Supramolecular Cross-Linking of Thiophenylene Polymers via Multiple Hydrogen Bonds toward High Refractive Index AITranslate
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Dihydroxy-substituted poly(phenylene sulfide) (DOHPPS) was synthesized via oxidative polymerization of bis(2,6-dimethoxyphenyl) disulfide and subsequent deprotection. The synergistic effect of multiple-hydrogen-bond cross-links and the rigidity of the thiophenylene backbone afforded dense yet amorphous supramolecular networks, resulting in a polymer with visible transparency and an ultrahigh refractive index (nD = 1.85).
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DOI：https://doi.org/10.1021/acsapm.3c00391
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Dihydroxy-substituted poly(phenylene sulfide) (DOHPPS) was synthesized via oxidative polymerization of bis(2,6-dimethoxyphenyl) disulfide and subsequent deprotection. The synergistic effect of multiple-hydrogen-bond cross-links and the rigidity of the thiophenylene backbone afforded dense yet amorphous supramolecular networks, resulting in a polymer with visible transparency and an ultrahigh refractive index (nD = 1.85).
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| GB/T 7714-2015 | [1] Seigo Watanabe, Hiromichi Nishio, Teru Takayama, et al. ACS Applied Polymer Materials, 2023(5). DOI:10.1021/acsapm.3c00391. |
| MLA | [1] Seigo Watanabe, et al., ACS Applied Polymer Materials, no. 5, 2023, https://doi.org/10.1021/acsapm.3c00391. |
| APA | [1] Seigo Watanabe, Hiromichi Nishio, Teru Takayama, & Kenichi Oyaizu. (2023). ACS Applied Polymer Materials(5). https://doi.org/10.1021/acsapm.3c00391 |
| IEEE | [1] Seigo Watanabe, Hiromichi Nishio, Teru Takayama, and Kenichi Oyaizu, ACS Applied Polymer Materials, no. 5, 2023, doi: 10.1021/acsapm.3c00391. keywords: {sulfur;hydrogen bonds;crosslinking;oxidative polymerization;high refractive index} |