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Phosphine-Based Hyper-Cross-Linked Polymer-Supported Neutral Gold(I) Complex as a Recyclable Catalyst for the Regioselective Hydration of Alkynes to Ketones AITranslate

Lu Shen; Xingyou Han; Beixuan Dong; Yong Yang; Jiazhi Yang; Feng Li;
Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology; Nanjing University of Science & Technology
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Publisher: ACS
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Abstract AITranslate

Functionalized hyper-cross-linked polymer-supported metal complexes have been developed as heterogeneous catalysts for organic synthesis and have attracted much attention. In this regard, a phosphine-based hyper-cross-linked polymer-supported neutral gold(I) complex, Au@HCPs-PPh3, which is synthesized by incorporation of [(Me2S)AuCl] into a phosphine-based hyper-cross-linked polymer, is proven to be an efficient and general heterogeneous catalyst for the regioselective hydration of a series of alkynes to ketones. Furthermore, the synthesized catalyst is recycled six times without an obvious decrease in the catalytic activity.

KeyWords AITranslate

hypercrosslinked polymers neutral gold(I) complex hydration of alkynes regioselective recyclable catalyst phosphine ligand
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Basic Information:

DOI：https://doi.org/10.1021/acsapm.2c01167

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Citation Information:

Functionalized hyper-cross-linked polymer-supported metal complexes have been developed as heterogeneous catalysts for organic synthesis and have attracted much attention. In this regard, a phosphine-based hyper-cross-linked polymer-supported neutral gold(I) complex, Au@HCPs-PPh3, which is synthesized by incorporation of [(Me2S)AuCl] into a phosphine-based hyper-cross-linked polymer, is proven to be an efficient and general heterogeneous catalyst for the regioselective hydration of a series of alkynes to ketones. Furthermore, the synthesized catalyst is recycled six times without an obvious decrease in the catalytic activity.

quote

GB/T 7714-2015 [1] Lu Shen, Xingyou Han, Beixuan Dong, et al. ACS Applied Polymer Materials, 2022(4). DOI:10.1021/acsapm.2c01167.
MLA [1] Lu Shen, et al., ACS Applied Polymer Materials, no. 4, 2022, https://doi.org/10.1021/acsapm.2c01167.
APA [1] Lu Shen, Xingyou Han, Beixuan Dong, Yong Yang, Jiazhi Yang, & Feng Li. (2022). ACS Applied Polymer Materials(4). https://doi.org/10.1021/acsapm.2c01167
IEEE [1] Lu Shen, Xingyou Han, Beixuan Dong, Yong Yang, Jiazhi Yang, and Feng Li, ACS Applied Polymer Materials, no. 4, 2022, doi: 10.1021/acsapm.2c01167. keywords: {hypercrosslinked polymers;neutral gold(I) complex;hydration of alkynes;regioselective;recyclable catalyst;phosphine ligand}