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One-Step Synthesis of an Ionic Covalent Organic Polymer for CO2 Capture AITranslate

Syed Ibrahim Gnani Peer Mohamed; Tung Nguyen; Mona Bavarian; Siamak Nejati;
University of Nebraska-Lincoln; University of Nebraska-Lincoln; University of Nebraska-Lincoln; University of Nebraska-Lincoln
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Publisher: ACS
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Abstract AITranslate

We report on a scalable synthetic pathway to produce an ionic covalent organic polymer (iCOP) via the Menshutkin reaction. This one-step synthetic procedure avoids the need for postmodification of a COP and the use of ionic monomers. The as-synthesized materials precipitate as nanoparticles. The physical and chemical properties of the nanomaterials are characterized, and their sorption capacity for carbon dioxide (CO2) capture is evaluated. The results indicate that the iCOP has a CO2 uptake capacity of ∼1.5 mmol/g at 1 bar and 293 K. The synthesized materials are considered green, and the proposed one-step approach is cost-effective when compared with other approaches used to synthesize porous materials for adsorption.

KeyWords AITranslate

porous organic polymer CO2 polymer Menshutkin reaction mesoporous material onestep synthesis
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Basic Information:

DOI：https://doi.org/10.1021/acsapm.2c01436

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Citation Information:

We report on a scalable synthetic pathway to produce an ionic covalent organic polymer (iCOP) via the Menshutkin reaction. This one-step synthetic procedure avoids the need for postmodification of a COP and the use of ionic monomers. The as-synthesized materials precipitate as nanoparticles. The physical and chemical properties of the nanomaterials are characterized, and their sorption capacity for carbon dioxide (CO2) capture is evaluated. The results indicate that the iCOP has a CO2 uptake capacity of ∼1.5 mmol/g at 1 bar and 293 K. The synthesized materials are considered green, and the proposed one-step approach is cost-effective when compared with other approaches used to synthesize porous materials for adsorption.

quote

GB/T 7714-2015 [1] Syed Ibrahim Gnani Peer Mohamed, Tung Nguyen, Mona Bavarian, et al. ACS Applied Polymer Materials, 2022(4). DOI:10.1021/acsapm.2c01436.
MLA [1] Syed Ibrahim Gnani Peer Mohamed, et al., ACS Applied Polymer Materials, no. 4, 2022, https://doi.org/10.1021/acsapm.2c01436.
APA [1] Syed Ibrahim Gnani Peer Mohamed, Tung Nguyen, Mona Bavarian, & Siamak Nejati. (2022). ACS Applied Polymer Materials(4). https://doi.org/10.1021/acsapm.2c01436
IEEE [1] Syed Ibrahim Gnani Peer Mohamed, Tung Nguyen, Mona Bavarian, and Siamak Nejati, ACS Applied Polymer Materials, no. 4, 2022, doi: 10.1021/acsapm.2c01436. keywords: {porous organic polymer;CO2;polymer;Menshutkin reaction;mesoporous material;onestep synthesis}