The steel industry is among one of the largest CO2 emitters in the world. To meet climate targets, replacing fossil-based carbon with renewable biocarbon in metallurgical processes, particularly in blast furnaces (BFs) and electric arc furnaces (EAFs), has emerged as a viable short- to mid-term solution. Hydrothermal carbonization is a promising technology that converts low-grade, high-moisture biomass into hydrochar, a carbon-rich material with potential applications in ironmaking and steelmaking processes. This review examines the physicochemical and metallurgical properties of hydrochar—both in its pristine and pyrolyzed forms—derived from various biomass sources, and compares them with those of conventional carbonaceous materials such as fossil coal. This review also evaluates recent experimental and industrial studies demonstrating the application of hydrochar in BF injection and carbon composite agglomerates as well as its use for carburization and slag foaming in the EAF process. It demonstrates the potential of hydrochar as a partial substitute for fossil carbon, contributing to significant reductions in steel production-related CO2 emissions.
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Carbon capture and storage (CCS) has evolved from a conceptual mitigation option into a cornerstone of global decarbonization strategies. This review provides a comprehensive synthesis of CCS’s technological, intellectual, and institutional evolution, emphasizing its transition from isolated engineering applications to system-wide integration. Drawing on a bibliometric analysis of more than 19,000 publications (2001–2025) from the Web of Science Core Collection visualized through CiteSpace, we map the global research landscape and reveal the field’s thematic shift from capture and sequestration processes toward integrated approaches that couple CCS with hydrogen, bioenergy, and digital optimization frameworks. Technologically, CCS has advanced through three primary pathways—post-combustion, pre-combustion, and oxy–fuel combustion—each with distinct capture mechanisms, energy penalties, and retrofit potentials. At the deployment level, CCS expansion remains geographically uneven: industrialized economies such as China, the United States, and the United Kingdom dominate operational capacity, whereas emerging and developing economies face barriers related to infrastructure, financing, and governance. By integrating bibliometric, technological, and comparative analyses, this review develops a multidimensional framework encompassing policy design, institutional capacity, and deployment structure. The findings highlight that CCS’s future effectiveness depends not only on technological efficiency but also on coordinated governance, cross-border storage networks, and its alignment with broader innovation ecosystems driving the global net-zero transition.
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Hydrogen-enriched shaft furnaces serve as the central reactors in hydrogen metallurgy. The accuracy of the furnace design critically influences the internal operating conditions, including the dynamic variations in the gas distribution, pressure, temperature, and metallization rate. Particular attention should be paid to the injection angle of the reducing gas, which is a key operational parameter that significantly affects the system performance. In this study, a computational fluid dynamics model was established to simulate the internal working conditions of an industrial-scale ENERGIRON shaft furnace, revealing complex heat and mass transfer phenomena. Based on the simulation results, the upper wall of the reduction zone (within the height range of 16.0–16.5 m) withstands a significant temperature difference of 200 K, whereas the lower wall of the reduction zone (at a height of 1.5–2.5 m) experiences a substantial pressure difference (500 kPa). The metallization rate was approximately 93%. In the special cases where the reducing gas blowing angle was deflected from 90° to 30° or 150°, the wall temperature difference increased by approximately 100 K, the maximum pressure difference decreased by approximately 250 kPa, and the metallization rate increased by approximately 0.8%. Considering the balance between the service environment of the furnace wall and the metallization rate, a reducing gas blowing angle of 45° was selected as optimal.
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