Flux Pinning Research Progress of ‘11’ System Iron-Based Superconducting Materials AITranslate
Abstract AITranslate
With the gradual advancement of the practicality of superconducting materials in more and more fields such as superconducting motors,superconducting cables,levitated superconducting magnet trains,and superconducting magnets,the demand for the scale and industrialization of superconducting materials has become increasingly urgent. Developing more advanced superconducting materials and studying the mechanism of their superconducting properties are the foundation for achieving superconducting practicality. For Class Ⅱ superconductors such as iron based materials,a mixed state of normal and superconducting states will occur under a certain external magnetic field and temperature. This mixed state has characteristics that high upper critical magnetic field and large critical current,which making it possible for superconducting materials to be practical. Relatively speaking,in order to expand the application range of superconductivity,it is necessary to improve related superconducting properties like the upper critical magnetic field and critical current of superconductors. The "11" series material,which is easily prepared and non-toxic in iron-based superconductors has rich superconducting properties while being stable for impurities,and the simplest layered tetragonal crystal makes it a premium platform for studying and improving superconducting properties. Currently,considerable progress has been made in the study of the mechanisms for improving the performance of these superconducting properties. Based on Dew-Hughes theory standard,materials can be roughly divided into two categories according to their pinning properties:δTc pinning is generated by the fluctuation of the transition temperature Tc in the sample and the other type that δl pinning is caused by spatial changes in the average free path of charge carriers. Based on this theory,the type and morphology of pinning were determined,and on the temperature range from 4.25 to 14 K,the transformation of the pinning mechanism was also observed. The influence of different magnetic field strengths from 0 to 20 kOe and two magnetic field directions about perpendicular and paralleled to the c-axis of the material on the pinning mechanism was also observed. And some factors unrelated to the pinning force density curve were attempted to be excluded and discussed the standard for obtaining the normalized magnetic field h value source in the pinning curve. The conclusion was that a more suitable and unified upper critical magnetic field (Hc2)should be chosen instead of an irreversible field (Hirr)to reduce the impact of data errors on the experimental results. By analyzing the behavior curves of the critical current and magnetic field of materials and comparing them with the performance of other superconducting materials,more information could be obtained. Under the consideration of thermal fluctuations (Ginzburg number-1×10−3),Griessen theory model under collective pinning theory was used to determine the type of pinning and verified with the conclusions under Dew-Hughes theory standards. Also considering the strong and weak pinning theories under different magnetic fields to fit and analyze the data,as well as considering the influence of magnetic relaxation on pinning transformation and compared and analyzing it using multiple theories. It was found that the pinning mechanism might be dominated by multiple mechanisms rather than one. It was attempted to integrate several possible pinning types into the same formula and tested them under different magnetic field intensities to obtain the transformation process and degree of influence of the pinning mechanism in different environments,and also attempted to combine the weak pinning theory with the strong pinning theory,using the weak pinning theory at low fields,the strong pinning theory at high fields,and the combination of the two theories at mid field to describe the critical current curves under different magnetic fields. It was undeniable that Dew Hughes model could provide with a very powerful basis for analyzing the superconducting pinning mechanism,but more and more studies had found that relying solely on Dew-Hughes model was no longer sufficient to explain the increasingly in-depth pinning mechanism research. Currently,attempts were being made to combine different and diverse theoretical models to compensate for the limitations of a single theory,achieve a more comprehensive and accurate description of pinning behavior,understand the mechanism of superconducting flux pinning,and seek methods to improve superconducting performance,ultimately achieving the goal of promoting the practicality of superconducting materials. Although there might be differences or conflicts among the various viewpoints introduced,each viewpoint achieved logical self-consistency and provided an angle and method for analyze the pinning mechanism of superconducting materials. Obviously,in the process of continuously exploring its pinning essence,the current theoretical models had become increasingly difficult to achieve expectations,which might also be one of the reasons for the current disagreement. Therefore,a more appropriate theoretical model might be one of the most effective methods to solve the current problem,and it was also an important work to further achieve practicality.
