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Naphthyl Methylacrylate Block Copolymer Insulators for Application in Pentacene Organic Thin-Film Transistors AITranslate

Jiufu Zhu; Bo Yu; Dacheng Bai; Dongye Pan; Jiawei Zou; Xiaoyu Shi; Shuxiang Ding; Bowen Zhang; Donghang Yan; Xiaojuan Hao; Zuosen Shi; Zhanchen Cui;
Jilin University; Changchun Institute of Applied Chemistry;Sanyou Intelligent Manufacturing & Technology Co. Ltd.;Sanyou Intelligent Manufacturing & Technology Co. Ltd.; Jilin University; Jilin University; Jilin University; Jilin University; Changchun Institute of Applied Chemistry;CSIRO Manufacturing, Clayton 3168; Jilin University; Jilin University
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Publisher: ACS
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Abstract AITranslate

In this paper, we prepared a series of aryl group functionalized polymers, via the reversible addition–fragmentation chain transfer (RAFT) polymerization, used as insulator layer materials for pentacene thin-film transistors. The poly(methyl methacrylate) (PMMA)-based block polymers contain naphthyl side groups that could induce ordered morphology of pentacene due to π–π interaction. Furthermore, the block polymers can effectively increase the dielectric constant (6.59), resulting in a threshold voltage drop from −15 V to −7 V.

KeyWords AITranslate

organic thin film transistors pentacene dielectric materials RAFT polymerization polymer
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Basic Information:

DOI：https://doi.org/10.1021/acsapm.2c00779

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Citation Information:

In this paper, we prepared a series of aryl group functionalized polymers, via the reversible addition–fragmentation chain transfer (RAFT) polymerization, used as insulator layer materials for pentacene thin-film transistors. The poly(methyl methacrylate) (PMMA)-based block polymers contain naphthyl side groups that could induce ordered morphology of pentacene due to π–π interaction. Furthermore, the block polymers can effectively increase the dielectric constant (6.59), resulting in a threshold voltage drop from −15 V to −7 V.

quote

GB/T 7714-2015 [1] Jiufu Zhu, Bo Yu, Dacheng Bai, et al. ACS Applied Polymer Materials, 2022(4). DOI:10.1021/acsapm.2c00779.
MLA [1] Jiufu Zhu, et al., ACS Applied Polymer Materials, no. 4, 2022, https://doi.org/10.1021/acsapm.2c00779.
APA [1] Jiufu Zhu, Bo Yu, Dacheng Bai, Dongye Pan, Jiawei Zou, Xiaoyu Shi, Shuxiang Ding, Bowen Zhang, Donghang Yan, Xiaojuan Hao, Zuosen Shi, & Zhanchen Cui. (2022). ACS Applied Polymer Materials(4). https://doi.org/10.1021/acsapm.2c00779
IEEE [1] Jiufu Zhu, Bo Yu, Dacheng Bai, Dongye Pan, Jiawei Zou, Xiaoyu Shi, Shuxiang Ding, Bowen Zhang, Donghang Yan, Xiaojuan Hao, Zuosen Shi, and Zhanchen Cui, ACS Applied Polymer Materials, no. 4, 2022, doi: 10.1021/acsapm.2c00779. keywords: {organic thin film transistors;pentacene;dielectric materials;RAFT polymerization;polymer}