Research on Tungsten Extraction from Alkali Sodium Tungstate Solution with Quaternary Ammonium Salt AITranslate
Abstract AITranslate
Study was made of tungsten extraction from alkaline sodium tungstate solution with the quaternary ammonium salt of tri-n-octylmethyl ammonium chloride (TOMAC) as the extractant. The effects of various conditions on tungsten extraction were investigated such as extractant concentration,DL-2-octanol concentration,phase ratio, extraction time and NaOH concentration of feed solution. And the extraction isotherms were plotted. The results show that the organic phase comprising 50% TOMAC+20% DL-2-oetanol+30% sulfonated kerosene has excellent performance of tungsten extraction and phase separation, and extraction equilibrium can be reached within 1 min. Both tungsten extraction rate and WO3-loading saturation capacity of the organic phase slightly decrease with the increase of NaOH concentration of feed solution. The extraction system can meet the requirement for deeply extracting tungsten from alkali soda leaching liquor of tungsten ores.
KeyWords AITranslate
1万林生,晏慧娟,肖学有,陈帮明,王辉.我国钨冶炼离子交换工艺的技术发展与工艺评价[J].中国钨业,2003,18(6):31-33. 被引量:20
2Drobnick J L, Lewis C J. Recovery and purification of tungsten by liquid ion exchange process [A]. Unit Processes in Hydrometallurgy[C]. London: Gordon and Breach Science Publishers, 1964. 504-514.
3李大任,苏元复.N263萃取分离W、P[J].稀有金属,1991,15(1):6-9. 被引量:7
4张祥麟,成本诚,经棠轩,等.N263萃取钨机理的研究[J].稀有金属,1980,4(3):23-28.
5Pzaitsev V, Ivanov I M, Kalesh N K, et al. Scientificfoundations of a new extraction technology for the pro- cessing of tungsten containing solutions [ A]. Proceed- ings of the Second International Conference on Hydro metallurgy (ICHM) [C]. Changsha: International Aca- demic Publishers, 1992. 768-772.
6关文娟.从钨矿苏打高压碱浸出液中萃取钨制取纯钨酸铵溶液的研究[D].长沙:中南大学,2009.
7关文娟,张贵清.用季铵盐从模拟钨矿苏打浸出液中直接萃取钨[J].中国有色金属学报,2011,21(7):1756-1762. 被引量:22
8张贵清,关文娟,张启修,肖连生,李青刚,曹佐英.从钨矿苏打浸出液中直接萃取钨的连续运转试验[J].中国钨业,2009,24(5):49-52. 被引量:22
9张贵清.从碱性介质中萃取钨制取钨酸铵溶液的研究[D].长沙:中南工业大学,1994.
10张贵清,张启修.一种钨湿法冶金清洁生产工艺[J].稀有金属,2003,27(2):254-257. 被引量:21
1陈金清,熊家任,林凯.碱性体系下萃取钒的研究[J].有色金属科学与工程,2014,5(1):20-24. 被引量:6
2陈世梁,张贵清,肖连生,关文娟.采用HCO_3^--CO_3^(2-)混合型季铵盐从模拟钨矿苏打高压浸出液中萃取钨[J].中国有色金属学报,2014,24(12):3155-3161. 被引量:10
3于亮,吴绍祖,程红光.季铵盐GW05和N263对Na_2WO_4溶液的萃钨性能对比研究[J].稀有金属,2015,39(3):193-200. 被引量:2
4陈金清,林凯,熊家任,段敏,黄亚祥.改性季铵盐从高碱度溶液中萃取钒的研究[J].有色金属科学与工程,2015,6(2):21-26. 被引量:4
5朱先正,霍广生,倪捷,宋琼.Tungsten removal from molybdate solutions using chelating ion-exchange resin:Equilibrium adsorption isotherm and kinetics[J].中南大学学报:英文版,2016,23(5):1052-1057. 被引量:2
6罗军,袁喜振.溶剂萃取法提取钨研究现状[J].中国钨业,2017,32(2):56-59. 被引量:5
7高腾跃,刘奎仁,韩庆,徐滨士.萃取-电沉积处理含铜氰化废水回收铜和氰化物[J].有色金属工程,2018,8(2):87-90. 被引量:6
8杨金洪,李江涛,刘文婷,赵中伟.硝酸-磷酸混合溶液中钨的萃取[J].中国有色金属学报,2018,28(5):1024-1032. 被引量:2
9李嘉豪,曹佐英,李嘉,张贵清,肖连生,李青刚.新型胺类萃取剂N1633萃取钨的研究[J].矿冶工程,2018,38(2):74-78.
10向小艳,尹建国,杨文强,夏文堂,袁晓丽.对比教学法在稀有金属冶金学教学中的应用[J].中国冶金教育,2018,23(6):4-6. 被引量:4
1陈金清,林凯,熊家任,段敏,黄亚祥.改性季铵盐从高碱度溶液中萃取钒的研究[J].有色金属科学与工程,2015,6(2):21-26. 被引量:4
2韦建华,肖连生,曾理.碱性条件下钨萃取过程中铝的行为研究[J].中国钨业,2016,31(2):43-48.
