Extraction of Tungsten and Molybdenum from Scheelite Chemical Beneficiation Acidic Leachate AITranslate
Abstract AITranslate
Tungsten and molybdenum were extracted from scheelite chemical beneficiation acidic leachate with the organic system of 15 % N235 + 10 %TBP+75 % sulfonated kerosene. The saturated loading capacity for Mo and WO3 of the organic system reaches 90.73 g/L,and the extracted complex ratio between N235 and Mo and WOa is 0. 886. Mo and W are extracted mainly in the form of MoO2Cln(n-2)- and H2WO4 ,respectively, Fe in the form of complex anion and P in the form of H3 PO4. The single stage extraction rates of Mo,WO3,Fe and P are 76.3%,94.8%,99.1% and 7.5% ,respectively. The loaded organic phase was eluted using dilute HC1 solution (pH=2). The removal rates of Fe and P reach 99.6% and 77% ,respectively. The single stage stripping rates of Mo and WOa are 88.35% and 66.52% ,respectively by using 2 mol/L NaOH solution.
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1李青刚,张启修,李赞恩,田吉英,肖连生.离子交换法回收高钼钨中矿化选液中的钨钼[J].中国钨业,2009,24(5):56-59. 被引量:9
2李循勋,文星照.用萃取法从酸沉母液中回收钼[J].中国钼业,1995,19(6):11-13. 被引量:8
3张启修 黄芍英 周良益.杂多酸萃取法回收三氧化钨的研究.中南矿冶学院学报,1994,.
4朱薇,肖连生,肖超,龚柏藩.N235萃取镍钼矿硫酸浸出液中钼的研究[J].稀有金属与硬质合金,2010,38(1):1-4. 被引量:23
5孙盈,李艳玲,权新军,廖伍平.二-(2-乙基己基)磷酸P204与三烷基叔胺N235协同萃取钼[J].应用化学,2009,26(11):1353-1356. 被引量:11
6赵由才,于淑秋,陈家镛.伯胺-磷酸三丁酯协同萃取分离钼酸钠溶液中磷的机理研究[J].有色金属,1992(3):59-62. 被引量:1
7李大任,苏元复.溶剂萃取法分离钨、磷的研究[J].化工学报,1990,41(1):43-49. 被引量:5
8Sato T,Watanabe H, Suzuki H. Liquid-liquid extraction of molybdenum (YI) from aqueous acid solutions by TBP and TOPO[J]. Hydrometallurgy, 1990, 23: 297- 308.
9Lippard S. Progress in Inorganic Chemistry(Vol. 22) [M]. Hoboken:John Wiley & Sons Inc,1977.35-39.
10拉斯科林BH.湿法冶金:加压浸出、吸附、萃取[M].北京:原子能出版社,1984.356-358.
1曾颜亮,廖春发,邓攀,陈静远,焦芸芬,郑春到.低浓度钼的亚砷酸还原终液萃取钼负载N235的反萃[J].有色金属工程,2016,6(2):44-47.
2周小舟,曹佐英,肖连生,刘劭钢,张贵清,李青刚,曾理,关文娟,白兰.新型三叔胺萃取剂的合成及其萃取性能[J].中南大学学报:自然科学版,2017,48(3):562-569. 被引量:2
1李嘉豪,曹佐英,李嘉,张贵清,李青刚,曾理,关文娟.高级脂肪胺类萃取剂在稀有金属溶剂萃取中的应用[J].稀有金属与硬质合金,2018,46(6):10-18. 被引量:1
2郭株辉.钼精矿氨加压浸出钼铼分离试验研究[J].中国钼业,2019,43(1):9-13. 被引量:1
1何宾宾,梁玉军,杨超,田熙科,皮振邦.电解金属锰合格液中锰镁的萃取分离研究[J].中国锰业,2010,28(1):41-44. 被引量:16
2曾冬铭,舒万艮,刘又年,雷存喜.低酸浸出-溶剂萃取法从含铟渣中回收铟[J].有色金属,2002,54(3):41-44. 被引量:29
3王林生,汪发波,文小强.P204萃取法对锂云母浸出液的除杂效果研究[J].稀有金属与硬质合金,2013,41(1):24-27. 被引量:2
4俞宏伟,陈虹,刘润,张勇.从含钼的P204—煤油体系中反萃取钼的研究[J].浙江化工,1998,29(1):40-41.
