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Inelastic Tunneling Spectroscopy-Based Electronic Tongue for Heavy Metal-Ion Detection Inelastic Tunneling Spectroscopy-Based Electronic Tongue for Heavy Metal-Ion Detection AITranslate

Indian Institute of Technology Bombay; Indian Institute of Technology Bombay; Indian Institute of Technology Bombay; Indian Institute of Technology Bombay; Indian Institute of Technology Bombay
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Publisher: ACS
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Abstract AITranslate

Heavy metal ions are found to be exceeding their safe limits in many drinking water sources and other aquatic systems that affect almost all forms of life on earth directly or indirectly. Detecting these metal ions in an aqueous solution needs highly sensitive and selective techniques. To that end, we demonstrate an electronic tongue based on inelastic electron tunneling spectroscopy (IETS). A metal–insulator–semiconductor (MIS) tunneling diode has been utilized as the sensing device and subsequently exposed to salt solutions of cadmium acetate and lead acetate. The measured IET spectra confirm the identity of the metal ions, with corroboration from measured Fourier transform infra-red (FTIR) spectroscopic peaks of the two salts and previously reported data. We have also shown the detection of these ions when the device is exposed to a solution of both salts, demonstrating its selectivity. This positions IETS as a promising mechanism to realize artificial gustatory sensing systems.

KeyWords AITranslate

heavy metal ions tunneling spectroscopy electronic tongue selectivity metal−insulator−semiconductor
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Basic Information:

DOI:https://doi.org/10.1021/acsaelm.3c00560

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Citation Information:

Heavy metal ions are found to be exceeding their safe limits in many drinking water sources and other aquatic systems that affect almost all forms of life on earth directly or indirectly. Detecting these metal ions in an aqueous solution needs highly sensitive and selective techniques. To that end, we demonstrate an electronic tongue based on inelastic electron tunneling spectroscopy (IETS). A metal–insulator–semiconductor (MIS) tunneling diode has been utilized as the sensing device and subsequently exposed to salt solutions of cadmium acetate and lead acetate. The measured IET spectra confirm the identity of the metal ions, with corroboration from measured Fourier transform infra-red (FTIR) spectroscopic peaks of the two salts and previously reported data. We have also shown the detection of these ions when the device is exposed to a solution of both salts, demonstrating its selectivity. This positions IETS as a promising mechanism to realize artificial gustatory sensing systems.

quote

GB/T 7714-2015 [1] Shankar Kesarwani, Nandhini Swaminathan, Ajay Singh, et al. ACS Applied Electronic Materials, 2023(5). DOI:10.1021/acsaelm.3c00560.
MLA [1] Shankar Kesarwani, et al., ACS Applied Electronic Materials, no. 5, 2023, https://doi.org/10.1021/acsaelm.3c00560.
APA [1] Shankar Kesarwani, Nandhini Swaminathan, Ajay Singh, Dipankar Saha, & Swaroop Ganguly. (2023). ACS Applied Electronic Materials(5). https://doi.org/10.1021/acsaelm.3c00560
IEEE [1] Shankar Kesarwani, Nandhini Swaminathan, Ajay Singh, Dipankar Saha, and Swaroop Ganguly, ACS Applied Electronic Materials, no. 5, 2023, doi: 10.1021/acsaelm.3c00560. keywords: {heavy metal ions tunneling spectroscopy electronic tongue selectivity metal−insulator−semiconductor}