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Arrays of Functionalized Graphene Chemiresistors for Selective Sensing of Volatile Organic Compounds Arrays of Functionalized Graphene Chemiresistors for Selective Sensing of Volatile Organic Compounds AITranslate

University of Ottawa; University of Ottawa; University of Ottawa; University of Ottawa; University of Ottawa; University of Ottawa; University of Ottawa; Argonne National Laboratory; University of Ottawa; University of Ottawa
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Publisher: ACS
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Abstract AITranslate

Real-time detection of volatile organic compounds (VOCs) is being spotlighted for its importance in environmental monitoring and disease detection from the breath. However, the selective detection of VOCs in a small form factor gas sensor remains a challenge. Here, we present the VOC sensing performance of phthalocyanine (Pc)-functionalized graphene chemiresistors supported by the theoretical prediction of Pc’s VOC interactions. Pc functionalization, with and without metalation, was studied parametrically with varying deposition parameters to explore impacts on the gas sensing response toward VOCs as a function of substrate coverage. Sensing data were collected to establish fingerprint signatures for a variety of VOCs. Improvement in selectivity is shown by successfully differentiating the VOCs from each other when combined into a gas sensor array tested with acetone, ethanol, formaldehyde, and toluene.

KeyWords AITranslate

graphene phthalocyanine sensing sensor arrays 2D materials
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Basic Information:

DOI:https://doi.org/10.1021/acsaelm.2c01544

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Citation Information:

Real-time detection of volatile organic compounds (VOCs) is being spotlighted for its importance in environmental monitoring and disease detection from the breath. However, the selective detection of VOCs in a small form factor gas sensor remains a challenge. Here, we present the VOC sensing performance of phthalocyanine (Pc)-functionalized graphene chemiresistors supported by the theoretical prediction of Pc’s VOC interactions. Pc functionalization, with and without metalation, was studied parametrically with varying deposition parameters to explore impacts on the gas sensing response toward VOCs as a function of substrate coverage. Sensing data were collected to establish fingerprint signatures for a variety of VOCs. Improvement in selectivity is shown by successfully differentiating the VOCs from each other when combined into a gas sensor array tested with acetone, ethanol, formaldehyde, and toluene.

quote

GB/T 7714-2015 [1] Natalia AlzateCarvajal, Jaewoo Park, Ilhem Bargaoui, et al. ACS Applied Electronic Materials, 2023(5). DOI:10.1021/acsaelm.2c01544.
MLA [1] Natalia AlzateCarvajal, et al., ACS Applied Electronic Materials, no. 5, 2023, https://doi.org/10.1021/acsaelm.2c01544.
APA [1] Natalia AlzateCarvajal, Jaewoo Park, Ilhem Bargaoui, Ranjana Rautela, Zachary J. Comeau, Lukas Scarfe, JeanMichel Ménard, Seth B. Darling, Benoît H. Lessard, & Adina LuicanMayer. (2023). ACS Applied Electronic Materials(5). https://doi.org/10.1021/acsaelm.2c01544
IEEE [1] Natalia AlzateCarvajal, Jaewoo Park, Ilhem Bargaoui, Ranjana Rautela, Zachary J. Comeau, Lukas Scarfe, JeanMichel Ménard, Seth B. Darling, Benoît H. Lessard, and Adina LuicanMayer, ACS Applied Electronic Materials, no. 5, 2023, doi: 10.1021/acsaelm.2c01544. keywords: {graphene phthalocyanine sensing sensor arrays 2D materials}