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Washable Antibacterial Modified Bio-based PA56 with High Toughness AITranslate

East China University of Science and Technology; East China University of Science and Technology;Shanghai Cathay Biotechnology Company Limited, Shanghai 200237;Shanghai Cathay Biotechnology Company Limited, Shanghai 200237; East China University of Science and Technology; East China University of Science and Technology
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Publisher: ACS
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Abstract AITranslate

An effective method was developed for the preparation of a washable antibacterial modified bio-based polyamide 56 (PA56) with high toughness by a simple reactive extrusion technique. In this work, polypentamethylene guanidine hydrochloride (PPMG), as a bio-based antibacterial reagent, was successfully grafted onto a bio-based PA56 polymer. The micromorphology of the samples was studied by scanning electron microscopy, which proved that the addition of ethylene-methyl acrylate-glycidyl methacrylate terpolymer (EMA) greatly improved the compatibility. In addition, the mechanical properties of the modified antibacterial bio-based polyamide were improved, especially the impact toughness of PA56-g-1.0 (1.0 wt % PPMG and 1.0 wt % EMA) could be 48% higher than pure PA56. When the content of PPMG was higher than 1.0%, the inhibition rates of the products against Escherichia coli and Staphylococcus aureus both reached over 99.99%, and such a high inhibition rate would still maintain after 30 washing times with hot water (90 °C) and detergent.

KeyWords AITranslate

biobased PA56 PPMG chemical bonding antibacterial activities washing durability high toughness
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Basic Information:

DOI:https://doi.org/10.1021/acsapm.3c00542

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Citation Information:

An effective method was developed for the preparation of a washable antibacterial modified bio-based polyamide 56 (PA56) with high toughness by a simple reactive extrusion technique. In this work, polypentamethylene guanidine hydrochloride (PPMG), as a bio-based antibacterial reagent, was successfully grafted onto a bio-based PA56 polymer. The micromorphology of the samples was studied by scanning electron microscopy, which proved that the addition of ethylene-methyl acrylate-glycidyl methacrylate terpolymer (EMA) greatly improved the compatibility. In addition, the mechanical properties of the modified antibacterial bio-based polyamide were improved, especially the impact toughness of PA56-g-1.0 (1.0 wt % PPMG and 1.0 wt % EMA) could be 48% higher than pure PA56. When the content of PPMG was higher than 1.0%, the inhibition rates of the products against Escherichia coli and Staphylococcus aureus both reached over 99.99%, and such a high inhibition rate would still maintain after 30 washing times with hot water (90 °C) and detergent.

quote

GB/T 7714-2015 [1] Lili Wang, Haohui Jiang, Yuliu Du, et al. ACS Applied Polymer Materials, 2023(5). DOI:10.1021/acsapm.3c00542.
MLA [1] Lili Wang, et al., ACS Applied Polymer Materials, no. 5, 2023, https://doi.org/10.1021/acsapm.3c00542.
APA [1] Lili Wang, Haohui Jiang, Yuliu Du, Yuanbo Zhao, Yong Guan, & Xiucai Liu. (2023). ACS Applied Polymer Materials(5). https://doi.org/10.1021/acsapm.3c00542
IEEE [1] Lili Wang, Haohui Jiang, Yuliu Du, Yuanbo Zhao, Yong Guan, and Xiucai Liu, ACS Applied Polymer Materials, no. 5, 2023, doi: 10.1021/acsapm.3c00542. keywords: {biobased PA56;PPMG;chemical bonding;antibacterial activities;washing durability;high toughness}