Research Progress in Soil Remediation of Lead,Cadmium and Arsenic Pollution AITranslate
Abstract AITranslate
With the rapid development of industry,agriculture,mining and urbanization,a large number of heavy metals and other pollutants enter the soil environmental system,and the combined pollution of heavy metals in soil caused by this problem has attracted much attention. According to the 2014 National Soil Pollution Status Report,19.4% of China's arable land has exceeded the standard for heavy metal pollutants such as Pb,Cd and As,with the sites exceeding the standard for these three typical heavy metals ranking at the top,resulting in a polluted area of over 50 million acres. Soil heavy metal pollution is characterized by long-term persistence,durability,and difficulty in degradation. Through surface and subsurface runoff,it can be transferred from the soil to surrounding water bodies,exacerbating water heavy metal pollution. At the same time,heavy metals in land and water can be absorbed by crops,entering the food chain and accumulating in organisms,causing significant harm to human health. Pb has irreversible effects on the nervous system and children's intellectual development. Cd is a highly toxic heavy metal,long-term exposure to cadmium-contaminated environments may lead to diseases such as kidney damage,osteoporosis,and cancer. As is associated with health issues including cancer,skin diseases,and cardiovascular diseases. However,the coexistence of heavy metals such as Pb,Cd and As in soil in composite pollution poses greater environmental hazards compared to single pollution. Therefore,it is of great significance to comprehensively understand the current situation,characteristics,and remediation technologies of heavy metal composite pollution for the prevention and control of heavy metal pollution and the safe utilization of soil. This review provides a comprehensive overview of the current status,sources of pollution,and distribution and migration characteristics of Pb,Cd and As in soils affected by composite pollution. It particularly emphasized the impact of soil pH,redox potential (Eh),soil organic matter (SOM) and soil types on the migration and transformation of Pb,Cd and As. The study presented a summary of the research progress in the remediation of Pb,Cd and As composite pollution using physical remediation methods,solidification/stabilization techniques,and bioremediation approaches. It discussed the advantages,disadvantages,and applicability of various soil remediation technologies and provides an outlook on future development directions. Specifically,the ex-situ soil washing method had a fast remediation rate but was expensive,easily disrupts soil structure,and might cause secondary pollution. The electrokinetic remediation method had simple equipment operation but was relatively costly,consumed a significant amount of energy,and might pose safety hazards. The bioremediation method could improve soil quality and maintain ecological balance but had a slow remediation process and is highly influenced by the environment. The solidification/stabilization techniques had become the mainstream technology for the remediation of composite pollution in soils due to their high efficiency,low cost,and easy implementation. Furthermore,due to the pressing demand for the large-scale disposal of metal mine wastes in China,the research on developing new solidification/stabilization materials utilizing local mining solid wastes for the remediation of Pb,Cd and As composite polluted soils would become a key focus in the field of solidification/stabilization technologies.
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[1]陈世宝,王萌,李杉杉,郑涵,雷小琴,孙晓艺,王立夫. 中国农田土壤重金属污染防治现状与问题思考[J].地学前缘,2019,26(6):35.
S B Chen,M Wang,S S Li,H Zheng,X Q Lei,X Y Sun,L F Wang. Current situation and problems in the prevention and control of heavy metal pollution in farmland soil in China [J]. Frontiers of Geoscience,2019,26(6):35.
[2]Zhao F J,Ma Y,Zhu Y G,Tang Z,McGrath S P. Soil contamination in China:current status and mitigation strategies[J].Environmental Science & Tamechnology,2015,49(2):750.
[3]王慧芳,李辕成,杨雪,吕东蓬. 土壤重金属污染现状及修复技术研究[J].种子科技,2021,39(20):81.
H F Wang,Y C Li,X Yang,D P Lv. Research on the current situation and remediation technology of soil heavy metal pollution [J]. Seed Technology,2021,39(20):81.
[4]邹明英,苑蓉,张宇,章宝成. 不同土地利用方式下土壤重金属污染修复技术研究[J].环境科学与管理,2015,40(2):160.
M Y Zou,R Yuan,Y Zhang,B C Zhang. Research on remediation techniques for soil heavy metal pollution under different land use methods [J]. Environmental Science and Management,2015,40(2):160.
[5]Shi C J,Krivenko P,Roy D. Alkali-Activated Cements and Concretes [M]. London:Taylor & Francis,2006. 90.
[6]Xu D M,Fu R B,Liu H Q,Guo X P. Current knowledge from heavy metal pollution in Chinese smelter contaminated soils,health risk implications and associated remediation progress in recent decades:a critical review[J].Journal of Cleaner Production,2021,286:124989.
[7]余远翠.烂泥沟金矿露天采坑分区生态修复与植被重建工程实践 [J].黄金,2023,44(11):93.
