Research on Preparation of TiC Powders by Molten Salt Electrolysis AITranslate
Abstract AITranslate
The cathode was synthesized with TiO2, CaO and C as raw materials,and then TiC powders were prepared by electrolysis in CaCl2-NaCl mixed molten salt. The resultant cathode and its electrolytic product were characterized by SEM, EDX and XRD. The results show that under 1 300℃ sintering temperature and 2 h sintering duration,CaTiO3-C compound with favorable electrical conductivity and strength can be obtained to meet the requirement of molten salt electrolysis for cathode. With the resultant compound as cathode,TiC powders with irregular spheroidal distribution and uniform particle sizes can be obtained by molten salt electrolysis.
KeyWords AITranslate
1李奎,潘复生,汤爱涛.TiC、TiN、Ti(C、N)粉末制备技术的现状及发展[J].重庆大学学报:自然科学版,2002,25(6):135-138. 被引量:28
2Koc R. Kinetics and phase evolution during carbothermaI synthesis of titanium carbide from ultrafine titania/car hon mixture[J]. Journal o{ Materials Science, 1998,33 (4) : 1 049-1 055.
3陈怡元,邹正光,龙飞.碳源对自蔓延高温合成TiC粉末的影响[J].桂林工学院学报,2006,26(4):534-537. 被引量:9
4Haiverson D C,Ewald K H,Munir Z A. Influence of re actant characteristics on the microstructures of combus tion synthesized titanium carbide[J]. Journal of Materi als Science,1993,28(17) :4 583- 4 594.
5Ali M,Basu P. Mechanochemical synthesis of nanostruc- tured titanium carbide from industrial Fe-Ti[J]. Journal o{ Alloys and Compounds, 2010,491(1-2) : 581-583.
6Lee D W, Alexandroyskii S, Kim B K. Mg-thermal redu- ction of TIC14-I-C, C14 solution {or producing ultra{ine ti tanium carbide[J]. Materials Chemistry and Physics, 2004,88(1) :23-26.
7黎茂祥,苏国钧.溶胶-凝胶和碳热还原法制备碳化钛的研究[J].无机盐工业,2007,39(7):36-38. 被引量:8
8Claen (; Z, Fray D J, Farthing T W. Direct electrochem- ical reduction of titanium dioxide to titanium in molten calcium chloride-J]. Nature, 2000,407 : 361-364.
9Hyslop D J S, Abdelkader A M, Cox A, et al. Electroch emical synthesis of a biomedically important Co-Cr alloy [J]. Acta Materialia,2010,58(8) :3 124 3 130.
10Song Q S, Xu Q,Kang X, et al. Mechanistic insight of electrochemical reduction of Taz 0:> to tantalum in a eu tectie CaCI2 NaCI molten salt[J]. Journal of Alloys andCompounds,2010,490(1-2):241-246.
1白鑫涛,王锦霞,谢宏伟,崔富辉,翟玉春.非传统TiC合成研究进展[J].有色金属科学与工程,2015,6(1):59-65. 被引量:2
2朱靖,戴磊,曹吉林,王岭.熔盐电脱氧法制备金属间化合物研究进展[J].稀有金属与硬质合金,2016,0(3):61-66.
3田亚斌,黄晶明,叶昌美,董泉,王昭文,杨少华.NaCl-KCl-K2TiF6熔盐Ti4+在钨电极上的电化学还原机制[J].稀有金属,2020,44(9):941-948. 被引量:4
4王珍,凌永一,王子昊,张婧,贾全利,刘新红.熔盐辅助法制备碳化钛材料的研究进展[J].工程科学学报,2021,43(1):97-107. 被引量:2
5彭爽,陈朝轶,王仕愈,白杨,李天培,顾炜.氯化钙熔盐中电解-刻蚀制备碳化钛衍生碳研究[J].无机盐工业,2023,55(3):78-83.
1李亮星,朱志城,贾孟熹,黄茜琳.硬质合金废料电解回收钨及W(Ⅵ)在熔盐中的电化学行为[J].材料导报,2022,36(S01):448-453.
2杜军,杨吉哲,王尧.Zr/C纳米自蔓延反应薄膜制备及表征[J].表面技术,2016,45(8):98-102. 被引量:1
3刘文扬,张建波,陈婷婷,胡美俊.MAX/金属基自润滑复合材料摩擦学研究[J].有色金属科学与工程,2017,8(4):61-67. 被引量:3
4黄晶明,田亚斌,张晓虎,叶昌美,杨少华.NaF-KF-K2TaF7熔盐Ta(V)在钨电极上的电化学还原机理[J].功能材料,2020,51(5):5097-5102.
