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Research on Adsorption Performance of P204 Solvent Impregnated Resins for Gallium(Ⅲ)in Sulfuric Acid Solution AITranslate

Science and Technology Branch,Ludong University;Science and Technology Branch,Ludong University;Science and Technology Branch,Ludong University;Science and Technology Branch,Ludong University;Science and Technology Branch,Ludong University
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Publisher: Editorial Office of Rare Metals and Cemented Carbides
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Abstract AITranslate

P204 solvent impregnated resins(P204 SIRs)were prepared by using styrene-divinylbenzene macroporous resin(HZ818)as a carrier and bis(2-ethylhexyl)phosphoric acid(P204)as an extractant,and were characterized by scanning electron microscope(SEM),infrared spectrometer(IR),and thermogravimetric analyzer(TG)to investigate the adsorption performance of P204 SIRs for Ga(Ⅲ)in sulfuric acid solution.The results show that the optimal pH value for Ga(Ⅲ)adsorption by P204 SIRs is 1.8.The adsorption equilibrium time of Ga(Ⅲ)at 298 K is approximately 20 h,with a saturation adsorption capacity of 10.9 mg/g,and the kinetic adsorption behavior could be described by a pseudo-second-order kinetic equation as t/Qt=0.2173+0.0962t.The isothermal adsorption of Ga(Ⅲ)by P204 SIRs follows the Langmuir isothermal adsorption model of Ce/Qe=0.4482+0.0588Ce,and the fitted saturation adsorption capacity of Ga(Ⅲ)at 298 K is about 17 mg/g.

KeyWords AITranslate

impregnated resin adsorption gallium(Ⅲ) sulfuric acid kinetic equation isothermal adsorption model

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DOI:

Chinese Library Classification Number:TF843.1[冶金工程—有色金属冶金]

Citation Information:

P204 solvent impregnated resins(P204 SIRs)were prepared by using styrene-divinylbenzene macroporous resin(HZ818)as a carrier and bis(2-ethylhexyl)phosphoric acid(P204)as an extractant,and were characterized by scanning electron microscope(SEM),infrared spectrometer(IR),and thermogravimetric analyzer(TG)to investigate the adsorption performance of P204 SIRs for Ga(Ⅲ)in sulfuric acid solution.The results show that the optimal pH value for Ga(Ⅲ)adsorption by P204 SIRs is 1.8.The adsorption equilibrium time of Ga(Ⅲ)at 298 K is approximately 20 h,with a saturation adsorption capacity of 10.9 mg/g,and the kinetic adsorption behavior could be described by a pseudo-second-order kinetic equation as t/Qt=0.2173+0.0962t.The isothermal adsorption of Ga(Ⅲ)by P204 SIRs follows the Langmuir isothermal adsorption model of Ce/Qe=0.4482+0.0588Ce,and the fitted saturation adsorption capacity of Ga(Ⅲ)at 298 K is about 17 mg/g.

quote

GB/T 7714-2015 [1] LI Zhi-ling, XU Cui-ping, LIU Jun-shen, et al. Research on Adsorption Performance of P204 Solvent Impregnated Resins for Gallium(Ⅲ)in Sulfuric Acid Solution[J]. Rare Metals and Cemented Carbides, 2023(5): 15-21.
MLA [1] LI Zhi-ling, et al., "Research on Adsorption Performance of P204 Solvent Impregnated Resins for Gallium(Ⅲ)in Sulfuric Acid Solution." Rare Metals and Cemented Carbides, no. 5, 2023, pp. 15-21.
APA [1] LI Zhi-ling, XU Cui-ping, LIU Jun-shen, LIU Qing-qing, & CHEN Xiao-liang. (2023). Research on Adsorption Performance of P204 Solvent Impregnated Resins for Gallium(Ⅲ)in Sulfuric Acid Solution. Rare Metals and Cemented Carbides(5), 15-21.
IEEE [1] LI Zhi-ling, XU Cui-ping, LIU Jun-shen, LIU Qing-qing, and CHEN Xiao-liang, "Research on Adsorption Performance of P204 Solvent Impregnated Resins for Gallium(Ⅲ)in Sulfuric Acid Solution," Rare Metals and Cemented Carbides, no. 5, pp. 15-21, 2023. keywords: {impregnated resin;adsorption;gallium(Ⅲ);sulfuric acid;kinetic equation;isothermal adsorption model}