Y C Yu. Engineering practice of ecological restoration and vegetation reconstruction in open-pit mining pits of Lannigou Gold Mine[J].Gold,2023,44(11):93.
[8]Xin X P,Shentu J L,Zhang T Q,Yang X E,Baligar V C,He Z L. Sources,Indicators,and Assessment of Soil Contamination by Potentially Toxic Metals[J]. Sustainability,2022,14(23):15878.
[9]Shaji E,Santosh M,Sarath K U,Prakash P,Deepchand V,Divya B V.Arsenic contamination of groundwater:a global synopsis with focus on the Indian Peninsula[J].Geoscience Frontiers,2020,12(3):101079.
[10]Hou D,O’Connor D,Igalavithana A D,Alessi D S,Luo J,Tsang D C,Ok Y S. Metal contamination and bioremediation of agricultural soils for food safety and sustainability[J].Nature Reviews Earth & Environment,2020,1(7):366.
[11]Kumar V,Sharma A,Kaur P,Sidhu G P S,Bali A S,Bhardwaj R,Cerda A. Pollution assessment of heavy metals in soils of India and ecological risk assessment:a state-of-the-art[J].Chemosphere,2019,216:449.
[12]Shi J D,Zhao D,Ren F T,Huang L. Spatiotemporal variation of soil heavy metals in China:the pollution status and risk assessment[J].Science of The Total Environment,2023,871:161768.
[13]Wu Q Y,Zhang X L,Liu C H,Chen Z. The de-industrialization,re-suburbanization and health risks of brownfield land reuse:case study of a toxic soil event in Changzhou,China[J].Land Use Policy,2018,74:187.
[14]佟亚欧,金兰淑,土壤铅污染现状及钝化修复技术探讨[J]. 农业科技与装备,2010,6:31).
Y O Tong,L S Jin,Exploration of soil lead pollution status and passivation remediation technology [J].Agricultural Science and Technology and Equipment,2010,6:31.
[15]杜瑞英,聂呈荣,林初夏,刘勇. 镉污染土壤对潜在能源植物生长的影响[J].生态环境,2006,(4):735.
R Y Du,C R Nie,C X Lin,Y Liu. The impact of cadmium contaminated soil on the growth of potential energy plants [J]. Ecological Environment,2006,(4):735.
[16]刘应忠,胡从亮,袁义生,张美雪,罗明学. 黔西南地区土壤中镉的地球化学分级和污染修复建议[J].贵州地质,2007,(3):219.
Y Z Liu,C L Hu,Y S Yuan,M X Zhang,M X Luo. Geochemical classification and pollution remediation suggestions for cadmium in soil in southwestern Guizhou region[J]. Guizhou Geology,2007,(3):219.
[17]李典友,陆亦农,土壤中砷污染的危害和防治对策研究[J]. 新疆师范大学学报:自然科学版,2005,24(4):89.
D Y Li,Y N Lu. Research on the hazards and prevention strategies of arsenic pollution in soil[J].Journal of Xinjiang Normal University:Natural Science Edition,2005,24(4):89.
[18]仇荣亮,仇浩,雷梅,叶志鸿. 矿山及周边地区多金属污染土壤修复研究进展[J].农业环境科学学报,2009,28(6):1085.
R L Qiu,H Qiu,M Lei,Z H Ye. Research progress on remediation of soil contaminated with multiple metals in mines and surrounding areas [J]. Journal of Agricultural Environmental Science,2009,28(6):1085.
[19]丁丹阳,李天恩,赵荣艳,贾东方,张栋栋.金精矿综合回收铅锌工艺试验研究[J].黄金,2023,44(11):48.
D Y Ding,T E Li,R Y Zhao,D F Jia,D D Zhang. Experimental study on the process of comprehensive recovery of lead and zinc from gold concentrates[J].Gold,2023,44(11):48.
[20]曹心德,魏晓欣,代革联,杨永亮. 土壤重金属复合污染及其化学钝化修复技术研究进展[J].环境工程学报,2011,5(7):1441.
X D Cao,X X Wei,G L Dai,Y L Yang. Research progress on soil heavy metal composite pollution and its chemical passivation remediation technology [J]. Journal of Environmental Engineering,2011,5(7):1441.
[21]Acosta J A,Faz A,Martínez-Martínez S,Zornoza R,Carmona D M,Kabas S. Multivariate statistical and GIS-based approach to evaluate heavy metals behavior in mine sites for future reclamation [J]. Journal of Geochemical Exploration,2011,109:8.
[22]Wang C C,Zhang Q C,Yan C A,Tang G Y,Zhang M Y,Bao Y B,Xiang P. Heavy metal(loid)s in agriculture soils,rice,and wheat across China:status assessment and spatiotemporal analysis[J].Science of The Total Environment,2023. doi: https://doi.org/10.1016/j.scitotenv.2023.163361.
