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Highly Porous Curcumin-Loaded Polymer Mats for Rapid Detection of Volatile Amines AITranslate

Smart Materials, Istituto Italiano di Tecnologia;Smart Materials, Istituto Italiano di Tecnologia;Smart Materials, Istituto Italiano di Tecnologia;Pattern Analysis and Computer Vision, Istituto Italiano di Tecnologia;Smart Materials, Istituto Italiano di Tecnologia;Electron Microscopy Facility, Istituto Italiano di Tecnologia;Smart Materials, Istituto Italiano di Tecnologia;Smart Materials, Istituto Italiano di Tecnologia
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Publisher: ACS
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Abstract AITranslate

Here, the development of highly porous colorimetric indicators that are able to rapidly sense the presence of amine vapors is presented. Specifically, porous, curcumin-loaded polycaprolactone fibers are formed by electrospinning through non-solvent-induced phase separation. In comparison to the non-porous fibers, the developed system shows significantly higher sensitivity and responsivity to the presence of dimethylamine vapors, with a distinct color change at very low vapor concentrations (2.33 ppm compared to 9.26 ppm) within the first 5 s of exposure. Indeed, CIELAB analysis proves that the induced color changes can be easily perceived visually, as the differences between the initial and the final color of the indicator after its interaction with the modified environment are well above the limit for visual perception, even by inexperienced users. Furthermore, the color changes are reversible, enabling the use of the same indicator several times, making it, thus, a sustainable colorimetric indicator system that can be used in applications where the rapid detection of low concentration of alkaline vapors is necessary.

KeyWords AITranslate

porous electrospun fibers gas sensing intelligent packaging pH indicators dimethylamine
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Basic Information:

DOI:https://doi.org/10.1021/acsapm.2c00418

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Citation Information:

Here, the development of highly porous colorimetric indicators that are able to rapidly sense the presence of amine vapors is presented. Specifically, porous, curcumin-loaded polycaprolactone fibers are formed by electrospinning through non-solvent-induced phase separation. In comparison to the non-porous fibers, the developed system shows significantly higher sensitivity and responsivity to the presence of dimethylamine vapors, with a distinct color change at very low vapor concentrations (2.33 ppm compared to 9.26 ppm) within the first 5 s of exposure. Indeed, CIELAB analysis proves that the induced color changes can be easily perceived visually, as the differences between the initial and the final color of the indicator after its interaction with the modified environment are well above the limit for visual perception, even by inexperienced users. Furthermore, the color changes are reversible, enabling the use of the same indicator several times, making it, thus, a sustainable colorimetric indicator system that can be used in applications where the rapid detection of low concentration of alkaline vapors is necessary.

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GB/T 7714-2015 [1] Despoina Kossyvaki, Aurelio Barbetta, Marco Contardi, et al. ACS Applied Polymer Materials, 2022(4). DOI:10.1021/acsapm.2c00418.
MLA [1] Despoina Kossyvaki, et al., ACS Applied Polymer Materials, no. 4, 2022, https://doi.org/10.1021/acsapm.2c00418.
APA [1] Despoina Kossyvaki, Aurelio Barbetta, Marco Contardi, Matteo Bustreo, Katarzyna Dziza, Simone Lauciello, Athanassia Athanassiou, & Despina Fragouli. (2022). ACS Applied Polymer Materials(4). https://doi.org/10.1021/acsapm.2c00418
IEEE [1] Despoina Kossyvaki, Aurelio Barbetta, Marco Contardi, Matteo Bustreo, Katarzyna Dziza, Simone Lauciello, Athanassia Athanassiou, and Despina Fragouli, ACS Applied Polymer Materials, no. 4, 2022, doi: 10.1021/acsapm.2c00418. keywords: {porous electrospun fibers;gas sensing;intelligent packaging;pH indicators;dimethylamine}