Preparation of Aqueous Solutions with Information on Solids (ASIS) of a Mechanochromic Luminescent Tetraphenylethylene Derivative by Complexation with Polysaccharides AITranslate
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The emission wavelengths of mechanochromic luminescent (ML) materials differ in the solid state based on molecular packing, whereas they exhibit one homogenized emission wavelength when dispersed in a solvent. Using a top-down approach, we developed a method that can maintain the solid state properties of ML materials in aqueous solutions. We confirmed that the crystallographic information on a tetraphenylethylene derivative with mechanochromic luminescence in the solid state was preserved in aqueous solutions via complexation with polysaccharides. The aqueous solutions of the complexes were stable for over 1 week.
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DOI：https://doi.org/10.1021/acsapm.1c00646
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The emission wavelengths of mechanochromic luminescent (ML) materials differ in the solid state based on molecular packing, whereas they exhibit one homogenized emission wavelength when dispersed in a solvent. Using a top-down approach, we developed a method that can maintain the solid state properties of ML materials in aqueous solutions. We confirmed that the crystallographic information on a tetraphenylethylene derivative with mechanochromic luminescence in the solid state was preserved in aqueous solutions via complexation with polysaccharides. The aqueous solutions of the complexes were stable for over 1 week.
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| GB/T 7714-2015 | [1] Riku Omokawa, Riku Kawasaki, Kouta Sugikawa, et al. ACS Applied Polymer Materials, 2021(3). DOI:10.1021/acsapm.1c00646. |
| MLA | [1] Riku Omokawa, et al., ACS Applied Polymer Materials, no. 3, 2021, https://doi.org/10.1021/acsapm.1c00646. |
| APA | [1] Riku Omokawa, Riku Kawasaki, Kouta Sugikawa, Tomoki Nishimura, Toshimi Nakaya, & Atsushi Ikeda. (2021). ACS Applied Polymer Materials(3). https://doi.org/10.1021/acsapm.1c00646 |
| IEEE | [1] Riku Omokawa, Riku Kawasaki, Kouta Sugikawa, Tomoki Nishimura, Toshimi Nakaya, and Atsushi Ikeda, ACS Applied Polymer Materials, no. 3, 2021, doi: 10.1021/acsapm.1c00646. keywords: {aggregationinduced emission;mechanochromic luminescence;polysaccharides;aqueous solution;supramolecular chemistry;Show More} |