[23]雷 鸣,曾 敏,郑袁明,廖柏寒,朱永官. 湖南采矿区和冶炼区水稻土重金属污染及其潜在风险评价[J].环境科学学报,2008,(6):1212.
M Lei,M Zeng,Y M Zheng,B H Liao,Y G Zhu. Heavy metal pollution and potential risk assessment of paddy soil in mining and smelting areas of Hunan Province[J]Journal of Environmental Science,2008,(6):1212.
[24]郭朝晖,朱永官.典型矿冶周边地区土重金属污染及有效性含量[J].生态环境,2004,13(4):553.
C H Guo,Y G Zhu. Soil heavy metal pollution and effective content gate in typical mining and metallurgical surrounding areas[J].Ecological Environment,2004,13(4):553.
[25]高晓宁,土壤重金属污染现状及修复技术研究进展[J].现代农业科技,2013,9:229.
X N Gao. Current situation of soil heavy metal pollution and research progress in remediation technology[J].Modern Agricultural Science and Technology,2013,9:229.
[26]李波,林玉锁,张孝飞,徐亦钢,俞飞. 沪宁高速公路两侧土壤和小麦重金属污染状况[J].农村生态环境,2005,(3):50.
B Li,Y S Lin,X F Zhang,Y G Xu,F Yu. Heavy metal pollution status of soil and wheat on both sides of the Shanghai Nanjing Expressway[J].Rural Ecological Environment,2005,(3):50.
[27]龚航远. 掺铁羟基磷灰石对土壤铅镉砷复合污染稳定化修复研究[D]. 长沙:中南大学,2022. 1.
H Y Gong. A Study on the Stabilization and Remediation of Soil Lead,Cadmium,and Arsenic Composite Pollution by Iron Doped Hydroxyapatite[D]. Changsha:Central South University,2022. 1.
[28]张小敏,张秀英,钟太洋,江洪. 中国农田土壤重金属富集状况及其空间分布研究[J].环境科学,2014,35:692.
X M Zhang,X Y Zhang,T Y Zhong,H J. Research on the enrichment status and spatial distribution of heavy metals in farmland soils in China[J]. Environmental Science,2014,35:692.
[29]Luis R L,Guifan S,Michael B,Qiang Z,Hanbin X,Quanmei Z,Annette C, Groundwater arsenic contamination throughout China [J]. Science,2013,341:866.
[30]Duan Q N,Lee J C,Liu Y C,Chen H,Hu H Y. Distribution of heavy metal pollution in surface soil samples in China:a graphical review[J].Bulletin of Environmental Contamination and Toxicology,2016,97:303.
[31]Shao D W,Zhan Y,Zhou W J,Zhu L Z. Current status and temporal trend of heavy metals in farmland soil of the Yangtze River Delta Region:field survey and meta-analysis[J].Environmental Pollution,2016,219:329.
[32]王颜昊,刘增辉,柳新伟,宋祥云,崔德杰. 黄河三角洲表层土壤重金属空间分布与潜在生态风险评价[J].水土保持学报,2019,33(3):305.
Y H Wang,Z H Liu,X W Liu,X Y Song,D J Cui. Spatial distribution and potential ecological risk assessment of heavy metals in surface soil of the Yellow River Delta[J].Journal of Soil and Water Conservation,2019,33(3):305.
[33]孟敏,杨林生,韦炳干,李海蓉,虞江萍. 我国设施农田土壤重金属污染评价与空间分布特征[J].生态与农村环境学报,2018,34:1019.
M Meng,L S Yang,B G Wei,H R Li,J P Yu. Evaluation and spatial distribution characteristics of heavy metal pollution in soil of facility farmland in China[J].Journal of Ecology and Rural Environment,2018,34:1019.
[34]Jiang Z,Nie K,Arinzechi C,Li J X,Liao Q,Si M Y,Yang Z H,Li Q Z,Yang W C. Cooperative effect of slow-release ferrous and phosphate for simultaneous stabilization of As,Cd and Pb in soil[J].Journal of Hazardous Materials,2023,452:131232.
[35]Cipullo S,Snapir B,Tardif S,Campo P,Prpich G,Coulon F. Insights into mixed contaminants interactions and its implication for heavy metals and metalloids mobility,bioavailability and risk assessment[J].Science of the Total Environment,2018,645:662.
[36]Liu G N,Xue W,Tao L,Liu X H,Hou J,Wilton M,Gao D,Wang A J,Li R P. Vertical distribution and mobility of heavy metals in agricultural soils along Jishui River affected by mining in Jiangxi Province,China[J].CLEAN–Soil,Air,Water,2014,42(10):1450.
