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Additive Manufacturing

Additive Manufacturing

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4D printing of poly-Pickering high internal phase emulsions to assembly a thermo-responsive shape-memory hierarchical macroporous scaffold

Because of their enormous potential in biofabrication, adsorption, catalysis, and energy conversion applications, there has been substantial attention to fabricating 4D printed hierarchically porous structures from the molecular level to the macroscopic dimensions. To this end, an understanding of the structure-feature relationship of smart materials in 4D printing is necessary to design innovative constructs, which are not limited to any specific degree of freedom. Here, we report on the fabrication of thermo-responsive macroporous polymerized-high internal phase emulsions (poly-HIPEs) through 3D printing of Pickering-type HIPEs. The oil-in-water Pickering-HIPE-based inks contained methylcellulose/kappa-carrageenan blend (non-crosslinked) as a continuous phase, which was colloidally stabilized by a hybrid of cellulose nanocrystals and cellulose nanofibers. The Pickering-HIPE-based inks showed a non-linear and time-dependent oscillatory response with excellent viscoelastic interfacial properties. The poly-Pickering-HIPEs were readily fabricated by in-situ crosslinking of Pickering-HIPEs during hot-melt extrusion-based printing, which produced a series of 3D printed thermo-responsive hierarchical macroporous structures. The 4D printed objects presented a highly interconnected open-cell porous structure, which was thermo-responsive in nature. Moreover, these 4D structures showed high mechanical strength with outstanding self-recovery performance. Our results offer the prospect of developing a thermo-responsive macroporous construct having shape memory features at different temperatures by regulating emulsion formulation. Graphical Download : Download high-res image (248KB) Download : Download full-size image

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An airbrush 3D printer: Additive manufacturing of relaxor ferroelectric actuators

Highlights • Airbrush 3D printer was proposed for accessible contact-less additive manufacturing. • The printer attained resolutions of 0 . 5 mm (in-plane) and 0 . 63 μ m (thickness). • It proved a robust method for 3D printing materials that are difficult to deposit. • Bending cantilever actuators were printed from P(VDF-TrFE-CTFE) electroactive polymer. • The actuators produced 340 μ m (quasi-static) and 3 . 7 mm (resonant) tip deflections. The additive manufacturing of electroactive polymer (EAP) devices poses significant challenges due to their distinct structure and dissimilar properties of their constituent materials. It requires deposition of multiple functional materials with different properties, achieving μ m -scale resolution in layer thickness, and executing incremental deposition and curing steps while preserving the previously deposited functional material layers. This study introduces an airbrush 3D printer concept and employs it for fabricating EAP transducers. An airbrush 3D printer was constructed by adapting a standard extrusion printer platform and integrating it with a two fluid atomizer (i.e. an airbrush) as the deposition tool. A process was developed for printing of the bending P(VDF-TrFE-CTFE) actuators with carbon black electrodes, and actuators with a single and dual EAP layers were fabricated. The airbrush printer attained in-plane resolution of 0 . 5 mm , thickness resolutions of 0.63 μ m and allowed atomizing up to 7% P(VDF-TrFE-CTFE) solutions. The 18 mm × 4 mm EAP actuators achieved 340 μ m (440 V p p ) and 3.7 mm (400 V p p , 104 Hz) tip deflections respectively in quasi-static and resonant operation. Airbrush printing therefore proved to be a robust method for printing precursor materials with a wide range of properties, and is anticipated to be a versatile approach for printing other passive and stimuli-responsive materials and devices. Graphical abstract Download : Download high-res image (310KB) Download : Download full-size image

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Heterogeneous microstructure development in additive friction-stir deposited Al-Mg-Si alloy

Aluminum alloy 6061-T6511 was printed by additive friction stir deposition onto a cast aluminum A206-T4 plate. Metallography, X-ray powder diffraction, X-ray pole figure analysis, and electron backscatter diffraction of the center, advancing side, and retreating side of the 6061 deposit reveals different texture and grain structure characteristics across the transverse direction and through each layer. These distinct microstructural domains are indicative of spatially varied temperature, strain rate, and strain accumulation during deposition, and consequently of regions differing in the fraction of dynamic recovery and dynamic recrystallization during deposition. Hardness mapping over the complete cross section at 0.75 mm resolution shows the alloy continues to age after active deposition, and hardness increases over the 5 mm nearest the final printed layer. Additional mapping at 0.10 mm resolution shows intralayer hardness variations of the deposit on the retreating side. These observations demonstrate that complex and non-uniform thermal-mechanical transients occur during additive friction stir deposition, resulting in spatially non-uniform microstructure and properties.

