Suppressed Ion Migration in Reduced-Dimensional Perovskites Improves Operating Stability AITranslate

Basic Information:

DOI：https://doi.org/10.1021/acsenergylett.9b00892

Chinese Library Classification Number:

Citation Information:

Impressive progress in halide perovskite solar cells motivates further work to improve operating stability. It is known that ion-migration-driven decomposition represents a degradation pathway in perovskite solar cells and that it can occur within the perovskite material even in well-encapsulated devices. Here we find that quasi-two-dimensional (2.5D) perovskites suppress this ion-migration-induced degradation. Using TOF-SIMS, we confirm that iodide migration occurs in bulk perovskite photovoltaic devices operating at their maximum power point (MPP). We observe that iodine ions migrate across the spiro-OMeTAD layer to the spiro/gold contact interface, oxidizing and deteriorating the gold at the interface. In contrast, we find that large ⟨n⟩ 2.5D perovskites exhibit a significantly reduced rate of ion migration compared to 3D devices and exhibit less than 1% relative PCE loss in over 80 h of continuous operation at MPP, whereas the PCE of 3D devices diminishes by more than 50% within the first 24 h.