[37]Bissen M,Frimmel F H. Arsenic—a review. Part I:occurrence,toxicity,speciation,mobility[J].Acta Hydrochim. Et Hydrobiol,2003,31:9.
[38]Xu W. Arsenic release from arsenic-bearing Fe–Mn binary oxide:effects of Eh condition[J].Chemosphere,2011,83(7):1020.
[39]Goldberg S. Competitive adsorption of arsenate and arsenite on oxides and clay minerals[J].Soil Sci. Soc. Am. J.,2002,66:413.
[40]Vítková M,Rákosová S,Michálková Z,Komárek M. Metal(loid)s behaviour in soils amended with nano zero-valent iron as a function of pH and time[J].Journal of Environmental Management,2017,186:268.
[41]Pigna M,Caporale A G,Cavalca L,Sommella A,Violante A. Arsenic in the soil environment:mobility and phytoavailability[J].Environmental Engineering Science,2015,32(7):551.
[42]Grybos M,Davranche M,Gruau G,Petitjean P. Is trace metal release in wetland soils controlled by organic matter mobility or Fe-oxyhydroxides reduction?[J].Journal of Colloid and Interface Science,2007,314(2):490.
[43]Sungur A,Soylak M,Ozcan H. Investigation of heavy metal mobility and availability by the BCR sequential extraction procedure:relationship between soil properties and heavy metals availability[J].Chemical Speciation & Bioavailability,2014,26(4):219.
[44]Violante A,Cozzolino V,Perelomov L,Caporale A G,Pigna M U D N. Mobility and bioavailability of heavy metals and metalloids in soil environments[J].Journal of Soil Science and Plant Nutrition,2010,10(3):268.
[45]Sherene T. Mobility and transport of heavy metals in polluted soil environment[J].Biological Forum—An International Journal,2010,2(2):112.
[46]Olesen T,Moldrup P,Gamst J. Solute diffusion and adsorption in six soils along a soil texture gradient[J].Soil Science Society of America Journal,1999,63(3):519.
[47]陈维伟,何誉文,褚冯键,韦玮,何佺,王文海,冯鸿儒,潘远江. 含非挥发性盐样品的质谱分析技术进展[J].分析试验室,2023,42(5):696.
W W Chen,Y W He,F J C,W Wei,Q He,W H Wang,H R Feng,Y J Pan. Research progress in mass spectrometry analysis for samples containing non-volatile salts[J].Chinese Journal of Analysis Laboratory,2023,42(5):696.
[48]Esfandbod M,Forghani A,Adhami E,Rashti M R. The role of CEC and pH in Cd retention from soils of North of Iran[J].Soil and Sediment Contamination:An International Journal,2011,20(8):908.
[49]Caporale A G,Violante A. Chemical processes affecting the mobility of heavy metals and metalloids in soil environments[J].Current Pollution Reports,2016,2:15.
[50]Courtin-Nomade A,Waltzing T,Evrard C,Soubrand M,Lenain J F,Ducloux E,Bril H. Arsenic and lead mobility:from tailing materials to the aqueous compartment[J].Applied Geochemistry,2016,64:10.
[51]Nguyen T C,Loganathan P,Nguyen T V,Vigneswaran S,Kandasamy J,Naidu, R. Simultaneous adsorption of Cd,Cr,Cu,Pb,and Zn by an iron-coated Australian zeolite in batch and fixed-bed column studies[J].Chemical Engineering Journal,2015,270:393.
[52]路润峰,冯娟,鱼甜甜,王亚娇,杨春,黄嘉瑞. 镉污染土壤修复技术的研究进展[J].农业与技术,2023,43(8):52.
R F Lu,J Feng,T T Yu,Y J Wang,C Yang,J R Huang. Research progress on cadmium contaminated soil remediation technology [J]. Agriculture and Technology,2023,43(8):52.
[53]刘宇娟,陈建华,陈姣,周建良,彭宗良.废弃铁合金厂土壤重金属污染修复效果评估[J].绿色科技,2022,24(4):4.
Y J Liu,J H Chen,J Chen,J L Zhou,Z L Peng. Evaluation of soil pollution remediation effect of an abandoned ferroalloy factory in Hunan Province[J].Journal of Green Science and Technology,2022,24(4):4.
[54]阮敏,周康,黄忠良,李辉,张轩,吴子剑,覃晓莉,吴希锴,黄兢.铅锌矿区废弃 地修复客土层的重金属污染特征分析[J].环境科学学报,2021,41(9):3803.
M Ruan,K Zhou,Z L Huang,H Li,X Zhang,Z J Wu,X L Qin,X K Wu,J Huang. Analysis of heavy metal pollution characteristics of guest soil after restoration of abandoned lead-zinc mine area[J].Acta Scientiae Circumstantiae,2021,41(9):3803.
