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Ferromagnetism and Rashba Spin–Orbit Coupling in the Two-Dimensional (V,Pt)Se2 Alloy AITranslate

Université de Grenoble Alpes; Université de Grenoble Alpes;ESRF, The European Synchrotron; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes;Laboratorio TASC, Istituto Officina dei Materiali (IOM)-CNR;Laboratorio TASC, Istituto Officina dei Materiali (IOM)-CNR;L’Orme des Merisiers, Synchrotron SOLEIL;ESRF, The European Synchrotron;L’Orme des Merisiers, Synchrotron SOLEIL;L’Orme des Merisiers, Synchrotron SOLEIL; Université de Paris-Saclay; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes; Université de Grenoble Alpes
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Publisher: ACS
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Abstract AITranslate

We report on a two-dimensional (2D) V1–xPtxSe2 alloy that exhibits ferromagnetic order and Rashba spin–orbit coupling. Although ferromagnetism is absent in 1T-VSe2 because of the competition with the charge density wave phase, we demonstrate theoretically and experimentally that the substitution of vanadium by platinum in VSe2 (10–50%) to form a homogeneous 2D alloy restores ferromagnetic order down to one monolayer of V0.65Pt0.35Se2. Moreover, the presence of platinum atoms gives rise to Rashba spin–orbit coupling in (V,Pt)Se2, providing an original platform to study the interplay between ferromagnetism and spin–orbit coupling in the 2D limit.

KeyWords AITranslate

2D materials ferromagnetism Rashba spin−orbit coupling 2D alloys molecular beam epitaxy Xray magnetic circular dichroism spin and angleresolved photoemission spectroscopy
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Basic Information:

DOI:https://doi.org/10.1021/acsaelm.1c00992

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Citation Information:

We report on a two-dimensional (2D) V1–xPtxSe2 alloy that exhibits ferromagnetic order and Rashba spin–orbit coupling. Although ferromagnetism is absent in 1T-VSe2 because of the competition with the charge density wave phase, we demonstrate theoretically and experimentally that the substitution of vanadium by platinum in VSe2 (10–50%) to form a homogeneous 2D alloy restores ferromagnetic order down to one monolayer of V0.65Pt0.35Se2. Moreover, the presence of platinum atoms gives rise to Rashba spin–orbit coupling in (V,Pt)Se2, providing an original platform to study the interplay between ferromagnetism and spin–orbit coupling in the 2D limit.

quote

GB/T 7714-2015 [1] Emilio VélezFort, Ali Hallal, Roberto Sant, et al. ACS Applied Electronic Materials, 2022(4). DOI:10.1021/acsaelm.1c00992.
MLA [1] Emilio VélezFort, et al., ACS Applied Electronic Materials, no. 4, 2022, https://doi.org/10.1021/acsaelm.1c00992.
APA [1] Emilio VélezFort, Ali Hallal, Roberto Sant, Thomas Guillet, Khasan Abdukayumov, Alain Marty, Céline Vergnaud, JeanFrançois Jacquot, Denis Jalabert, Jun Fujii, Ivana Vobornik, Julien Rault, Nicholas B. Brookes, Danilo Longo, Philippe Ohresser, Abdelkarim Ouerghi, JeanYves Veuillen, Pierre Mallet, Hervé Boukari, . . . Matthieu Jamet. (2022). ACS Applied Electronic Materials(4). https://doi.org/10.1021/acsaelm.1c00992
IEEE [1] Emilio VélezFort, Ali Hallal, Roberto Sant, Thomas Guillet, Khasan Abdukayumov, Alain Marty, Céline Vergnaud, JeanFrançois Jacquot, Denis Jalabert, Jun Fujii, Ivana Vobornik, Julien Rault, Nicholas B. Brookes, Danilo Longo, Philippe Ohresser, Abdelkarim Ouerghi, JeanYves Veuillen, Pierre Mallet, Hervé Boukari, Hanako Okuno, Mairbek Chshiev, Frédéric Bonell, and Matthieu Jamet, ACS Applied Electronic Materials, no. 4, 2022, doi: 10.1021/acsaelm.1c00992. keywords: {2D materials ferromagnetism Rashba spin−orbit coupling 2D alloys molecular beam epitaxy Xray magnetic circular dichroism spin and angleresolved photoemission spectroscopy}