Study on Technology for Recycling Cobalt from Li-ion Secondary Battery Anode Scrap of Al-Co Film AITranslate
Abstract AITranslate
According to the property of LiCoO 2 in Li-ion secondary battery anode wastes of Al Co film,dissolution reaction of LiCoO 2 in a system of H 2SO 4 and H 2O 2 was put forward: 2LiCoO 2+3H 2SO 4+H 2O 2→Li 2SO 4+2CoSO 4+4H 2O+O 2↑ A simple process for recycling cobalt and aluminum was determined,including alkali leaching of wastes,acid dissolution of slag,purification of cobalt containing solution and precipitation of cobalt.The recovery of cobalt reaches 95.75%.Aluminum in alkali leaching solution was neutralized with H 2SO 4 and the product Al(OH) 3with a chemical purity was obtained,the recycling rate is 94.84%.The profit of 45600.6 RMB Yuan can be obtained in treating l ton waste by the technology.
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1郭鸣凤,杨瑞敏,张泽波,叶劲草.LiCoO_2的合成及其在锂蓄电池中的行为[J].电化学,1995,1(1):70-77. 被引量：8
2吴国良,杨新河,阚素荣,金维华.锂离子电池及其电极材料的研制[J].电池,1998,28(6):258-262. 被引量：31
3《有色金属提取冶金手册》编辑委员会.有色金属提取冶金手册（锌镉铅铋分册）[M].北京:冶金工业出版社,1992.246.
4文德荣.草酸钴和氧化钴[J].江西冶金,1997,17(5):55-56. 被引量：9
5彭忠东,杨建红,邓朝阳,刘业翔.锂离子二次电池正极材料的研制进展[J].电池,1999,29(3):125-127. 被引量：18
6章福平.酒石酸法合成的LiCoO_2的结构及其二次锂电池行为研究[J].电化学,1995,1(3):342-347. 被引量：21
1南俊民,韩东梅,崔明,左晓希.溶剂萃取法从废旧锂离子电池中回收有价金属[J].电池,2004,34(4):309-311. 被引量：45
2吴晓东,傅小明,柴永新,傅明喜,戴起勋.蓝色氧化钨氢还原制取超细钨粉的工艺研究[J].稀有金属与硬质合金,2005,33(1):14-17. 被引量：5
3王永利,赵丽霞.从含钴废料中提取钴的研究进展[J].再生资源研究,2005(2):29-32. 被引量：22
4欧秀芹,孙新华,赵庆云,范飞.锂离子废电池资源化技术进展[J].无机盐工业,2005,37(9):11-14. 被引量：14
5童东革,赖琼钰,吉晓洋.废旧锂离子电池正极材料钴酸锂的回收[J].化工学报,2005,56(10):1967-1970. 被引量：28
6张正洁,杨金侠.废锂离子电池的资源化回收方法[J].有色矿冶,2005,21(6):46-47. 被引量：11
7秦毅红,齐申.有机溶剂分离法处理废旧锂离子电池[J].有色金属：冶炼部分,2006(1):13-16. 被引量：17
8谭海翔,胡启阳,李新海,王志兴,郭华军.含铝硫酸钴溶液中回收氧化钴新工艺的研究[J].稀有金属与硬质合金,2006,34(1):33-35.
9刘云建,胡启阳,李新海,王志兴,郭华军,彭文杰.从不合格锂离子蓄电池中直接回收钴酸锂[J].电源技术,2006,30(4):308-310. 被引量：14
10何汉兵,秦毅红.从废旧锂离子蓄电池中回收钴[J].电源技术,2006,30(4):311-314. 被引量：7
1汪成东,施素杰,朱浪,李春滢,石贵明.废旧锂电池的回收处理进展及趋势[J].玉溪师范学院学报,2020(3):59-67. 被引量：2
2吴晓伟,秦佩.基于三元电池正极材料制程的废水资源化回用工艺技术[J].电子技术（上海）,2020(2):165-167.
3唐娜娜,马少健,莫伟.从某锰矿浸渣中回收钴的浮选试验研究[J].有色矿冶,2006,22(S1):8-9. 被引量：4
4唐娜娜,莫伟,马少健.钴矿资源及其选矿研究进展[J].有色矿冶,2006,22(S1):5-7. 被引量：7
5安洪力,吴宁宁,范茂松,李其其格.锰酸锂动力锂离子二次电池中主要化学元素的回收研究[J].北京大学学报：自然科学版,2006,42(S1):83-86. 被引量：6
6孟燕莎.低碳发展标准化实践之废旧手机回收再利用[J].标准科学,2013(12):17-19. 被引量：1
7刘庄,黄旭江,许开华,张翔.废旧锂离子电池制备硬脂酸钴的研究[J].化工新型材料,2011,39(S2):111-113. 被引量：2
8程家蓉,潘伦,陈先玉,许新.废旧手机电池资源综合利用现状[J].消费导刊,2009,0(14):197-197.