[55]Probstein R F,Hicks R E. Removal of contaminants from soils by electric fields[J].Science,1993,260(5107):498.
[56]Sun Z Y,Zhao M M,Chen L,Gong Z Y,Hu J J,Ma D G. Electrokinetic remediation for the removal of heavy metals in soil:limitations,solutions and prospection[J].Science of The Total Environment,2023. doi:10.1016/j.scitotenv.2023.165970.
[57]Yuan S H,Zheng Z H,Chen J,Lu X. Use of solar cell in electrokinetic remediation of cadmium-contaminated soil[J]. Journal of Hazardous Materials,2009,162(2–3):1583.
[58]肖惠萍,孙书琴,刘洋,李芳芳,赵先. 电动修复红壤镉污染的正交试验研究[J].工业安全与环保,2020,46(9):79.
H P Xiao,S Q Sun,Y Liu,F F Li,X Zhao. Orthogonal experimental study on electric remediation of cadmium pollution in red soil [J]. Industrial Safety and Environmental Protection,2020,46(9):79.
[59]胡宏韬,程金平. 土壤铜镉污染的电动力学修复实验[J].生态环境学报,2009,(2):511.
H T Hu,J P Cheng. Electrodynamic remediation experiment of soil copper and cadmium pollution[J]. Journal of Ecology and Environment,2009,(2):511.
[60]曹锐,王悦,陈爽,郑灵韵,徐莉,周际海,李辉信,胡锋. 镉砷复合污染水稻土原位钝化修复技术研究进展[J].土壤学报,2023,60(3):657.
R Cao,Y Wang,S Chen,L Y Zheng,L Xu,J H Zhou,H X Li,F Hu. Research progress on in-situ passivation remediation technology for cadmium arsenic compound polluted paddy soil [J]. Journal of Soil Science,2023,60(3):657.
[61]Malvyer R,Chaudhary R. Leaching behavior and immobilization of heavy metals in solidified/stabilized products[J].Journal of Hazardous Materials,2006,137:207.
[62]Paria S,Yuet P K. Solidification stabilization of organic and inorganic contaminants using port land cement:a literature review[J].Environmental Reviews,2006,14(4):217.
[63]Kogbara R B,Al-Tabba A. Mechanical and leaching behaviour of slag cement and lime-activated slag stabilised/solidified contaminated soil[J].Science of the total environment,2011,409(11):2325.
[64]Li J S,Xue Q,Wang P,Zhang T T,Zhao Y. Comparison of solidification/stabilization of lead contaminated soil between magnesia-phosphate cement and ordinary portland cement under the same dosage[J].Environmental Progress and Sustainable Energy,2015,35(1):88.
[65]Wang L,Zhang Y Y,Chen L,Guo B L,Tan Y S,Sasaki K,Tsang D C W. Designing novel magnesium oxysulfate cement for stabilization/solidification of municipal solid waste incineration fly ash[J].Journal of Hazardous Materials,2022,423:127025.
[66]Lombi E,Hamon R E,Mcgrath S P. Lability of Cd,Cu,and Zn in polluted soils treated with lime,beringite,and red mud and identification of a non-labile colloidal fraction of metals using is topic techniques[J].Environmental Scienceand Technology,2003,37(5):979.
[67]闫淑兰,赵秀红,罗启仕. 基于文献计量的重金属固化稳定化修复技术发展动态研究[J].农业环境科学学报,2020,39(2):229.
S L Yan,X H Zhao,Q S Luo. Research on the development dynamics of heavy metal solidification and stabilization remediation technology based on bibliometric methods[J].Journal of Agricultural Environmental Science,2020,39(2):229.
[68]郝汉舟,陈同斌,靳孟贵,雷梅,刘成武,祖文普,黄莉敏. 重金属污染土壤稳定/固化修复技术研究进展[J].应用生态学报,2011,22(3):816.
H Z Hao,T B Chen,M G Jin,M Lei,C W Liu,W P Zu,L M Huang. Research progress on stabilization/solidification remediation technology for heavy metal contaminated soil [J]. Journal of Applied Ecology,2011,22(3):816.
[69]张向军,王里奥.石灰、粉煤灰处理铅镉污染土壤的试验研究 [J].环境科技,2009,22(2):1.
X J Zhang,L A Wang. Experimental study on the treatment of lead and cadmium contaminated soil with lime and fly ash[J].Environmental Science and Technology,2009,22(2):1.
[70]郝双龙,丁园,余小芬,何春林,史蓉蓉. 粉煤灰和石灰对突发性污染土壤中重金属化学形态的影响[J].广东农业科学,2012,39(3):55.
S L Hao,Y Ding,X F Yu,C L He,R R Shi. The effects of fly ash and lime on the chemical forms of heavy metals in suddenly polluted soil [J]. Guangdong Agricultural Science,2012,39(3):55.
