Research on Hydrometallurgical Process of Germanium Recovery from Fly Ash AITranslate
Abstract AITranslate
Germanium was recovered from fly ash by ammonium fluoride-sulfuric acid leaching. In the process ,ammonium fluoride reacts with sulfuric acid to generate hydrogen fluoride as the destruction rea- gent of silica and calcium oxide in fly ash,sulfuric acid serves as the destruction reagent of magnesia,and sodium chlorate serves as the oxidant to oxidize Ge（ Ⅱ ） into Ge（Ig）,which can he dissolved into the leac- hing solution by sulfuric acid. Finally, germanium is precipitated with tannic acid. The above process has the advantages of high germanium recovery,low cost, low pollution and so on. Under the optimal technical conditions,the germanium recovery reaches 80.12% and the grade of resultant germanium concentrate is up to 4. 69%.
KeyWords AITranslate
1周智华,莫红兵.稀散金属锗富集回收技术的研究进展[J].中国矿业,2006,15(2):64-67. 被引量：10
2周娟,王吉坤,李勇.富锗硫化锌精矿浸出液萃取回收锗[J].有色金属：冶炼部分,2009(5):25-27. 被引量：13
3普世坤,段鑫敏.从氯化蒸馏残渣中回收锗的研究[J].材料研究与应用,2008,2(2):145-147. 被引量：10
4普世坤,包文东,郑洪.湿法从锗废料中回收锗[P].中国专利:200610048818.6,2009-07-15.
5普世坤,包文东,郑洪.湿法从铬一锗合金废料中回收锗[P].中国专利:200610048817.1,2009-08-26.
1普世坤,兰尧中.碱氧化预处理蒸馏分离回收还原精矿中的锗[J].有色金属：冶炼部分,2015(12):38-41. 被引量：2
2普世坤,兰尧中,吴王昌,谢高,杨再磊.微波加热常压挥发富集低品位褐煤锗精矿中锗的工艺研究[J].中国有色冶金,2016,45(1):78-82. 被引量：2
3程芳琴,王波,成怀刚.粉煤灰提取高附加值有价元素的技术现状及进展[J].无机盐工业,2017,49(2):1-4. 被引量：33
4张小东,赵飞燕,郭昭华,王永旺,陈东,张云峰.煤中稀有金属锗的提取技术研究进展[J].无机盐工业,2018,50(2):16-19. 被引量：4
5刘俊杰,刘丽霞,彭军,柴轶凡,李文挺,安胜利.高温二次火法富集粉煤灰中锗的工艺优化[J].稀有金属与硬质合金,2020,48(2):5-9. 被引量：2
6钞晓光,李依帆,张云峰,王瑞,陈东,王永旺.煤中锗的资源分布及其提取工艺研究进展[J].矿产综合利用,2020(4):21-25. 被引量：3
7王丽萍,李超,李世春.粉煤灰中稀散金属锗的富集回收技术研究进展[J].稀有金属与硬质合金,2022,50(6):27-32.
8刘殿传,李华楷,兰国辉.含锗资源湿法处理的研究进展[J].云南冶金,2023,52(3):86-90.
9普世坤,兰尧中,朱知国,谢天敏,尹国文.从含锗多金属物料中回收锗的工艺研究[J].稀有金属与硬质合金,2015,43(6):19-23. 被引量：2
10张艺婷,李世伟,李浩宇,尹少华,朱镕,张利波.从含锗物料中提锗的研究进展[J].冶金工程,2020,7(3):163-168.
1杨磊.粉煤灰酸浸液中磷、硅去除技术研究[J].轻金属,2021(2):20-25. 被引量：2
2刘汉斌.山西省粉煤灰煤矸石绿色发展的思考与建议[J].煤炭经济研究,2019,0(12):67-70. 被引量：1
3黄靖,王英滨,周冠轩,马真乾.混合酸溶-电感耦合等离子体发射光谱法测定粉煤灰样品中的微量元素镓[J].环境化学,2020(5):1427-1433. 被引量：2
4茹丘旭,马滋蔓.锗在红外光学行业的应用思考[J].中国科技纵横,2018,0(22):217-218.
5杨大锦.2015年云南冶金年评[J].云南冶金,2016,45(2):54-80. 被引量：1
6杨大锦.2016年云南冶金年评[J].云南冶金,2017,46(2):58-78.