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Metastable carbides and their impact on recrystallisation in IN738LC processed by selective laser melting

Selective laser melting of nickel based superalloys opens up new possibilities for gas turbine engine manufacturers; namely, efficient production of low component volumes, decreased component cost through reduced post-machining procedures and access to new component geometries that cannot be fabricated by conventional processing methods. However, processing high performance nickel-based superalloys components via additive manufacturing, without the occurrence of defects, is challenging and requires a better understanding of the resulting microstructure, especially as different compositions can lead to significant changes in the microstructure obtained. In addition, carefully selected post-processing heat-treatments are required to alter the microstructure and attain the required mechanical properties. In this study, the microstructure of the nickel base superalloy IN738LC has been characterised in the as-deposited and stress relieved heat-treated states, as well as following high temperature heat treatments. The data acquired highlights the influence of the stress relief step on the recrystallisation temperature and its relation with the distribution of carbide particles present in the alloy`s microstructure.

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Improving mechanical properties of wire arc additively manufactured AA2196 Al–Li alloy by controlling solidification defects

Additive manufacturing has advantages of cutting the time from design to making new parts but it suffers from metallurgical defects such as porosity. For example, wired arc additive manufacturing(WAAM) of new alloys such as Al–Li alloys is very challenging due to the fact that the porosity level is so high as to degrade not only fatigue life but also the static mechanical properties. In this study, we found that large chains of porosity could form at the interdendritic liquid during WAAM of an AA2196 Al–Li alloy. After T6 heat treatment, those chains of porosity actually grow bigger than the as-deposit state, with the microporosity size over 50 µm increasing from 2.8% to 5.8% and the maximum size grow up to 107 µm. Using X-ray Computed Tomography (XCT), we have quantified the spatial distribution of microporosity as a function of hot deformation after WAAM. It was found that the chain of microporosity along the direction of deposition could be effectively eliminated by controlling the strain. Combining the 42% hot deformation and T6 heat treatment, the closure of microporosity together with nano-sized T1 precipitates can be achieved and yield tensile strength (YTS) can be improved by 199%, the ultimate tensile strength (UTS) can be increased by 168%, and the elongation can be extended by 460%, reaching up to 372 MPa, 439 MPa, and 6.9%, respectively. Therefore, the solidification defects during WAAM can be remediated by applying proper hot deformation which is extremely useful for the Al–Li alloys with a long solidification range and high susceptibility to solidification cracking.

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Strength/ductility trade-off of Laser Powder Bed Fusion Ti-6Al-4V: Synergetic effect of alpha-case formation and microstructure evolution upon heat treatments

Post-processing heat treatments (HT) are performed on Ti-6Al-4V components fabricated by Laser Powder Bed Fusion (L-PBF) to release the residual stresses and transform the non-equilibrium martensite into a dual-phase α + β microstructure. In the present study, post-processing sub-transus HT are conducted at various annealing temperatures for 2 h, with slow cooling either in a larger volumetric horizontal industrial furnace or a smaller volumetric tubular laboratory furnace. These two different furnaces were chosen to significantly modify the atmosphere and generate an oxygen-affected layer on the surface. The results show that the higher the annealing temperature, the coarser the α laths and the higher the β phase fraction. An oxygen-enriched hard and brittle alpha-case layer was revealed only for HT performed in the industrial furnace. The provided data allowed modeling of the oxygen diffusion in Ti-6Al-4V made by L-PBF. It has been found that without the alpha-case, post-processing HT helps to balance the strength/ductility compromise of the alloy in relation to the microstructural evolution. On the other hand, when an alpha-case layer greater than 50 µm is present, the elongation to failure is impacted and decreases as the alpha-case depth increases. Meanwhile, the impact toughness is less affected and remains mainly microstructure-dependent. The loss in ductility was attributed to the presence of cracks that develop at the surface of the samples during tensile solicitation. The opening rate of the crack lips is proportional to the applied strain, and the cracks spread through the brittle alpha-case layer. It has been shown for the first time that the cracks are visible on the sample’s surface for stress values lower than half of the material’s yield stress. The post-processing HT at 800 °C for 2 h provided a strong and ductile Ti-6Al-4V, which showed a minor effect of the alpha-case on the tensile properties.

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Insights into the influence of powder particle shape on forming process and mechanical properties of Al2O3 ceramic fabricated by laser directed energy deposition

