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Nickel-Doped Graphite and Fusible Alloy Bilayer Back Electrode for Vacuum-Free Perovskite Solar Cells AITranslate

Northern Illinois University; National Renewable Energy Laboratory; Northern Illinois University; Northwestern University; Northern Illinois University; Northern Illinois University; Argonne National Laboratory; Northern Illinois University; Argonne National Laboratory; Northwestern University; National Renewable Energy Laboratory; Northern Illinois University
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Publisher: ACS
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Abstract AITranslate

With the rapid development of perovskite solar cells (PSCs), lowering fabrication costs for PSCs has become a prominent challenge for commercialization. At present, gold is commonly used as the back metal electrode in state-of-the-art n-i-p structured PSCs due to its compatible work function, chemical inertness, and high conductivity. However, the high cost of gold and the expensive and time-consuming vacuum-based thin-film coating facilities may impede large-scale industrialization of PSCs. Here, we report a bilayer back electrode configuration consisting of an Ni-doped natural graphite layer with a fusible Bi-In alloy. This back electrode can be deposited in a vacuum-free approach and enables PSCs with a power conversion efficiency of 21.0%. These inexpensive materials and facile ambient fabrication techniques provide an appealing disruptive solution to low-cost PSC industrialization.

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DOI:https://doi.org/10.1021/acsenergylett.3c00852

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Citation Information:

With the rapid development of perovskite solar cells (PSCs), lowering fabrication costs for PSCs has become a prominent challenge for commercialization. At present, gold is commonly used as the back metal electrode in state-of-the-art n-i-p structured PSCs due to its compatible work function, chemical inertness, and high conductivity. However, the high cost of gold and the expensive and time-consuming vacuum-based thin-film coating facilities may impede large-scale industrialization of PSCs. Here, we report a bilayer back electrode configuration consisting of an Ni-doped natural graphite layer with a fusible Bi-In alloy. This back electrode can be deposited in a vacuum-free approach and enables PSCs with a power conversion efficiency of 21.0%. These inexpensive materials and facile ambient fabrication techniques provide an appealing disruptive solution to low-cost PSC industrialization.

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GB/T 7714-2015 [1] Mengyuan Li, So Yeon Park, Jianxin Wang, et al. ACS Energy Letters, 2023(8). DOI:10.1021/acsenergylett.3c00852.
MLA [1] Mengyuan Li, et al., ACS Energy Letters, no. 8, 2023, https://doi.org/10.1021/acsenergylett.3c00852.
APA [1] Mengyuan Li, So Yeon Park, Jianxin Wang, Ding Zheng, Owen S. Wostoupal, Xudong Xiao, Zhenzhen Yang, Xun Li, Benjamin T. Diroll, Tobin J. Marks, Kai Zhu, & Tao Xu. (2023). ACS Energy Letters(8). https://doi.org/10.1021/acsenergylett.3c00852
IEEE [1] Mengyuan Li, So Yeon Park, Jianxin Wang, Ding Zheng, Owen S. Wostoupal, Xudong Xiao, Zhenzhen Yang, Xun Li, Benjamin T. Diroll, Tobin J. Marks, Kai Zhu, and Tao Xu, ACS Energy Letters, no. 8, 2023, doi: 10.1021/acsenergylett.3c00852.