[71]刘玉林,刘长淼,刘红召,赵毅,谭琦. 我国矿山尾矿利用技术及开发利用建议[J].矿产保护与利用,2018,(6):140.
Y L Liu,C M Liu,H Z Liu,Y Zhao,Q Tan. Technology and development suggestions for the utilization of mining tailings in China [J]. Mineral Protection and Utilization,2018,(6):140.
[72]张晓刚,宋少民,刘枫,刘娟红,吴瑞东. 矿山废石制备砂石骨料的现状研究综述[J].粉煤灰综合利用,2023,37(6):55.
X G Zhang,S M Song,F Liu,J H Liu,R D Wu. A review of the current research on the preparation of sand and gravel aggregates from mining waste rock [J].Comprehensive Utilization of Fly Ash,2023,37(6):55.
[73]Ba H J,Li J J,Ni W,Li Y,Ju Y J,Zhao B,Wen G P,Hitch M. Effect of calcium to silicon ratio on the microstructure of hydrated calcium silicate gels prepared under medium alkalinity[J].Construction and Building Materials,2023,379:131240.
[74]鄢琪慧,倪文,高巍,李云云,张钰莹.矿渣-钢渣基胶凝材料固化某含砷尾砂试验[J].金属矿山,2018,(11):189.
Q H Yan,W Ni,W Gao,Y Y Li,Y Y Zhang. Experimental study on solidification of arsenic containing tailings using slag steel slag based cementitious materials[J].Metal Mining,2018,(11):189.
[75]阎爱云,倪文,黄晓燕,高赫,李文秀,任超.矿渣-钢渣基胶结剂固化—稳定化含铅尾砂[J].金属矿山,2016,(8):180.
A Y Yan,W Ni,X Y Huang,H Gao,W X Li,C Ren. Solidification and stabilization of lead containing tailings using slag steel slag based binders[J].Metal Mining,2016,(8):180.
[76]王珂,倪文,张思奇,李德忠,耿碧瑶,杜惠惠.垃圾焚烧飞灰-矿渣基胶凝体系及固镉研究[J].有色金属工程,2018,8(5):119.
K Wang,W Ni,S Q Zhang,D Z Li,B Y Geng,H H Du. Research on the cementitious system of waste incineration fly ash slag and cadmium fixation[J].Nonferrous Metals Engineering,2018,8(5):119.
[77]Mu J,Hu Z Y,Huang L J,Xie Z J,Holm P E. Preparation of a silicon-iron amend-ment from acid-extracted copper tailings for remediating multi-metal contaminated soils[J].Environmental Pollution,2020,257:113565.
[78]Lei M,Tang L,Du H H,Peng L,Tie B Q,Williams P N,Sun G X. Safety assessment and application of iron and manganese ore tailings for the remediation of As-contaminated soil[J].Process Safety and Environmental Protection,2019,125:334.
[79]张存仁,杨建康,李新,衡光普. 矿山剥离废石在水泥生产中的综合利用[J].中国水泥,2017,(4):122.
C R Zhang,J K Yang,X Li,G P Heng. The comprehensive utilization of mining stripped waste rock in cement production[J].China Cement,2017,(4):122.
[80]杨飞,孙晓敏. 利用钒钛磁铁矿尾矿制备普通硅酸盐水泥熟料的研究[J].钢铁钒钛,2020,41(2):75.
F Yang,X M Sun. Study on the preparation of ordinary Portland cement clinker using vanadium titanium magnetite tailings[J].Steel and Vanadium Titanium,2020,41(2):75.
[81]王超,宋卫锋,杨佐毅,钟永铿,孙梦格,白晓燕. 工业固废基地聚合物的制备及其吸附Pb(Ⅱ)的性能[J].环境科学学报,2021,41(7):2700.
C Wang,W F Song,Z Y Yang,Y K Zhong,M G Sun,X Y Bai. Preparation of industrial solid waste base polymers and their performance in adsorbing Pb(II)[J].Journal of Environmental Science,2021,41(7):2700.
[82]何荣兴,许雁超.非煤矿山固体废弃物综合利用存在问题及应对措施[J].当代化工研究,2023,(1):88.
R X He,Y C Xu. Problems and countermeasures for comprehensive utilization of solid waste in non-coal mines[J].Contemporary Chemical Research,2023,(1):88.
[83]Liang J,Fang Y L,Luo Y,Zeng G M,Deng J Q,Tan X F,Tang N,Li X M,He X Y,Feng C T,Ye S J. Magnetic nanoferromanganese oxides modified biochar derived from pine sawdust for adsorption of tetracycline hydrochloride[J]. Environmental Science and Pollution Research,2019,26:5892.
