-33, 2012. keywords: {BaMgAl10O17 : Eu^2+;blue phosphor;microwave synthesis;orthogonal test}