Review
Ionomer adsorption governs coverage structure: interfacial engineering of fuel cell electrodes toward high-efficiency proton/oxygen transport
Chain | Vol.3, Issue 2, 2026 |
pp. 117-151
The ionomer coating structure on the catalyst surface critically determines the performance
and durability of proton exchange membrane fuel cell (PEMFC) electrodes. Conventional
fabrication often yields non‑uniform overlayers, increasing oxygen transport resistance,
blocking active sites, and accelerating interfacial degradation. Advancing from random
deposition to controlled coating structure is therefore a key objective. Ionomer adsorption
is governed by its intrinsic properties, support characteristics, and catalyst morphology.
In liquid environments, adsorption involves backbone hydrophobicity and side‑chain
chemical bonding, with the latter dominating the final configuration. Solvent composition,
particularly water content, modulates dispersion, and adsorption behavior. Optimization
strategies focus on two main approaches: suppressing detrimental adsorption (e.g.,
by tailoring support porosity or using additives like ionic liquids) and constructing
favorable mass‑transport pathways (e.g., by designing ionomers with cyclic/porous
structures or engineering porous overlayers). Rational design of ionomer properties,
interface regulation, and integration of these strategies can synergistically enhance
proton conduction, mass transport, and stability, laying a foundation for high‑performance,
durable fuel cell electrodes.
DOI: 10.23919/CHAIN.2026.000012 Cited: 0 Download: 23