[84]王旌,罗启仕,张长波,谈亮,李旭. 铬污染土壤的稳定化处理及其长期稳定性研究[J].环境科学,2013,34(10):4036.
J Wang,Q S Luo,C B Zhang,L Tan,X Li. Research on the stabilization treatment and long-term stability of chromium contaminated soil[J].Environmental Science,2013,34(10):4036.
[85]费杨,阎秀兰,廖晓勇,林龙勇. 不同水分条件下铁基氧化物对土壤砷的稳定化效应研究[J].环境科学学报,2015,35(10):3252.
Y Fei,X L Yan,X Y Liao,L Y Lin. A study on the stabilization effect of iron-based oxides on soil arsenic under different water conditions[J]. Journal of Environmental Science,2015,35(10):3252.
[86]Guo S,Yang H F,Sun Q W,Zhang G,Zhao T,Zhou Y C,Li X,Gao P. Evaluation of a novel carbon-based micro-nano zero-valent iron composite for immobilization of heavy metals in soil[J].Journal of Environmental Chemical Engineering,2023,11(3):109740.
[87]Basta N T,Gradwohl R,Snethen K L,Schroder J L. Chemical immobilization of lead,zinc,and cadmium in smelter‐contaminated soils using biosolids and rock phosphate[J].Journal of Environmental Quality,2001,30(4):1222.
[88]梁媛,王晓春,曹心德. 基于磷酸盐、碳酸盐和硅酸盐材料化学钝化修复重金属污染土壤的研究进展[J].环境化学,2012,31(1):16.
Y Liang,X C Wang,X D Cao. Research progress on chemical passivation remediation of heavy metal contaminated soil based on phosphate,carbonate,and silicate materials[J]. Environmental Chemistry,2012,31(1):16.
[89]王碧玲,谢正苗,孙叶芳,李静,田兆君,陈英旭. 磷肥对铅锌矿污染土壤中铅毒的修复作用[J].环境科学学报,2005,(9):1189.
B L Wang,Z M Xie,Y F Sun,J Li,Z J Tian,Y X Chen. The remediation effect of phosphorus fertilizer on lead toxicity in lead zinc mine polluted soil[J].Journal of Environmental Science,2005,(9):1189.
[90]Wang B L,Xie Z M,Chen J J,Jiang J T,Su Q F. Effects of field application of phosphate fertilizers on the availability and uptake of lead,zinc and cadmium by cabbage (Brassica chinensis L.) in a mining tailing contaminated soil[J].Journal of Environmental Sciences,2008,20(9):1109.
[91]Hettiarachchi G M,Pierzynski G M,Ransom M D. In situ stabilization of soil lead using phosphorus[J].Journal of Environmental Quality,2001,30(4):1214.
[92]Yang Z H,Gong H Y,He F S,Repo E,Yang W C,Liao Q,Zhao F P. Iron-doped hydroxyapatite for the simultaneous remediation of lead-,cadmium-and arsenic-co-contaminated soil[J].Environmental Pollution,2022,312:119953.
[93]曹颖. 重金属污染土壤稳定化修复技术研究[J].化工管理,2022,(8):23.
Y Cao. Research on stable remediation technology for heavy metal contaminated soil[J].Chemical Management,2022,(8):23.
[94]许秀云,蔡玉曼. 改性沸石对重金属离子竞争吸附特性研究[J].地质学刊,2010,(1):92.
X Y Xu,Y M Cai. A study on the competitive adsorption characteristics of modified zeolite for heavy metal ions[J]. Journal of Geology,2010,(1):92.
[95]Wu J Z,Li Z T,Huang D,Liu X M,Tang C X,Parikh S J,Xu J M. A novel calcium-based magnetic biochar is effective in stabilization of arsenic and cadmium co-contamination in aerobic soils[J].Journal of hazardous materials,2020,387:122010.
[96]闫潇,王建雷,张明江,胡学武,刘兴宇. 土壤铬污染及生物修复技术研究进展[J].稀有金属,2023,47(9):1302.
X Yan,J L Wang,M J Zhang,X W Hu,X Y Liu. Research progress on soil chromium pollution and bioremediation technology[J].Chinese Journal of Rare Metals,2023,47(9):1302.
[97]Shah V,Daverey A. Phytoremediation:a multidisciplinary approach to clean up heavy metal contaminated soil[J]. Environmental Technology & Innovation,2020,18:100774.
[98]Li X X,Lan X,Feng X W,Luan X Y,Cao X F,Cui Z J. Biosorption capacity of Mucor circinelloides bioaugmented with Solanum nigrum L. for the cleanup of lead,cadmium and arsenic[J].Ecotoxicology and Environmental Safety,2021,212:112014.
