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Organic Photodiode Integration on Si Substrates beyond 1000 nm Wavelength AITranslate

VisEra Technologies Company Limited, No. 12;VisEra Technologies Company Limited, No. 12;RaynergyTek Inc.;RaynergyTek Inc.
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Publisher: ACS
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Abstract AITranslate

Organic photodiode integration on the Si readout circuit offers a solution for extending the sensitivity beyond 1000 nm. In this work, we report the way to integrate organic photodiodes on Si substrates with metals that are complementary metal–oxide–semiconductor process-compatible as bottom electrodes, such as titanium nitride (TiN), tungsten (W), and aluminum (Al). We report on a high-efficiency near-infrared sensor enabled by employing TiN and W as bottom electrodes, with an external quantum efficiency of ∼50% at 940 nm and ∼70% at 1030 nm, a dark leakage current density of 15 nA/cm2, a bandwidth of 15 kHz at −4 V, and a dynamic range of ∼100 dB. Low resistivity and inert properties of TiN make it form a good interface with the organic active layer, leading to an ideal bottom-contact metal for the organic photodiode when integrated on the Si substrate.

KeyWords AITranslate

infrared organic photodiode CMOS image sensor organic photodetector organic photoactive layer bottom electrode
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Basic Information:

DOI:https://doi.org/10.1021/acsaelm.1c00915

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Citation Information:

Organic photodiode integration on the Si readout circuit offers a solution for extending the sensitivity beyond 1000 nm. In this work, we report the way to integrate organic photodiodes on Si substrates with metals that are complementary metal–oxide–semiconductor process-compatible as bottom electrodes, such as titanium nitride (TiN), tungsten (W), and aluminum (Al). We report on a high-efficiency near-infrared sensor enabled by employing TiN and W as bottom electrodes, with an external quantum efficiency of ∼50% at 940 nm and ∼70% at 1030 nm, a dark leakage current density of 15 nA/cm2, a bandwidth of 15 kHz at −4 V, and a dynamic range of ∼100 dB. Low resistivity and inert properties of TiN make it form a good interface with the organic active layer, leading to an ideal bottom-contact metal for the organic photodiode when integrated on the Si substrate.

quote

GB/T 7714-2015 [1] LaiHung Lai, ChinChuan Hsieh, JhaoLin Wu, et al. ACS Applied Electronic Materials, 2022(4). DOI:10.1021/acsaelm.1c00915.
MLA [1] LaiHung Lai, et al., ACS Applied Electronic Materials, no. 4, 2022, https://doi.org/10.1021/acsaelm.1c00915.
APA [1] LaiHung Lai, ChinChuan Hsieh, JhaoLin Wu, & YiMing Chang. (2022). ACS Applied Electronic Materials(4). https://doi.org/10.1021/acsaelm.1c00915
IEEE [1] LaiHung Lai, ChinChuan Hsieh, JhaoLin Wu, and YiMing Chang, ACS Applied Electronic Materials, no. 4, 2022, doi: 10.1021/acsaelm.1c00915. keywords: {infrared organic photodiode CMOS image sensor organic photodetector organic photoactive layer bottom electrode}