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Conjugated Copolymers of Poly(arylenevinylene)s: Synthesis by Ring-Opening Metathesis Polymerization, Film Morphology, and Resonant Luminescence from Microspheres AITranslate

YenJen Lin; HsinYu Chiang; Osamu Oki; Soh Kushida; ShuWei Chang; ShihTing Chiu; Yohei Yamamoto; Takuya Hosokai; Masaki Horie;
National Tsing Hua University; National Tsing Hua University; University of Tsukuba; University of Tsukuba; National Tsing Hua University; National Tsing Hua University; University of Tsukuba; National Institute of Advanced Industrial Science and Technology (AIST); National Tsing Hua University
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Publisher: ACS
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Abstract AITranslate

A series of copolymers of poly(arylenevinylene)s have been prepared by ring-opening metathesis polymerization (ROMP) of cyclic conjugated monomers composed of cyclopentadithiophene, bis(thienyl)benzothiadiazole, or bithiophene using a second-generation Grubbs catalyst and the sequential monomer addition technique. The spectroscopic, electrochemical, and morphological properties of these polymers are tailored by changing the chemical structures and fractions of the monomers. The polymers self-assemble to form microspheres (diameter: 2–5 μm), which act as whispering-gallery-mode optical resonators.

KeyWords AITranslate

conjugated copolymers ringopening metathesis polymerization film morphology microspheres resonant luminescence
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Basic Information:

DOI：https://doi.org/10.1021/acsapm.9b00549

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Citation Information:

A series of copolymers of poly(arylenevinylene)s have been prepared by ring-opening metathesis polymerization (ROMP) of cyclic conjugated monomers composed of cyclopentadithiophene, bis(thienyl)benzothiadiazole, or bithiophene using a second-generation Grubbs catalyst and the sequential monomer addition technique. The spectroscopic, electrochemical, and morphological properties of these polymers are tailored by changing the chemical structures and fractions of the monomers. The polymers self-assemble to form microspheres (diameter: 2–5 μm), which act as whispering-gallery-mode optical resonators.

quote

GB/T 7714-2015 [1] YenJen Lin, HsinYu Chiang, Osamu Oki, et al. ACS Applied Polymer Materials, 2019(1). DOI:10.1021/acsapm.9b00549.
MLA [1] YenJen Lin, et al., ACS Applied Polymer Materials, no. 1, 2019, https://doi.org/10.1021/acsapm.9b00549.
APA [1] YenJen Lin, HsinYu Chiang, Osamu Oki, Soh Kushida, ShuWei Chang, ShihTing Chiu, Yohei Yamamoto, Takuya Hosokai, & Masaki Horie. (2019). ACS Applied Polymer Materials(1). https://doi.org/10.1021/acsapm.9b00549
IEEE [1] YenJen Lin, HsinYu Chiang, Osamu Oki, Soh Kushida, ShuWei Chang, ShihTing Chiu, Yohei Yamamoto, Takuya Hosokai, and Masaki Horie, ACS Applied Polymer Materials, no. 1, 2019, doi: 10.1021/acsapm.9b00549. keywords: {conjugated copolymers;ringopening metathesis polymerization;film morphology;microspheres;resonant luminescence}