KeyWords AITranslate
[1]Yoichi K,Takumi W,Masahiro H,Hideo H. Iron-based layered superconductor La[O(1–x)F(x)]FeAs (x=0.05~0.12)with Tc=26 K [J]. Journal of the American Chemical Society,2008,130(11):3296.
[2]Fang M H,Pham H M,Qian B,Liu T J,Vehstedt E K,Liu Y,Spinu L,Mao Z Q. Superconductivity close to magnetic instability in Fe(Se1–xTex)0.82 [J]. Physical Review B,2008,78(22):4503.
[3](李小宝,古宏伟,黄大兴,陈玉雷,杨坤. YBa2Cu3O7–δ高温超导带材双面磁控溅射镀铜研究 [J]. 铜业工程,2023,(6):31.)
X B Li,H W Gu,D X Huang,Y L Chen,K Yang. YBa2Cu3O7–δ high-temperature superconducting tape prepared by double sided magnetron sputtering with copper plating [J]. Copper Engineering,2023,(6):31.
[4]Lu X F,Wang N Z,Wu H,Wu Y P,Zhao D,Zeng X Z,Luo X G,Wu T,Bao W,Zhang G H,Huang F Q,Huang Q Z,Chen X H. Coexistence of superconductivity and antiferromagnetism in (Li0.8Fe0.2)OHFeSe [J]. Nature Materials,2015,14(3):325.
[5](金艳营,韩徐,蒋艳玲,周新红,马丽,谢清连. Tl-2223超导薄膜的快速烧结新工艺研究 [J]. 稀有金属,2024,48(1):43.)
Y Y Jin,X Han,Y L Jiang,X H Zhou,L Ma,Q L Xie. New rapid sintering process of Tl-2223 superconducting films [J]. Chinese Journal of Rare Metals,2024,48(1):43.
[6](廖亮,张岩岗,袁章福,赵和明,王洪,赵宏欣. 碳钢表面铜-碳纤维薄膜的制备及腐蚀 [J]. 有色金属工程,2022,12(10):54.)
L Liao,Y G Zhang,Z F Yuan,H M Zhao,H Wang,H X Zhao. Preparation and corrosion of copper-carbon fiber film on carbon steel [J]. Nonferrous Metals Engineering,2022,12(10):54.
[7](李亚敏,范树通,吴显崟,刘洪军. NiCrAlFe合金薄带制备过程织构的遗传及其与电阻方向性的关系 [J]. 锻压技术,2024,49(11):62.)
Y M Li,S T Fan,X Y Wu,H J Zhao. Inheritance of texture and its relationship with resistance directionality during thin strip preparation process of NiCrAlFe alloy [J]. Forging & Stamping Technology,2024,49(11):62.
[8](方学彬,李贵,许成. 金属材料的晶体建模方法及有限元数值模拟 [J]. 塑性工程学报,2024,31(3):119.)
X B Fang,G Li,C Xu. Crystal modeling methods and finite element numerical simulation of metal materials [J]. Journal of Plasticity Engineering,2024,31(3):119.
[9]Hughes D. Flux pinning mechanisms in type Ⅱ superconductors [J]. Philosophical Magazine,1974,30(2):293.
[10]Bonura M,Giannini E,Viennois R,Senatore C. Temperature and time scaling of the peak-effect vortex configuration in FeTe0.7Se0.3 [J]. Physical Review B,2012,85(13):4532.
[11]Griessen R,Wen H H,Van D A J J,Dam B,Rector J,Schnack H G,Libbrecht S,Osquiguil E,Bruynseraede Y. Evidence for mean free path fluctuation induced pinning in YBa2Cu3O7 and YBa2Cu4O8 films [J]. Physical Review Letters,1994,72(12):1910.
[12]Das P,Thakur A D,Anil K Y,Tomy C V,Lees M R,Balakrishnan G,Ramakrishnan S,Grover A K. Magnetization hysteresis and time decay measurements in FeSe0.50Te0.50:evidence for fluctuation in mean free path induced pinning [J]. Physical Review B,2011,84(12):4526.
[13]Yadav C S,Paulose P L. The flux pinning force and vortex phase diagram of single crystal FeTe0.60Se0.40 [J]. Solid State Communications,2011,151(3):216.
