daohang fenxiangbox searchbox qikanlogonew daohangnew searchboxnew navrightzone footerzone paper
English
Chinese 简体中文 English English
Home > Journals > ACS Applied Polymer Materials
‹ Previous Article Next Article ›

Poly(2,2′-Bibenzimidazole)-Supported Ruthenium Complex: A Recyclable Heterogeneous Catalyst for the Redox Isomerization of Allylic Alcohols to Ketones AITranslate

Xiaozhong Chen; Xingyou Han; Jing Xu; Junjie Yu; Chen Chen; Jiazhi Yang; Feng Li
Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology
AITranslate
Publisher: ACS
Share Citation Information Add to Favorites

    Scan to share on WeChat or Moments

Use WeChat scan.
Share with WeChat friends or Moments

Abstract AITranslate

A metallopolymer, Ru(p-cymene)@poly(2,2′-BiBzlm), which is synthesized by the incorporation of [Ru(p-cymene)Cl]2 into poly(bibenzimidazoles), was proven to be a general and efficient catalyst for the redox isomerization of allylic alcohols to ketones. Mechanistic experiments showed that this reaction is in agreement with an intramolecular hydrogen shift. This catalyst was also applied to the gram-scale synthesis of a biologically active molecule. Furthermore, this catalyst could be recycled five times without an obvious decrease in activity.

KeyWords AITranslate

isomerization of allylic alcohols ketones atom economy ruthenium recyclable catalyst poly(2 2′bibenzimidazoles)
No data

Basic Information:

DOI：https://doi.org/10.1021/acsapm.2c01668

Chinese Library Classification Number:

Citation Information:

A metallopolymer, Ru(p-cymene)@poly(2,2′-BiBzlm), which is synthesized by the incorporation of [Ru(p-cymene)Cl]2 into poly(bibenzimidazoles), was proven to be a general and efficient catalyst for the redox isomerization of allylic alcohols to ketones. Mechanistic experiments showed that this reaction is in agreement with an intramolecular hydrogen shift. This catalyst was also applied to the gram-scale synthesis of a biologically active molecule. Furthermore, this catalyst could be recycled five times without an obvious decrease in activity.

quote

GB/T 7714-2015 [1] Xiaozhong Chen, Xingyou Han, Jing Xu, et al. ACS Applied Polymer Materials, 2023(5). DOI:10.1021/acsapm.2c01668.
MLA [1] Xiaozhong Chen, et al., ACS Applied Polymer Materials, no. 5, 2023, https://doi.org/10.1021/acsapm.2c01668.
APA [1] Xiaozhong Chen, Xingyou Han, Jing Xu, Junjie Yu, Chen Chen, Jiazhi Yang, & Feng Li. (2023). ACS Applied Polymer Materials(5). https://doi.org/10.1021/acsapm.2c01668
IEEE [1] Xiaozhong Chen, Xingyou Han, Jing Xu, Junjie Yu, Chen Chen, Jiazhi Yang, and Feng Li, ACS Applied Polymer Materials, no. 5, 2023, doi: 10.1021/acsapm.2c01668. keywords: {isomerization of allylic alcohols;ketones;atom economy;ruthenium;recyclable catalyst;poly(2;2′bibenzimidazoles)}