5张晨阳,潘昆明,徐流杰,周玉成,李秀青,张桥保.高温金属结构材料单晶制备及其研究进展[J].稀有金属,2021,45(5):541-550. 被引量:3
6田方,胡途,张利波,杨黎.TiC的制备方法及应用研究进展[J].功能材料,2022,53(10):10046-10053.
7程登峰,柯昌明,张锦化,王景然.碳/氮化物陶瓷粉体的熔盐法合成研究进展[J].中国陶瓷,2023,59(1):1-12.
8汤帅,胡宪伟,于江玉,刘爱民,石忠宁,王兆文,纪武仁.氧化对熔融NaCl-KCl-K_(2)TiF_(6)体系离子结构的影响[J].中国有色金属学报,2023,33(2):590-597.
1李勇辉,明大增,李志祥,王智娟,杜璐杉.以二氧化硅为硅源制备纯硅的方法[J].化工生产与技术,2010,17(6):35-38. 被引量:5
2陈怡元,邹正光,龙飞.碳源对自蔓延高温合成TiC粉末的影响[J].桂林工学院学报,2006,26(4):534-537. 被引量:9
3胡继林,刘鑫,胡传跃,郭文明.TiC制备技术及其增强SiC基复合材料的研究进展[J].中国陶瓷,2013,49(12):1-5. 被引量:5
4王为民,傅正义,王皓.自蔓延高温合成TiC特种陶瓷[J].陶瓷,1995(1):40-42. 被引量:1
5耿天发.影响熔盐电解法制备同位素硼—10粉收率主要因素的探讨[J].丹东化工,1991(1):21-22.
6朱心昆,赵昆渝,程抱昌,林秋实,张修庆,陈铁力,苏云生,雍歧龙.在不同球磨机上合成TiC粉末的研究[J].昆明理工大学学报:理工版,2000,25(6):57-59. 被引量:3
7向道平,李元元.碳热还原合成TiC粉末及相演变[J].材料导报,2009,23(12):106-108. 被引量:3
8刘继富,李建保,王厚亮.原位选择性碳化法制备ZrO_2-TiC粉末[J].硅酸盐学报,1999,27(3):342-345. 被引量:1
9于仁红,史晓琪,蒋明学.TiO_2碳热还原氮化反应的热力学分析[J].耐火材料,2005,39(6):460-462. 被引量:7
10梁宝岩,张旺玺,王艳芝,徐世帅.自蔓延高温合成Ti_2SnC材料研究[J].稀有金属与硬质合金,2015,43(4):43-46. 被引量:1
Basic Information:
DOI:
Chinese Library Classification Number:TQ134.11[化学工程—无机化工]
Citation Information:
The cathode was synthesized with TiO2, CaO and C as raw materials,and then TiC powders were prepared by electrolysis in CaCl2-NaCl mixed molten salt. The resultant cathode and its electrolytic product were characterized by SEM, EDX and XRD. The results show that under 1 300℃ sintering temperature and 2 h sintering duration,CaTiO3-C compound with favorable electrical conductivity and strength can be obtained to meet the requirement of molten salt electrolysis for cathode. With the resultant compound as cathode,TiC powders with irregular spheroidal distribution and uniform particle sizes can be obtained by molten salt electrolysis.
quote
| GB/T 7714-2015 | [1] LANG Xiao-chuan, XIE Hong-wei, DI Yu-chun, et al. Research on Preparation of TiC Powders by Molten Salt Electrolysis[J]. Rare Metals and Cemented Carbides, 2013(5): 1-4. |
| MLA | [1] LANG Xiao-chuan, et al., "Research on Preparation of TiC Powders by Molten Salt Electrolysis." Rare Metals and Cemented Carbides, no. 5, 2013, pp. 1-4. |
| APA | [1] LANG Xiao-chuan, XIE Hong-wei, DI Yu-chun, & ZOU Xiang-yu. (2013). Research on Preparation of TiC Powders by Molten Salt Electrolysis. Rare Metals and Cemented Carbides(5), 1-4. |
| IEEE | [1] LANG Xiao-chuan, XIE Hong-wei, DI Yu-chun, and ZOU Xiang-yu, "Research on Preparation of TiC Powders by Molten Salt Electrolysis," Rare Metals and Cemented Carbides, no. 5, pp. 1-4, 2013. keywords: {TiC powder;molten salt electrolysis;CaTiO3-C;cathode;electrical conductivity;strength} |
