Study on Electrochemical Performance of Cu(Ⅰ)Ions in Choline Chloride-Urea Deep Eutectic Solvent AITranslate
Abstract AITranslate
The electrochemical performance was studied of Cu(Ⅰ)ions in CuCl-containing choline chloride-urea(ChCl-Urea)deep eutectic solvent as the electrolyte.The results show that the conductivity of ChCl-Urea-CuCl electrolyte increases with the increase of temperature,but increases at first and then decreases with the increase of CuCl concentration.The variation of its viscosity is opposite to its conductivity.In addition,the reduction reaction of Cu(Ⅰ)ions in ChCl-Urea-CuCl electrolyte is quasi-reversible and controlled by diffusion.The diffusion coefficient of Cu(Ⅰ)ions increases with the increase of temperature,but increases firstly and then decreases with the increase of CuCl concentration,which is mainly related to the existence form of Cu(Ⅰ)ions in ChCl-Urea deep eutectic solvent.
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Basic Information:
DOI：
Chinese Library Classification Number:TF811[冶金工程—有色金属冶金]
Citation Information:
The electrochemical performance was studied of Cu(Ⅰ)ions in CuCl-containing choline chloride-urea(ChCl-Urea)deep eutectic solvent as the electrolyte.The results show that the conductivity of ChCl-Urea-CuCl electrolyte increases with the increase of temperature,but increases at first and then decreases with the increase of CuCl concentration.The variation of its viscosity is opposite to its conductivity.In addition,the reduction reaction of Cu(Ⅰ)ions in ChCl-Urea-CuCl electrolyte is quasi-reversible and controlled by diffusion.The diffusion coefficient of Cu(Ⅰ)ions increases with the increase of temperature,but increases firstly and then decreases with the increase of CuCl concentration,which is mainly related to the existence form of Cu(Ⅰ)ions in ChCl-Urea deep eutectic solvent.
quote
| GB/T 7714-2015 | [1] TANG Jie, XU Cun-ying. Study on Electrochemical Performance of Cu(Ⅰ)Ions in Choline Chloride-Urea Deep Eutectic Solvent[J]. Rare Metals and Cemented Carbides, 2020(3): 18-24. |
| MLA | [1] TANG Jie, and XU Cun-ying. "Study on Electrochemical Performance of Cu(Ⅰ)Ions in Choline Chloride-Urea Deep Eutectic Solvent." Rare Metals and Cemented Carbides, no. 3, 2020, pp. 18-24. |
| APA | [1] TANG Jie, & XU Cun-ying. (2020). Study on Electrochemical Performance of Cu(Ⅰ)Ions in Choline Chloride-Urea Deep Eutectic Solvent. Rare Metals and Cemented Carbides(3), 18-24. |
| IEEE | [1] TANG Jie and XU Cun-ying, "Study on Electrochemical Performance of Cu(Ⅰ)Ions in Choline Chloride-Urea Deep Eutectic Solvent," Rare Metals and Cemented Carbides, no. 3, pp. 18-24, 2020. keywords: {Cu(Ⅰ)ion;choline chloride-urea;deep eutectic solvent;conductivity;viscosity;diffusion coefficient;metallurgical electrochemistry} |