3陈金清,黄亚祥,段敏,黄彬,黄超.高钙低钒渣碱熔活化—超声波强化浸出提钒研究[J].有色金属工程,2016,6(5):33-37. 被引量:4
4罗军,袁喜振.溶剂萃取法提取钨研究现状[J].中国钨业,2017,32(2):56-59. 被引量:5
5高腾跃,刘奎仁,韩庆,徐滨士.萃取-电沉积处理含铜氰化废水回收铜和氰化物[J].有色金属工程,2018,8(2):87-90. 被引量:6
6肖超,曾理,韦建华,肖连生.碱性萃取分离钨铝过程的热力学分析[J].稀有金属,2018,42(3):291-298.
7杨金洪,李江涛,刘文婷,赵中伟.硝酸-磷酸混合溶液中钨的萃取[J].中国有色金属学报,2018,28(5):1024-1032. 被引量:2
8李嘉豪,曹佐英,李嘉,张贵清,肖连生,李青刚.新型胺类萃取剂N1633萃取钨的研究[J].矿冶工程,2018,38(2):74-78.
9曹才放,章行,李小文,邱晓辰,李昱芃,钟镇宇,王艺瞾,王建松.氯型季铵树脂对钨酸根吸附的热力学研究[J].有色金属科学与工程,2018,9(3):1-4. 被引量:2
10马子洋,闫柏军.石煤中五价钒的检测方法及碱浸规律[J].有色金属科学与工程,2018,9(1):45-50. 被引量:2
1龙扬.提高钨矿物碱分解收率的工艺措施[J].稀有金属与硬质合金,2008,36(4):20-23. 被引量:2
2赵燕,黄小龙,张盼盼,王震.从废脱硝催化剂中回收有价金属钨的研究[J].金属材料与冶金工程,2015,43(2):48-50. 被引量:7
3陈金清,熊家任,林凯.碱性体系下萃取钒的研究[J].有色金属科学与工程,2014,5(1):20-24. 被引量:6
4刘克俊,李剑虹,李长根.用硫代硫酸盐溶液浸出和回收金[J].国外金属矿选矿,2005,42(3):13-18. 被引量:11
5关文娟,张贵清.用季铵盐从模拟钨矿苏打浸出液中直接萃取钨[J].中国有色金属学报,2011,21(7):1756-1762. 被引量:22
6胡如忠.锌电积大极板制造应用与研究[J].世界有色金属,2015,40(11):20-24. 被引量:1
7胡如忠.锌电积大极极制造应用与研究[J].中国铅锌,2015,0(12):51-58.
8涂超平,肖进胜,杜康华,易本顺.基于各向异性热扩散方程的多聚焦图像融合算法[J].电子学报,2015,43(6):1192-1199. 被引量:21
Basic Information:
DOI:
Chinese Library Classification Number:TF841.1[冶金工程—有色金属冶金]
Citation Information:
Study was made of tungsten extraction from alkaline sodium tungstate solution with the quaternary ammonium salt of tri-n-octylmethyl ammonium chloride (TOMAC) as the extractant. The effects of various conditions on tungsten extraction were investigated such as extractant concentration,DL-2-octanol concentration,phase ratio, extraction time and NaOH concentration of feed solution. And the extraction isotherms were plotted. The results show that the organic phase comprising 50% TOMAC+20% DL-2-oetanol+30% sulfonated kerosene has excellent performance of tungsten extraction and phase separation, and extraction equilibrium can be reached within 1 min. Both tungsten extraction rate and WO3-loading saturation capacity of the organic phase slightly decrease with the increase of NaOH concentration of feed solution. The extraction system can meet the requirement for deeply extracting tungsten from alkali soda leaching liquor of tungsten ores.
quote
| GB/T 7714-2015 | [1] KE Zhao-hua, ZHANG Gui-qing, GUAN Wen-juan, et al. Research on Tungsten Extraction from Alkali Sodium Tungstate Solution with Quaternary Ammonium Salt[J]. Rare Metals and Cemented Carbides, 2012(6): 1-4. |
| MLA | [1] KE Zhao-hua, et al., "Research on Tungsten Extraction from Alkali Sodium Tungstate Solution with Quaternary Ammonium Salt." Rare Metals and Cemented Carbides, no. 6, 2012, pp. 1-4. |
| APA | [1] KE Zhao-hua, ZHANG Gui-qing, GUAN Wen-juan, & SHANG Guang-hao. (2012). Research on Tungsten Extraction from Alkali Sodium Tungstate Solution with Quaternary Ammonium Salt. Rare Metals and Cemented Carbides(6), 1-4. |
| IEEE | [1] KE Zhao-hua, ZHANG Gui-qing, GUAN Wen-juan, and SHANG Guang-hao, "Research on Tungsten Extraction from Alkali Sodium Tungstate Solution with Quaternary Ammonium Salt," Rare Metals and Cemented Carbides, no. 6, pp. 1-4, 2012. keywords: {tungsten sodium tungstate solution alkali extraction quaternary ammonium salt NaOH} |