[14]Pan Y Q,Zhou N,Lin B C,Wang J H,Zhu Z W,Zhou W,Sun Y,Shi Z X. Anisotropic critical current density and flux pinning mechanism of Fe1+yTe0.6Se0.4 single crystals [J]. Superconductor Science and Technology,2022,35(1):5002.
[15]Tanaka Y,Mizuguchi Y,Miura O. FeTe0.6Se0.4 bulk single crystals with high critical current densities under magnetic fields [J]. Journal of Physics:Conference Series,2017,871(1):2064.
[16]Sun Y,Taen T,Yu J T,Pyon S,Shi Z X,Tsuyoshi T. Magnetic relaxation and collective vortex creep in FeTe0.6Se0.4 single crystal [J]. Europhysics Letters,2013,103(57):13.
[17]Sun Y,Pyon S,Tsuyoshi T,Ryo K,Tatsuya W,Shigeru K,Yuji M,Takasada S. Critical current density,vortex dynamics and phase diagram of single-crystal FeSe [J]. Physical Review B,2015,92(14):4509.
[18]Liu T J,Ke X,Qian B,Hu J,Fobes D,Vehstedt E K,Pham H,Yang J H,Fang M H,Spinu L,Schiffer P,Liu Y,Mao Z Q. Charge-carrier localization induced by excess Fe in the superconductor Fe1+yTe1–xSex [J]. Physical Review B,2009,80(17):4509.
[19]Miu D,Noji T,Adachi T,Koike Y,Miu L. On the nature of the second magnetization peak in FeSe1–xTex single crystals [J]. Physical Review B,2012,25(11):5009.
[20]Yuan P S,Xu Z T,Ma Y W,Sun Y,Tamegai T. Angular-dependent vortex pinning mechanism and magneto-optical characterizations of FeSe0.5Te0.5 thin films grown on CaF2 substrates [J]. Superconductor Science and Technology,2016,29(3):5013.
[21]Hagen B,Ruben H,Kazumasa I,Sebastian M,Alberto S,Marina P,Ludwig S,Kornelius N,Jens H. Deposition and properties of Fe(Se,Te)thin films on vicinal CaF2 substrates [J]. Superconductor Science and Technology,2017,30(11):5008.
[22]Si W D,Han S J,Shi X Y,Steven N,Jaroszynski J,Goyal A,Li Q. High current superconductivity in FeSe0.5Te0.5-coated conductors at 30 tesla [J]. Nature Communications,2013,4:1347.
[23]Bellingeri E,Kawale S,Caglieris F,Braccini V,Lamura G,Pellegrino L,Sala A,Putti M,Ferdeghini C,Jost A. High field vortex phase diagram of Fe(Se,Te)thin films [J]. Superconductor Science and Technology,2014,27(4):4007.
[24]Derya F,Nilay K G,Yakıncı K,Ahmet E,Faruk K,Mehmet E Y,Özçelik B. The cooling rate effect on structure and flux pinning force of FeTeSe single crystal deposited by self-flux method [J]. Journal of Materials Science:Materials in Electronics,2018,29(8):6477.
[25]Liu Y,Kremer R K,Lin C T. Superconductivity and vortex pinning in Fe1.04Te0.60Se0.40 single crystal [J]. Europhysics Letters Association Europhysics Letters,2010,92(57):4.
[26]Leo A,Grimaldi G,Guarino A,Avitabile F,Nigro A,Galluzzi A. Vortex pinning properties in Fe-chalcogenides [J]. Superconductor Science and Technology,2015,28(12):5001.
[27]Taen T,Tsuchiya Y,Nakajima Y,Tamegai T. Critical current densities and vortex dynamics in FeTexSe1–x single crystals [J]. Physica C:Superconductivity and its Applications,2010,470(20):1106.
[28]Taen T,Nakajima Y,Tsuyoshi T,Hisashi K. Enhancement of critical current density and vortex activation energy in proton-irradiated Co-doped BaFe2As2 [J]. Physical Review B,2012,86(9):4527.