Laser directed energy deposition (LDED) is a promising technology for preparing complex-shaped melt-grown Al2O3-based ceramics which are important candidates for new high-temperature structural materials. The characteristics of ceramic powder particle significantly affect the stability of LDED process and the forming quality of ceramic samples. In this study, rod-like and thin-walled Al2O3 ceramics were one-step fabricated by LDED by using the plasma spheroidized alumina powder (PSAP) and irregular alumina powder (IAP), respectively. The differences in forming quality and mechanical properties of the specimens prepared by the above two powders were analyzed and discussed. Both powders achieved high-quality forming of rod-like samples with high relative densities of more than 99% and 98%, respectively. The flowability of IAP met the fundamental forming requirements of LDED technology. The microhardness and fracture toughness of the Al2O3 ceramics obtained by using IAP were 17.77 ± 0.97 GPa and 4.58 ± 0.50 MPa·m1/2, respectively. Due to the angular shape and narrow particle size distribution of IAP, there were lack-of-fusion (LOF) pores at the grain boundaries. Intergranular oxide impurities and LOF pores reduced the flexural strength. In contrast, the flexural strength of Al2O3 ceramics prepared by PSAP reached 276.6 ± 22.9 MPa due to the columnar crystals with highly consistent growth orientation. Combining the reduction of line energy density and the supplement of additional laser energy input, crack-free thin-walled Al2O3 ceramics with a width of 30 mm were successfully manufactured using PSAP. Its relative density was close to 99%, and the forming error of width direction was only 5.7%. The study demonstrates the profound influence of powder particle shape on the forming quality of LDED, which provides an essential reference for laser additive manufacturing of high-quality Al2O3-based ceramics.

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Mechanics-guided manufacturing optimization framework to enhance the strength of architected lattice made from recycled plastic wastes

Improving the built quality of printed objects is commonly tackled from a material composition or manufacturing processing perspective, but mechanics also play a critical role in controlling performance of the printed parts. In this study, we investigate lattices that are manufactured with recycled PLA (Polylactic Acid) using a mechanics-guided approach, which assigned optimal printing parameters to specific struts according to a possible tensile, compressive, and flexural stress state. We identify the optimal combinations of nozzle temperature, printing speed, and layer heights using standard test specimens for each loading scenario, The strengths of specimens with optimal parameters are up to 23% higher than those with default parameters. Guided by simulations and experiments, we then compared the compressive strength and energy absorption of recycled PLA lattices fabricated by programmable printing parameter sets against those with default parameter sets without considering mechanical features. Strength and energy-absorbing ability can be improved by up to 25.52% and 140.22% respectively. Overall, we validate the role of mechanics in fabricating a 3D-printed object and envision that our approach is universal and applicable to improving the mechanical properties of any given geometries printed by other methods and with other base materials.

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Machine learning-assisted in-situ adaptive strategies for the control of defects and anomalies in metal additive manufacturing

Highlights • We review conventional and modern machine learning (ML)-assisted works employing closed loop control (CLC) strategies in metal additive manufacturing (AM). • We discuss various AM defects and their causes, their observability, and controllability in terms of avoidance, mitigation, or repair. • We show that traditional CLC control solutions lack the flexibility and scalability to adequately support AM processes. • We propose an ML-assisted CLC solution framework supported by ML algorithms which solve quickly and support a broader spectrum of situations. • We focus our discussion on ML-assisted adaptive in-situ control – the topic which has received the least attention in the literature so far. In metal additive manufacturing (AM), the material microstructure and part geometry are formed incrementally. Consequently, the resulting part could be defect- and anomaly-free if sufficient care is taken to deposit each layer under optimal process conditions. Conventional closed-loop control (CLC) engineering solutions which sought to achieve this were deterministic and rule-based, thus resulting in limited success in the stochastic environment experienced in the highly dynamic AM process. On the other hand, emerging machine learning (ML) based strategies are better suited to providing the robustness, scope, flexibility, and scalability required for process control in an uncertain environment. Offline ML models that help optimise AM process parameters before a build begins and online ML models that efficiently processed in-situ sensory data to detect and diagnose flaws in real-time (or near-real-time) have been developed. However, ML models that enable a process to take evasive or corrective actions in relation to flaws via on the fly decision-making are only emerging. These models must possess prognostic capabilities to provide context-sensitive recommendations for in-situ process control based on real-time diagnostics. In this article, we pinpoint the shortcomings in traditional CLC strategies, and provide a framework for defect and anomaly control through ML-assisted CLC in AM. We discuss flaws in terms of their causes, in-situ detectability, and controllability, and examine their management under three scenarios: avoidance, mitigation, and repair. Then, we summarise the research into ML models developed for offline optimisation and in-situ diagnosis before initiating a detailed conversation on the implementation of ML-assisted in-situ process control. We found that researchers favoured reinforcement learning approaches or inverse ML models for making rapid, situation-aware control decisions. We also observed that, to-date, the defects addressed were those that may be quantified relatively easily autonomously, and that mitigation (rather than avoidance or repair) was the aim of ML-assisted in-situ control strategies. Additionally, we highlight the various technologies that must seamlessly combine to advance the field of autonomous in-situ control so that it becomes a reality in industrial settings. Finally, we raise awareness of seldom discussed, yet highly pertinent, topics relevant to adaptive control. Our work closes a significant gap in the current AM literature by broaching wide-ranging discussions on matters relevant to in-situ adaptive control in AM.

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