7张苏江,季根源,王楠,姜爱玲,尚磊.中国锗矿资源现状及其可持续发展对策研究[J].矿产保护与利用,2017,37(2):6-12. 被引量：22
8郝喜才,焦婵.从废催化剂中回收钒的新工艺研究[J].无机盐工业,2017,49(8):57-61.
9秦健波,方莹,范仁东,何富军,曹君.氢氧化钠煅烧活化锅炉底渣的实验研究[J].无机盐工业,2018,50(2):62-65. 被引量：1
10杨再磊,李长林,谢高,薛丹,滕文,陈代凤,普世坤.乳化氧化预处理-氯化蒸馏法回收锗的工艺研究[J].中国有色冶金,2018,47(1):58-61. 被引量：1
1王昌.从锌厂滤渣中回收锗和其它有价金属[J].世界有色金属,2009(10):26-29. 被引量：2
2梁德华,王成彦,张永禄,李强,邢鹏.锌烟灰浸出液中铟和锗的提取[J].矿冶,2014,23(4):76-78. 被引量：5
3普世坤,严云南,兰尧中.铟精矿中铟等金属的综合回收工艺研究[J].中国有色冶金,2012,41(5):67-69. 被引量：1
4张博亚,王吉坤,彭友奇,许克昌.湿法炼锌过程中铟锗的综合回收[J].云南冶金,2007,36(5):25-28. 被引量：13
5徐兵.酸洗净化丹宁锗制取高品位锗精矿的技术探讨[J].中国金属通报,2003(19):19-22. 被引量：1
6李来时,刘瑛瑛.硫酸浸出法提取氧化铝的热力学讨论[J].轻金属,2009(5):19-22. 被引量：10
7刘波.丹宁分解产物对电解的影响[J].云南冶金,2002,31(S1):45-46.
8张永孝,张林.锌浮渣制备高纯氧化锌[J].四川有色金属,1991(2):9-11. 被引量：2
9韦文宾,何启贤.从湿法炼锌浸出渣中回收镓的试验研究[J].湿法冶金,2008,27(2):103-105. 被引量：5
10邓国珠,王雪飞.用攀枝花钛精矿制取高品位富钛料的途径[J].钢铁钒钛,2002,23(4):14-17. 被引量：28
Basic Information:
DOI：
Chinese Library Classification Number:TF843[冶金工程—有色金属冶金]
Citation Information:
Germanium was recovered from fly ash by ammonium fluoride-sulfuric acid leaching. In the process ,ammonium fluoride reacts with sulfuric acid to generate hydrogen fluoride as the destruction rea- gent of silica and calcium oxide in fly ash,sulfuric acid serves as the destruction reagent of magnesia,and sodium chlorate serves as the oxidant to oxidize Ge（ Ⅱ ） into Ge（Ig）,which can he dissolved into the leac- hing solution by sulfuric acid. Finally, germanium is precipitated with tannic acid. The above process has the advantages of high germanium recovery,low cost, low pollution and so on. Under the optimal technical conditions,the germanium recovery reaches 80.12% and the grade of resultant germanium concentrate is up to 4. 69%.
quote
| GB/T 7714-2015 | [1] PU Shi-kun, LAN Yao-zhong. Research on Hydrometallurgical Process of Germanium Recovery from Fly Ash[J]. Rare Metals and Cemented Carbides, 2012(5): 15-17. |
| MLA | [1] PU Shi-kun, and LAN Yao-zhong. "Research on Hydrometallurgical Process of Germanium Recovery from Fly Ash." Rare Metals and Cemented Carbides, no. 5, 2012, pp. 15-17. |
| APA | [1] PU Shi-kun, & LAN Yao-zhong. (2012). Research on Hydrometallurgical Process of Germanium Recovery from Fly Ash. Rare Metals and Cemented Carbides(5), 15-17. |
| IEEE | [1] PU Shi-kun and LAN Yao-zhong, "Research on Hydrometallurgical Process of Germanium Recovery from Fly Ash," Rare Metals and Cemented Carbides, no. 5, pp. 15-17, 2012. keywords: {fly ash;germanium recovery;ammonium fluoride-sulfuric acid leaching;germanium precipitationwith tannic acid} |