[29]Ghorbani S R,Wang X L,Shahbazi M,Dou S X,Lin C T. Fluctuation of mean free path and transition temperature induced vortex pinning in (Ba,K)Fe2As2 superconductors [J]. Applied Physics Letters,2012,100(21):2601.
[30]Hossaini S J,Ghorbani S R,Arabi H,Wang X L,Lin C T. Temperature and field dependence of the flux pinning mechanisms in Fe1.06Te0.6Se0.4 single crystal [J]. Solid State Communications,2016,246(38):29.
[31]Mario S,Ilaria P,Antonio L,Angela N,Gaia G,Carlo F,Corrado S,Marco G,Antonio T,Valeria B. Nanoscale analysis of superconducting Fe(Se,Te)epitaxial thin films and relationship with pinning properties [J]. Scientific Reports,2021,11(2):0100.
[32]Küpfer H,Meier H R,Reichert T. Field dependent change of the critical current density in neutron irradiated A 15 superconductors with grain boundary pinning [J]. Journal of Applied Physics,1980,51(2):1121.
[33]Baumgartner T,Eisterer M,Weber H W,Flükiger R,Scheuerlein C,Bottura L. Efects of neutron irradiation on pinning force scaling in state of the art Nb3Sn wires [J]. Superconductor Science and Technology,2014,27(1):5005.
[34]Galluzzi A,Buchkov K,Tomov V,Nazarova E,Leo A,Grimaldi G,Nigro A,Pace S,Polichetti M. Evidence of pinning crossover and the role of twin boundaries in the peak effect in FeSeTe iron based superconductor [J]. Superconductor Science and Technology,2018,31(1):5014.
[35]Blatter G,Feigel'man M V,Geshkenbein V B,Larkin A I,Vinokur V M. Vortices in high-temperature superconductors [J]. Reviews of Modern Physics,1994,66(4):1125.
[36]Terence H,Doussal P L,Nelson D R,Vinokur V M. Flux pinning and forced vortex entanglement by splayed columnar defects [J]. Physical Review Letters,1993,71(21):3545.
[37]Plain J,Puig T,Sandiumenge F,Obradors X,Rabier J. Microstructural influence on critical currents and irreversibility line in melt-textured YBa2Cu3O7–x reannealed at high oxygen pressure [J]. Physical Review B,2002,65(10):4526.
[38]Wu Z F,Wang Z H,Tao J,Qiu L,Yang S G,Wen H H. Flux pinning and relaxation in FeSe0.5Te0.5 single crystals [J]. Superconductor Science and Technology,2016,29(3):5006.
Basic Information:
DOI:10.13373/j.cnki.cjrm.XY23080006
Chinese Library Classification Number:TF803.21
Citation Information:
With the gradual advancement of the practicality of superconducting materials in more and more fields such as superconducting motors,superconducting cables,levitated superconducting magnet trains,and superconducting magnets,the demand for the scale and industrialization of superconducting materials has become increasingly urgent. Developing more advanced superconducting materials and studying the mechanism of their superconducting properties are the foundation for achieving superconducting practicality. For Class Ⅱ superconductors such as iron based materials,a mixed state of normal and superconducting states will occur under a certain external magnetic field and temperature. This mixed state has characteristics that high upper critical magnetic field and large critical current,which making it possible for superconducting materials to be practical. Relatively speaking,in order to expand the application range of superconductivity,it is necessary to improve related superconducting properties like the upper critical magnetic field and critical current of superconductors. The "11" series material,which is easily prepared and non-toxic in iron-based superconductors has rich superconducting properties while being stable for impurities,and the simplest layered tetragonal crystal makes it a premium platform for studying and improving superconducting properties. Currently,considerable progress has been made in the study of the mechanisms for improving the performance of these superconducting properties. Based on Dew-Hughes theory standard,materials can be roughly divided into two categories according to their pinning properties:δTc pinning is generated by the fluctuation of the transition temperature Tc in the sample and the other type that δl pinning is caused by spatial changes in the average free path of charge carriers. Based on this theory,the type and morphology of pinning were determined,and on the temperature range from 4.25 to 14 K,the transformation of the pinning mechanism was also observed. The influence of different magnetic field strengths from 0 to 20 kOe and two magnetic field directions about