9胡宝磊,周雍茂.红土镍矿硫酸铵焙烧-水浸实验研究[J].现代冶金,2013,41(3):11-14. 被引量：2
10戴长松,路密,熊岳平,江洪伟.废旧锂离子电池处理处置现状及污染防治对策[J].环境科学与技术,2013,36(S2):332-335. 被引量：13
1丁慧,潘帅军,吕经康,张登科,陈得军,石起增,卢雁.由锂离子电池正极废料制备电池级硫酸钴的研究[J].河南师范大学学报：自然科学版,2007,35(2):193-194. 被引量：8
2谭海翔,胡启阳,李新海,王志兴,郭华军.含铝硫酸钴溶液中回收氧化钴新工艺的研究[J].稀有金属与硬质合金,2006,34(1):33-35.
3张永禄,王成彦,杨卜,杨永强.废旧锂离子电池LiCoO_2电极中钴的浸出动力学[J].有色金属：冶炼部分,2012(8):4-6. 被引量：6
4王文军.硫酸-双氧水体系氧化浸出铅冰铜的试验研究[J].湖南有色金属,2016,32(6):30-32. 被引量：2
5宾智勇,刘景槐,吴海国,李婕.废旧锂离子电池的综合利用试验研究[J].湖南有色金属,2008,24(5):27-31. 被引量：8
6新技术[J].中国金属通报,2002,0(18):17-13.
7吉鸿安.锂离子电池正极废料中钴和锂的回收[J].甘肃冶金,2012,34(4):63-66. 被引量：3
8张守全,程登峰,王海峰,肖伟.粗大钴团在硬质合金烧结过程中的演变[J].粉末冶金材料科学与工程,2010,15(6):661-666. 被引量：7
9苏树发,曹高劭,赵新兵.金属锑薄膜用作锂离子电池负极的研究[J].稀有金属材料与工程,2005,34(3):452-454. 被引量：10
10张文钲,刘燕.钼冶金技术发展近况[J].中国钼业,2013,37(3):1-5. 被引量：4
Basic Information:
DOI：
Chinese Library Classification Number:TF816.052[冶金工程—有色金属冶金]
Citation Information:
According to the property of LiCoO 2 in Li-ion secondary battery anode wastes of Al Co film,dissolution reaction of LiCoO 2 in a system of H 2SO 4 and H 2O 2 was put forward: 2LiCoO 2+3H 2SO 4+H 2O 2→Li 2SO 4+2CoSO 4+4H 2O+O 2↑ A simple process for recycling cobalt and aluminum was determined,including alkali leaching of wastes,acid dissolution of slag,purification of cobalt containing solution and precipitation of cobalt.The recovery of cobalt reaches 95.75%.Aluminum in alkali leaching solution was neutralized with H 2SO 4 and the product Al(OH) 3with a chemical purity was obtained,the recycling rate is 94.84%.The profit of 45600.6 RMB Yuan can be obtained in treating l ton waste by the technology.
quote
| GB/T 7714-2015 | [1] ZHONG Hai-yun, LI Jian, CHAI Li-yuan. Study on Technology for Recycling Cobalt from Li-ion Secondary Battery Anode Scrap of Al-Co Film[J]. Rare Metals and Cemented Carbides, 2001(1): 1-4. |
| MLA | [1] ZHONG Hai-yun, et al., "Study on Technology for Recycling Cobalt from Li-ion Secondary Battery Anode Scrap of Al-Co Film." Rare Metals and Cemented Carbides, no. 1, 2001, pp. 1-4. |
| APA | [1] ZHONG Hai-yun, LI Jian, & CHAI Li-yuan. (2001). Study on Technology for Recycling Cobalt from Li-ion Secondary Battery Anode Scrap of Al-Co Film. Rare Metals and Cemented Carbides(1), 1-4. |
| IEEE | [1] ZHONG Hai-yun, LI Jian, and CHAI Li-yuan, "Study on Technology for Recycling Cobalt from Li-ion Secondary Battery Anode Scrap of Al-Co Film," Rare Metals and Cemented Carbides, no. 1, pp. 1-4, 2001. keywords: {Li ion secondary battery;anode material scrap;LiCoO 2;recycling;cobalt;cobalt oxalate} |