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Synthesis and Self-Assembly of Fully Zwitterionic Triblock Copolymers AITranslate

Tufts University; Tufts University; Tufts University; Tufts University
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Publisher: ACS
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Abstract AITranslate

Zwitterionic polymers are a distinctive class of materials with unique physical and chemical properties. In this study, the synthesis of fully zwitterionic ABA triblock copolymers was achieved by controlled radical polymerization using two different zwitterionic monomers, sulfobetaine methacrylate (SBMA) and 2-methacryloyloxyethyl phosphorylcholine (MPC). Due to the strong tendency of the sulfobetaine groups to aggregate, the fully zwitterionic triblock copolymers demonstrated self-assembly as well as salt and thermal responsiveness in solution.

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DOI:https://doi.org/10.1021/acsmaterialslett.9b00500

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Citation Information:

Zwitterionic polymers are a distinctive class of materials with unique physical and chemical properties. In this study, the synthesis of fully zwitterionic ABA triblock copolymers was achieved by controlled radical polymerization using two different zwitterionic monomers, sulfobetaine methacrylate (SBMA) and 2-methacryloyloxyethyl phosphorylcholine (MPC). Due to the strong tendency of the sulfobetaine groups to aggregate, the fully zwitterionic triblock copolymers demonstrated self-assembly as well as salt and thermal responsiveness in solution.

quote

GB/T 7714-2015 [1] Morgan E. Taylor, Samuel J. Lounder, Ayse Asatekin, et al. ACS Materials Letters, 2020(2). DOI:10.1021/acsmaterialslett.9b00500.
MLA [1] Morgan E. Taylor, et al., ACS Materials Letters, no. 2, 2020, https://doi.org/10.1021/acsmaterialslett.9b00500.
APA [1] Morgan E. Taylor, Samuel J. Lounder, Ayse Asatekin, & Matthew J. Panzer. (2020). ACS Materials Letters(2). https://doi.org/10.1021/acsmaterialslett.9b00500
IEEE [1] Morgan E. Taylor, Samuel J. Lounder, Ayse Asatekin, and Matthew J. Panzer, ACS Materials Letters, no. 2, 2020, doi: 10.1021/acsmaterialslett.9b00500.