5张莹,张廷安.N1923萃取钒渣无焙烧浸出液中钒的实验探究[J].有色金属科学与工程,2015,6(6):14-19. 被引量:6
6汤兵,朱又春,白雪梅,蔡斌,陈丽卿,张俊浩.溶剂萃取法从镀锌酸洗废液中分离锌、铁的研究[J].矿冶工程,2003,23(5):47-49. 被引量:16
7和晓才,谢刚,李怀仁,杨大锦,徐庆鑫.高铁、高硅溶液中萃取钼[J].有色金属:冶炼部分,2012(1):16-19. 被引量:4
8康立武,胡江平,李强.用P204从废钒催化剂中萃取钒[J].有色金属:冶炼部分,2016(1):46-48. 被引量:3
9韩曙祥,梁宏.钨酸生产工艺的改进[J].有色金属:冶炼部分,1994(3):5-7.
10李桂英,戴子林,唐谦.水相pH值和有机相配比对从石煤酸浸液中萃取钒影响的研究[J].材料研究与应用,2010,4(2):142-144. 被引量:5
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DOI:
Chinese Library Classification Number:TF111.3[冶金工程—冶金物理化学]
Citation Information:
Tungsten and molybdenum were extracted from scheelite chemical beneficiation acidic leachate with the organic system of 15 % N235 + 10 %TBP+75 % sulfonated kerosene. The saturated loading capacity for Mo and WO3 of the organic system reaches 90.73 g/L,and the extracted complex ratio between N235 and Mo and WOa is 0. 886. Mo and W are extracted mainly in the form of MoO2Cln(n-2)- and H2WO4 ,respectively, Fe in the form of complex anion and P in the form of H3 PO4. The single stage extraction rates of Mo,WO3,Fe and P are 76.3%,94.8%,99.1% and 7.5% ,respectively. The loaded organic phase was eluted using dilute HC1 solution (pH=2). The removal rates of Fe and P reach 99.6% and 77% ,respectively. The single stage stripping rates of Mo and WOa are 88.35% and 66.52% ,respectively by using 2 mol/L NaOH solution.
quote
| GB/T 7714-2015 | [1] LI Qing-gang, LIAO Yu-long, ZHANG Qi-xiu, et al. Extraction of Tungsten and Molybdenum from Scheelite Chemical Beneficiation Acidic Leachate[J]. Rare Metals and Cemented Carbides, 2011(3): 1-5. |
| MLA | [1] LI Qing-gang, et al., "Extraction of Tungsten and Molybdenum from Scheelite Chemical Beneficiation Acidic Leachate." Rare Metals and Cemented Carbides, no. 3, 2011, pp. 1-5. |
| APA | [1] LI Qing-gang, LIAO Yu-long, ZHANG Qi-xiu, XIAO Lian-sheng, & TIAN Ji-ying. (2011). Extraction of Tungsten and Molybdenum from Scheelite Chemical Beneficiation Acidic Leachate. Rare Metals and Cemented Carbides(3), 1-5. |
| IEEE | [1] LI Qing-gang, LIAO Yu-long, ZHANG Qi-xiu, XIAO Lian-sheng, and TIAN Ji-ying, "Extraction of Tungsten and Molybdenum from Scheelite Chemical Beneficiation Acidic Leachate," Rare Metals and Cemented Carbides, no. 3, pp. 1-5, 2011. keywords: {extraction molybdenum;tungsten;15 % N235 + 10 % TBP + 75 % sulfonated kerosene;scheelite;chemical beneficiation leachate} |
