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Reclamation of Oily Wastewater at High Temperatures Using Thermosetting Polyurethane-Nanosilicon Sponges AITranslate

University of Toronto; University of Toronto; Imperial College London; University of Toronto; University of Toronto
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Publisher: ACS
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Abstract AITranslate

Reclamation of fracking wastewater at its high discharge temperature is a global energy and environmental challenge. Herein, the utilization of thermosetting polyurethane-nanosilicon sponges with thermal stability up to 220 °C is demonstrated for reclaiming emulsified oily wastewater between 30 and 100 °C. The sponge achieved 92–96% removal efficiency within 5 min where efficiency of 27% was increased by melting wax crystallites in the crude oil. The adsorbed oil was extracted from the sponge by rinsing with Heptol. These results show that thermoset polymers are promising high-temperature sorbents to reclaim fracking effluents and achieve Net-Zero goals in the oil industry.

KeyWords AITranslate

oil/water separation superwetting sponges thermosetting polymers nanosilicon wax crystallization resource recovery Show More
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Basic Information:

DOI:https://doi.org/10.1021/acsapm.1c00944

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Citation Information:

Reclamation of fracking wastewater at its high discharge temperature is a global energy and environmental challenge. Herein, the utilization of thermosetting polyurethane-nanosilicon sponges with thermal stability up to 220 °C is demonstrated for reclaiming emulsified oily wastewater between 30 and 100 °C. The sponge achieved 92–96% removal efficiency within 5 min where efficiency of 27% was increased by melting wax crystallites in the crude oil. The adsorbed oil was extracted from the sponge by rinsing with Heptol. These results show that thermoset polymers are promising high-temperature sorbents to reclaim fracking effluents and achieve Net-Zero goals in the oil industry.

quote

GB/T 7714-2015 [1] Pavani Cherukupally, Wei Sun, Daryl R. Williams, et al. ACS Applied Polymer Materials, 2022(4). DOI:10.1021/acsapm.1c00944.
MLA [1] Pavani Cherukupally, et al., ACS Applied Polymer Materials, no. 4, 2022, https://doi.org/10.1021/acsapm.1c00944.
APA [1] Pavani Cherukupally, Wei Sun, Daryl R. Williams, Geoffrey A. Ozin, & Amy M. Bilton. (2022). ACS Applied Polymer Materials(4). https://doi.org/10.1021/acsapm.1c00944
IEEE [1] Pavani Cherukupally, Wei Sun, Daryl R. Williams, Geoffrey A. Ozin, and Amy M. Bilton, ACS Applied Polymer Materials, no. 4, 2022, doi: 10.1021/acsapm.1c00944. keywords: {oil/water separation;superwetting sponges;thermosetting polymers;nanosilicon;wax crystallization;resource recovery;Show More}