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Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF6 and Cyclic Carbonate Additives AITranslate

Xiaodi Ren; Yaohui Zhang; Mark H. Engelhard; Qiuyan Li; JiGuang Zhang; Wu Xu;
Pacific Northwest National Laboratory; Pacific Northwest National Laboratory; Pacific Northwest National Laboratory; Pacific Northwest National Laboratory; Pacific Northwest National Laboratory; Pacific Northwest National Laboratory
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Publisher: ACS
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Abstract AITranslate

Spatial and morphology control over lithium (Li) metal nucleation and growth, as well as improving Li Coulombic efficiency (CE), are among the most challenging issues for rechargeable Li metal batteries. Here, we report that LiAsF6 and cyclic carbonate additives such as vinylene carbonate (VC) or fluoroethylene carbonate (FEC) can work synergistically to address these challenges. It is revealed that LiAsF6 can be reduced to LixAs alloy and LiF, which act as nanosized seeds for Li growth and form a robust solid electrolyte interface layer. The addition of VC or FEC not only enables the uniform distribution of LixAs seeds but also improves the flexibility of the solid electrolyte interface layer. As a result, highly compact, uniform, and dendrite-free Li film with vertically aligned column structure can be obtained with increased Li CE, and the Li metal batteries using the electrolyte with both LiAsF6 and cyclic carbonate additives can have improved cycle life.

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DOI：https://doi.org/10.1021/acsenergylett.7b00982

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Citation Information:

Spatial and morphology control over lithium (Li) metal nucleation and growth, as well as improving Li Coulombic efficiency (CE), are among the most challenging issues for rechargeable Li metal batteries. Here, we report that LiAsF6 and cyclic carbonate additives such as vinylene carbonate (VC) or fluoroethylene carbonate (FEC) can work synergistically to address these challenges. It is revealed that LiAsF6 can be reduced to LixAs alloy and LiF, which act as nanosized seeds for Li growth and form a robust solid electrolyte interface layer. The addition of VC or FEC not only enables the uniform distribution of LixAs seeds but also improves the flexibility of the solid electrolyte interface layer. As a result, highly compact, uniform, and dendrite-free Li film with vertically aligned column structure can be obtained with increased Li CE, and the Li metal batteries using the electrolyte with both LiAsF6 and cyclic carbonate additives can have improved cycle life.

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GB/T 7714-2015 [1] Xiaodi Ren, Yaohui Zhang, Mark H. Engelhard, et al. ACS Energy Letters, 2018(3). DOI:10.1021/acsenergylett.7b00982.
MLA [1] Xiaodi Ren, et al., ACS Energy Letters, no. 3, 2018, https://doi.org/10.1021/acsenergylett.7b00982.
APA [1] Xiaodi Ren, Yaohui Zhang, Mark H. Engelhard, Qiuyan Li, JiGuang Zhang, & Wu Xu. (2018). ACS Energy Letters(3). https://doi.org/10.1021/acsenergylett.7b00982
IEEE [1] Xiaodi Ren, Yaohui Zhang, Mark H. Engelhard, Qiuyan Li, JiGuang Zhang, and Wu Xu, ACS Energy Letters, no. 3, 2018, doi: 10.1021/acsenergylett.7b00982.