Nickel Isonicotinate Framework with Optimal Pore Structure for Complete Discrimination of Hexane Isomers AITranslate

Basic Information:

DOI：https://doi.org/10.1021/acsmaterialslett.3c01278

Chinese Library Classification Number:

Citation Information:

Efficient separation of physicochemically similar alkanes is of vital importance. Adsorptive separation utilizing porous materials such as metal–organic frameworks with tunable pore structure and surface functionality represents an energy-efficient technology. In this study, we demonstrate successful separation of alkanes with varying degree of branching using a microporous nickel isonicotinate framework, Ni(4-PyC)2. Its 2-fold interpenetrated diamondoid structure with well-suited pore size enables selective adsorption of linear and monobranched hexane isomers, while excluding dibranched isomer. Breakthrough experiments validated its capability to completely discriminate all three hexane isomers. Ab initio calculations combined with in situ infrared spectroscopic analysis unveiled the nature of host–guest interactions and differences in the binding energies and diffusion barriers among the isomers. Having well-balanced adsorption uptakes (146 and 79 mg g–1 of nHEX and 3MP), high nHEX/DMB uptake ratio (12.2) and fast kinetics, Ni(4-PyC)2 stands out as a promising adsorbent for complete separation of hexane isomers under ambient conditions.