perpendicular and paralleled to the c-axis of the material on the pinning mechanism was also observed. And some factors unrelated to the pinning force density curve were attempted to be excluded and discussed the standard for obtaining the normalized magnetic field h value source in the pinning curve. The conclusion was that a more suitable and unified upper critical magnetic field (Hc2)should be chosen instead of an irreversible field (Hirr)to reduce the impact of data errors on the experimental results. By analyzing the behavior curves of the critical current and magnetic field of materials and comparing them with the performance of other superconducting materials,more information could be obtained. Under the consideration of thermal fluctuations (Ginzburg number-1×10−3),Griessen theory model under collective pinning theory was used to determine the type of pinning and verified with the conclusions under Dew-Hughes theory standards. Also considering the strong and weak pinning theories under different magnetic fields to fit and analyze the data,as well as considering the influence of magnetic relaxation on pinning transformation and compared and analyzing it using multiple theories. It was found that the pinning mechanism might be dominated by multiple mechanisms rather than one. It was attempted to integrate several possible pinning types into the same formula and tested them under different magnetic field intensities to obtain the transformation process and degree of influence of the pinning mechanism in different environments,and also attempted to combine the weak pinning theory with the strong pinning theory,using the weak pinning theory at low fields,the strong pinning theory at high fields,and the combination of the two theories at mid field to describe the critical current curves under different magnetic fields. It was undeniable that Dew Hughes model could provide with a very powerful basis for analyzing the superconducting pinning mechanism,but more and more studies had found that relying solely on Dew-Hughes model was no longer sufficient to explain the increasingly in-depth pinning mechanism research. Currently,attempts were being made to combine different and diverse theoretical models to compensate for the limitations of a single theory,achieve a more comprehensive and accurate description of pinning behavior,understand the mechanism of superconducting flux pinning,and seek methods to improve superconducting performance,ultimately achieving the goal of promoting the practicality of superconducting materials. Although there might be differences or conflicts among the various viewpoints introduced,each viewpoint achieved logical self-consistency and provided an angle and method for analyze the pinning mechanism of superconducting materials. Obviously,in the process of continuously exploring its pinning essence,the current theoretical models had become increasingly difficult to achieve expectations,which might also be one of the reasons for the current disagreement. Therefore,a more appropriate theoretical model might be one of the most effective methods to solve the current problem,and it was also an important work to further achieve practicality.
quote
| GB/T 7714-2015 | [1] Shuai Zhao, Fang Yang, Jixing Liu, et al. Flux Pinning Research Progress of ‘11’ System Iron-Based Superconducting Materials[J]. Chinese Journal of Rare Metals, 2025, 49(6): 884-897. DOI:10.13373/j.cnki.cjrm.XY23080006. |
| MLA | [1] Shuai Zhao, et al., "Flux Pinning Research Progress of ‘11’ System Iron-Based Superconducting Materials." Chinese Journal of Rare Metals, vol. 49, no. 6, 2025, pp. 884-897, https://doi.org/10.13373/j.cnki.cjrm.XY23080006. |
| APA | [1] Shuai Zhao, Fang Yang, Jixing Liu, Shengnan Zhang, Guo Yan, & Pingxiang Zhang. (2025). Flux Pinning Research Progress of ‘11’ System Iron-Based Superconducting Materials. Chinese Journal of Rare Metals, 49(6), 884-897. https://doi.org/10.13373/j.cnki.cjrm.XY23080006 |
| IEEE | [1] Shuai Zhao, Fang Yang, Jixing Liu, Shengnan Zhang, Guo Yan, and Pingxiang Zhang, "Flux Pinning Research Progress of ‘11’ System Iron-Based Superconducting Materials," Chinese Journal of Rare Metals, vol. 49, no. 6, pp. 884-897, 2025, doi: 10.13373/j.cnki.cjrm.XY23080006. keywords: {iron based superconductor;Fe (SeTe);magnetic flux pinning;pinning type} |
