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Fluorosilicone Composites with Functionalized Graphene Oxide for Advanced Applications AITranslate

Universidad de Chile; Universidad de Chile; Universidad de Chile; Universidad de Concepción; Universidad de Concepción; Chile|Millennium Institute for Subatomic physics at high energy frontier − SAPHIR;Instituto de Ciencia y Tecnología de Polímeros (ICTP);Instituto de Ciencia y Tecnología de Polímeros (ICTP);Instituto de Ciencia y Tecnología de Polímeros (ICTP); Universidad de Concepción
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Publisher: ACS
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Abstract AITranslate

In this work, we develop fluorosilicone elastomer (FSE) compounds with advanced properties by incorporating graphene oxides functionalized with vinyltrimethoxysilane (GO-V) and allyl isocyanate (GO-A). The morphology and structure of the graphene oxides were characterized confirming the successful functionalization, with contents of functional groups of 9.80 and 3.60% for GO-V and GO-A, respectively. The strong elastomer–graphene oxide interaction accelerates the crosslinking reaction and causes an important enhancement of the mechanical properties and thermal stability of composites. In addition, the swelling resistance to acid, base, and organic solvents is improved by more than 30%. These functional properties make FSE/GO composites a promising new class of advanced materials, expanding their potential application in edge technologies, spanning the manufacture of automotive components, aerospace and aviation parts, oil, gas, and petrochemical components, among others, particularly, seals, gaskets, valves and pipelines, or different components exposed to oil or solvent and high temperatures that require higher performance compared to conventional FSE products.

KeyWords AITranslate

fluorosilicone elastomer graphene oxide functionalization mechanical properties thermal properties swelling resistance
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Basic Information:

DOI:https://doi.org/10.1021/acsapm.3c00949

Chinese Library Classification Number:

Citation Information:

In this work, we develop fluorosilicone elastomer (FSE) compounds with advanced properties by incorporating graphene oxides functionalized with vinyltrimethoxysilane (GO-V) and allyl isocyanate (GO-A). The morphology and structure of the graphene oxides were characterized confirming the successful functionalization, with contents of functional groups of 9.80 and 3.60% for GO-V and GO-A, respectively. The strong elastomer–graphene oxide interaction accelerates the crosslinking reaction and causes an important enhancement of the mechanical properties and thermal stability of composites. In addition, the swelling resistance to acid, base, and organic solvents is improved by more than 30%. These functional properties make FSE/GO composites a promising new class of advanced materials, expanding their potential application in edge technologies, spanning the manufacture of automotive components, aerospace and aviation parts, oil, gas, and petrochemical components, among others, particularly, seals, gaskets, valves and pipelines, or different components exposed to oil or solvent and high temperatures that require higher performance compared to conventional FSE products.

quote

GB/T 7714-2015 [1] Ernesto AguilaToledo, Santiago MaldonadoMagnere, Mehrdad YazdaniPedram, et al. ACS Applied Polymer Materials, 2023(5). DOI:10.1021/acsapm.3c00949.
MLA [1] Ernesto AguilaToledo, et al., ACS Applied Polymer Materials, no. 5, 2023, https://doi.org/10.1021/acsapm.3c00949.
APA [1] Ernesto AguilaToledo, Santiago MaldonadoMagnere, Mehrdad YazdaniPedram, Allan BascuñanHeredia, Mohamed Redoine Dahrouch, Francisco Molina, Marianella Hernández Santana, Raquel Verdejo, Miguel A. LopezManchado, & Héctor AguilarBolados. (2023). ACS Applied Polymer Materials(5). https://doi.org/10.1021/acsapm.3c00949
IEEE [1] Ernesto AguilaToledo, Santiago MaldonadoMagnere, Mehrdad YazdaniPedram, Allan BascuñanHeredia, Mohamed Redoine Dahrouch, Francisco Molina, Marianella Hernández Santana, Raquel Verdejo, Miguel A. LopezManchado, and Héctor AguilarBolados, ACS Applied Polymer Materials, no. 5, 2023, doi: 10.1021/acsapm.3c00949. keywords: {fluorosilicone elastomer;graphene oxide functionalization;mechanical properties;thermal properties;swelling resistance}