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Experimental Study on Extraction of Gallium from Sulfuric Acid Leaching Solution of Coal Gangue by Using P507 AITranslate

School of Chemistry and Chemical Engineering,Henan Polytechnic University;School of Chemistry and Chemical Engineering,Henan Polytechnic University;School of Chemistry and Chemical Engineering,Henan Polytechnic University;School of Chemistry and Chemical Engineering,Henan Polytechnic University;School of Chemistry and Chemical Engineering,Henan Polytechnic University
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Publisher: Editorial Office of Rare Metals and Cemented Carbides
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Abstract AITranslate

Gallium and iron from sulfuric acid leaching solution of coal gangue were separated by extraction with 2-ethylhexyl phosphate mono-2-ethylhexyl ester(P507).The effects of solution pH value,P507 concentration,oscillation time,oscillation intensity and extraction temperature on the extraction efficiency of gallium and iron were investigated.The results show that the single-stage extraction rate of Ga3+reaches 82%while that of Fe2+is lower than 18%,under the conditions of A/O ratio of 1:1,P507 concentration of 20%,solution pH value of 1.5,oscillation time of 15 min,oscillation intensity of 200 r/min and extraction temperature of 35℃.The extraction experiments were performed by changing the A/O ratio,and then the equilibrium isotherm of gallium extraction was determined.Under the condition of 4:1 A/O ratio,the theoretical extraction stage of gallium is four,and the extraction rate of gallium is 98.4%while the extraction rate of iron is 17.4%,and the extraction rate of other metal ions is less than 10%.Therefore,the selective extraction of gallium from sulfuric acid leaching solution of coal gangue could be realized.

KeyWords AITranslate

gallium extraction P507 coal gangue leaching solution iron

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DOI:

Chinese Library Classification Number:TF843.1[冶金工程—有色金属冶金]

Citation Information:

Gallium and iron from sulfuric acid leaching solution of coal gangue were separated by extraction with 2-ethylhexyl phosphate mono-2-ethylhexyl ester(P507).The effects of solution pH value,P507 concentration,oscillation time,oscillation intensity and extraction temperature on the extraction efficiency of gallium and iron were investigated.The results show that the single-stage extraction rate of Ga3+reaches 82%while that of Fe2+is lower than 18%,under the conditions of A/O ratio of 1:1,P507 concentration of 20%,solution pH value of 1.5,oscillation time of 15 min,oscillation intensity of 200 r/min and extraction temperature of 35℃.The extraction experiments were performed by changing the A/O ratio,and then the equilibrium isotherm of gallium extraction was determined.Under the condition of 4:1 A/O ratio,the theoretical extraction stage of gallium is four,and the extraction rate of gallium is 98.4%while the extraction rate of iron is 17.4%,and the extraction rate of other metal ions is less than 10%.Therefore,the selective extraction of gallium from sulfuric acid leaching solution of coal gangue could be realized.

quote

GB/T 7714-2015 [1] GUO Wen-chao, LI Wang, ZHU Xiao-bo, et al. Experimental Study on Extraction of Gallium from Sulfuric Acid Leaching Solution of Coal Gangue by Using P507[J]. Rare Metals and Cemented Carbides, 2022(4): 28-32.
MLA [1] GUO Wen-chao, et al., "Experimental Study on Extraction of Gallium from Sulfuric Acid Leaching Solution of Coal Gangue by Using P507." Rare Metals and Cemented Carbides, no. 4, 2022, pp. 28-32.
APA [1] GUO Wen-chao, LI Wang, ZHU Xiao-bo, ZHANG Zhi-guo, & ZHANG Chuan-xiang. (2022). Experimental Study on Extraction of Gallium from Sulfuric Acid Leaching Solution of Coal Gangue by Using P507. Rare Metals and Cemented Carbides(4), 28-32.
IEEE [1] GUO Wen-chao, LI Wang, ZHU Xiao-bo, ZHANG Zhi-guo, and ZHANG Chuan-xiang, "Experimental Study on Extraction of Gallium from Sulfuric Acid Leaching Solution of Coal Gangue by Using P507," Rare Metals and Cemented Carbides, no. 4, pp. 28-32, 2022. keywords: {gallium;extraction;P507;coal gangue;leaching solution;iron}