[99]Feng R W,Zhu Q H,Xu Y M,Li W S,Ding Y Z,Han L,Rensing C,Wang R G. Safe utilization of polluted soil by arsenic,cadmium and lead through an integrated sericultural measure[J].Science of the Total Environment,2019,659:1234.
Basic Information:
DOI:10.13373/j.cnki.cjrm.XY24010028
Chinese Library Classification Number:X53
Citation Information:
With the rapid development of industry,agriculture,mining and urbanization,a large number of heavy metals and other pollutants enter the soil environmental system,and the combined pollution of heavy metals in soil caused by this problem has attracted much attention. According to the 2014 National Soil Pollution Status Report,19.4% of China's arable land has exceeded the standard for heavy metal pollutants such as Pb,Cd and As,with the sites exceeding the standard for these three typical heavy metals ranking at the top,resulting in a polluted area of over 50 million acres. Soil heavy metal pollution is characterized by long-term persistence,durability,and difficulty in degradation. Through surface and subsurface runoff,it can be transferred from the soil to surrounding water bodies,exacerbating water heavy metal pollution. At the same time,heavy metals in land and water can be absorbed by crops,entering the food chain and accumulating in organisms,causing significant harm to human health. Pb has irreversible effects on the nervous system and children's intellectual development. Cd is a highly toxic heavy metal,long-term exposure to cadmium-contaminated environments may lead to diseases such as kidney damage,osteoporosis,and cancer. As is associated with health issues including cancer,skin diseases,and cardiovascular diseases. However,the coexistence of heavy metals such as Pb,Cd and As in soil in composite pollution poses greater environmental hazards compared to single pollution. Therefore,it is of great significance to comprehensively understand the current situation,characteristics,and remediation technologies of heavy metal composite pollution for the prevention and control of heavy metal pollution and the safe utilization of soil. This review provides a comprehensive overview of the current status,sources of pollution,and distribution and migration characteristics of Pb,Cd and As in soils affected by composite pollution. It particularly emphasized the impact of soil pH,redox potential (Eh),soil organic matter (SOM) and soil types on the migration and transformation of Pb,Cd and As. The study presented a summary of the research progress in the remediation of Pb,Cd and As composite pollution using physical remediation methods,solidification/stabilization techniques,and bioremediation approaches. It discussed the advantages,disadvantages,and applicability of various soil remediation technologies and provides an outlook on future development directions. Specifically,the ex-situ soil washing method had a fast remediation rate but was expensive,easily disrupts soil structure,and might cause secondary pollution. The electrokinetic remediation method had simple equipment operation but was relatively costly,consumed a significant amount of energy,and might pose safety hazards. The bioremediation method could improve soil quality and maintain ecological balance but had a slow remediation process and is highly influenced by the environment. The solidification/stabilization techniques had become the mainstream technology for the remediation of composite pollution in soils due to their high efficiency,low cost,and easy implementation. Furthermore,due to the pressing demand for the large-scale disposal of metal mine wastes in China,the research on developing new solidification/stabilization materials utilizing local mining solid wastes for the remediation of Pb,Cd and As composite polluted soils would become a key focus in the field of solidification/stabilization technologies.
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| GB/T 7714-2015 | [1] Yingchun Sun, Xinglan Cui, Peng Zheng, et al. Research Progress in Soil Remediation of Lead,Cadmium and Arsenic Pollution[J]. Chinese Journal of Rare Metals, 2024, 48(9): 1335-1351. DOI:10.13373/j.cnki.cjrm.XY24010028. |
| MLA | [1] Yingchun Sun, et al., "Research Progress in Soil Remediation of Lead,Cadmium and Arsenic Pollution." Chinese Journal of Rare Metals, vol. 48, no. 9, 2024, pp. 1335-1351, https://doi.org/10.13373/j.cnki.cjrm.XY24010028. |
| APA | [1] Yingchun Sun, Xinglan Cui, Peng Zheng, Xinyue Shi, Hongxia Li, Lei Wang, Zeen Yu, & Qi Zheng. (2024). Research Progress in Soil Remediation of Lead,Cadmium and Arsenic Pollution. Chinese Journal of Rare Metals, 48(9), 1335-1351. https://doi.org/10.13373/j.cnki.cjrm.XY24010028 |
| IEEE | [1] Yingchun Sun, Xinglan Cui, Peng Zheng, Xinyue Shi, Hongxia Li, Lei Wang, Zeen Yu, and Qi Zheng, "Research Progress in Soil Remediation of Lead,Cadmium and Arsenic Pollution," Chinese Journal of Rare Metals, vol. 48, no. 9, pp. 1335-1351, 2024, doi: 10.13373/j.cnki.cjrm.XY24010028. keywords: {compound pollution;;soil remediation;;solidification/stabilization;;solid waste resourceization} |
